Development of highly thermally-stabile thermoplastic elastomers composed of hydrocarbon monomers using a single-site catalyst
| Project/Area Number |
25288100
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Partial Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Polymer/Textile materials
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| Research Institution | Hiroshima University |
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Principal Investigator |
Shiono Takeshi 広島大学, 工学(系)研究科(研究院), 教授 (10170846)
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| Co-Investigator(Kenkyū-buntansha) |
NAKAYAMA YUUSHOU 広島大学, 工学研究院, 准教授 (20273576)
TANAKA RYOU 広島大学, 工学研究院, 助教 (60640795)
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| Project Period (FY) |
2013-04-01 – 2016-03-31
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| Project Status |
Completed (Fiscal Year 2015)
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| Budget Amount *help |
¥18,720,000 (Direct Cost: ¥14,400,000、Indirect Cost: ¥4,320,000)
Fiscal Year 2015: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2014: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2013: ¥10,920,000 (Direct Cost: ¥8,400,000、Indirect Cost: ¥2,520,000)
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| Keywords | 熱可塑性エラストマー / ポリオレフィン / 配位重合 / リビング重合 / ブロック共重合 / グラフト共重合 / シクロオレフィン共重合体 / 高耐熱 / 重合触媒 / ブロック共重合体 |
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| Outline of Final Research Achievements |
Thermoplastic elastomers are expected materials due to their processability and recyclability because common elastomers chemically cross-linked needs energy and time for processing and are difficult to be recycled. In this study, we developed thermoplastic elastomers with high thermal stability from simple hydrocarbon monomers, propylene, 1-octene and norbornene, using a coordination polymerization catalyst which the authors have been developed by precisely controlling the polymer structures. The elastomers developed possessed (1-octene-stat-norbornene) sequences as a hard segment, of which glass transition temperature is controllable below 400 degree Celsius, and an atactic polypropylene sequence as a soft segment.
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Report
(4 results)
Research Products
(83 results)
