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Development of highly thermally-stabile thermoplastic elastomers composed of hydrocarbon monomers using a single-site catalyst

Research Project

Project/Area Number 25288100
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Polymer/Textile materials
Research InstitutionHiroshima University

Principal Investigator

Shiono Takeshi  広島大学, 工学(系)研究科(研究院), 教授 (10170846)

Co-Investigator(Kenkyū-buntansha) NAKAYAMA YUUSHOU  広島大学, 工学研究院, 准教授 (20273576)
TANAKA RYOU  広島大学, 工学研究院, 助教 (60640795)
Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥18,720,000 (Direct Cost: ¥14,400,000、Indirect Cost: ¥4,320,000)
Fiscal Year 2015: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2014: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2013: ¥10,920,000 (Direct Cost: ¥8,400,000、Indirect Cost: ¥2,520,000)
Keywords熱可塑性エラストマー / ポリオレフィン / 配位重合 / リビング重合 / ブロック共重合 / グラフト共重合 / シクロオレフィン共重合体 / 高耐熱 / 重合触媒 / ブロック共重合体
Outline of Final Research Achievements

Thermoplastic elastomers are expected materials due to their processability and recyclability because common elastomers chemically cross-linked needs energy and time for processing and are difficult to be recycled. In this study, we developed thermoplastic elastomers with high thermal stability from simple hydrocarbon monomers, propylene, 1-octene and norbornene, using a coordination polymerization catalyst which the authors have been developed by precisely controlling the polymer structures. The elastomers developed possessed (1-octene-stat-norbornene) sequences as a hard segment, of which glass transition temperature is controllable below 400 degree Celsius, and an atactic polypropylene sequence as a soft segment.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • Research Products

    (83 results)

All 2016 2015 2014 2013 Other

All Journal Article (19 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 17 results,  Acknowledgement Compliant: 3 results) Presentation (63 results) (of which Int'l Joint Research: 8 results,  Invited: 12 results) Book (1 results)

  • [Journal Article] The preparation of boron-containing aluminoxanes and their application as cocatalysts in the polymerization of olefins2016

    • Author(s)
      Tanaka, R.; Hirose, T.; Nakayama, Y.; Shiono, T.
    • Journal Title

      Polymer Journal

      Volume: 48 Issue: 1 Pages: 67-71

    • DOI

      10.1038/pj.2015.81

    • NAID

      40020685239

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] オレフィンと13族アルケニル化合物の共重合による官能基化ポリオレフィンの合成2016

    • Author(s)
      田中 亮,塩野 毅
    • Journal Title

      触媒

      Volume: 58 Pages: 27-31

    • Related Report
      2015 Annual Research Report
  • [Journal Article] Synthesis of Polystyrene-grafted Cycloolefin Copolymer2015

    • Author(s)
      R. Tanaka, I. Kamei, Z. Cai, Y. Nakayama, T. Shiono
    • Journal Title

      Polymer

      Volume: 70 Pages: 252-256

    • DOI

      10.1016/j.polymer.2015.06.036

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Highly Soluble Polynorbornene Prepared by an Anilinonaphthoquinone-Ligated Nickel Complex via Coordination-Insertion Polymerization2015

    • Author(s)
      M. Okada, Y. Nakayama, T. Shiono
    • Journal Title

      J. Organometal. Chem.

      Volume: 70 Pages: 384-387

    • DOI

      10.1016/j.jorganchem.2015.06.028

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Facile Synthesis of Novel Polyethylene-Based A-B-C Block Copolymers Containing Poly(methyl methacrylate) Using a Living Polymerization System2015

    • Author(s)
      X. Song, Q. Ma, Z. Cai, R. Tanaka, T. Shiono, R. B. Grubbs
    • Journal Title

      Macromol. Rapid Commun.

      Volume: 37 Issue: 3 Pages: 227-231

    • DOI

      10.1002/marc.201500614

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Structure-stereospecificity relationships of propylene polymerization using substituted ansa-silylene(fluorenyl)(amido) titanium complexes2015

    • Author(s)
      12) R. Tanaka, C. Yanase, Y. Nakayama, T. Shiono
    • Journal Title

      J. Organomet. Chem.

      Volume: 804 Pages: 95-100

    • DOI

      10.1016/j.jorganchem.2015.12.028

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 計算化学的手法によるフルオレニルアミドチタン錯体を用いたプロピレン重合の機構解析2015

    • Author(s)
      田中 亮,柳瀬 千絵,蔡 正国,中山祐正,塩野 毅
    • Journal Title

      次世代ポリオレフィン総合研究

      Volume: 9 Pages: 27-30

    • Related Report
      2015 Annual Research Report
  • [Journal Article] Ethylene-propylene copolymerization behavior of ansa-dimethylsilylene(fluorenyl)(amido)dimethyltitanium complex: application to ethylene-propylene-diene or ethylene-propylene-norbornene terpolymers2015

    • Author(s)
      Ryo Tanaka, Issei Kamei, Zhengguo Cai, Yuushou Nakayama, Takeshi Shiono
    • Journal Title

      J. Polym. Sci. Part A: Polym. Chem.

      Volume: 53 Issue: 5 Pages: 685-691

    • DOI

      10.1002/pola.27494

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Pseudo-living copolymerization of norbornene and omega-alkenylborane - synthesis of monodisperse functionalized cycloolefin copolymer2015

    • Author(s)
      Ryo Tanaka, Tomomi Ikeda, Yuushou Nakayama, Takeshi Shiono
    • Journal Title

      Polymer

      Volume: 56 Pages: 218-222

    • DOI

      10.1016/j.polymer.2014.11.059

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Synthesis and application of α-diimine Ni(II) and Pd(II) complexes with bulky steric groups to polymerization of ethylene and methyl methacrylate2015

    • Author(s)
      Fuzhou Wang, Ryo Tanaka, Qingshan Li, Yuushou Nakayama, Jianchao Yuan, Takeshi Shiono
    • Journal Title

      J. Mol. Catal. A: Chem.

      Volume: 398 Pages: 231-240

    • DOI

      10.1016/j.molcata.2014.11.004

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of C1 symmetrical ansa-cyclopentadienylamidotitanium complexes and their application for living polymerization of propylene2014

    • Author(s)
      Zhengguo Cai, Haihui Su, Yuushou Nakayama, Takeshi Shiono, Munetaka Akita
    • Journal Title

      J. Organomet Chem.

      Volume: 770 Pages: 136-141

    • DOI

      10.1016/j.jorganchem.2014.08.019

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Heterogenization of an Anilinonaphthoquinone-Chelated Nickel Complex for Ethylene Polymerization Using Silica-Supported Modifi ed Methylaluminoxane2014

    • Author(s)
      Mitsuhiro Okada, Yuushou Nakayama, Takeshi Shiono
    • Journal Title

      Macromol. Chem. Phys.

      Volume: 215 Issue: 18 Pages: 1792-1796

    • DOI

      10.1002/macp.201400165

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] New Nickel(II) Diimine Complexes Bearing Phenyl and sec-Phenethyl Groups: Synthesis, Characterization, and Ethylene Polymerization Behaviour2014

    • Author(s)
      Fuzhou Wang, Jianchao Yuan, Qingshan Li, Ryo Tanaka, Yuushou Nakayama, Takeshi Shiono
    • Journal Title

      Appl. Organomet. Chem.

      Volume: 28 Issue: 7 Pages: 477-483

    • DOI

      10.1002/aoc.3151

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Precise Synthesis of Cycloolefin Copolymer Using ansa-Silylene(fluorenyl)(amido)dimethyltitanium Complex as a Catalyst2014

    • Author(s)
      田中亮、塩野毅
    • Journal Title

      Journal of Synthetic Organic Chemistry, Japan

      Volume: 72 Issue: 2 Pages: 118-125

    • DOI

      10.5059/yukigoseikyokaishi.72.118

    • NAID

      130003395378

    • ISSN
      0037-9980, 1883-6526
    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and their thermal, mechanical, and optical properties of A-B-A or A-B block copolymers containing poly(norbornene-co-1-octene)2014

    • Author(s)
      R. Tanaka, T. Suenaga, Z. Cai, Y. Nakayama, T. Shiono
    • Journal Title

      J. Polym. Sci. PART A, Polym. Chem.

      Volume: 52 Issue: 2 Pages: 267-271

    • DOI

      10.1002/pola.26999

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and their thermal, mechanical, and optical properties of A-B-A or A-B block copolymers containing poly(norbornene-co-1-octene)2014

    • Author(s)
      R. Tanaka, Y. Kasai, M. Shinzawa, Z. Cai, Y. Nakayama, T. Shiono
    • Journal Title

      Macromol. Chem. Phys.

      Volume: 215 Issue: 9 Pages: 888-892

    • DOI

      10.1002/macp.201400016

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of high-molecular weight block copolymers of norbornene and propylene with methyl methacrylate initiated by fluorenylamido titanium complex2013

    • Author(s)
      R. Tanaka, Y. Nakayama, T. Shiono
    • Journal Title

      Polym. Commun.

      Volume: 4 Issue: 14 Pages: 3974-3980

    • DOI

      10.1039/c3py00400g

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Facile Synthesis of Hydroxy-Functionalized Cycloolefin Copolymer Using omega-Alkenylaluminum as a Comonomer2013

    • Author(s)
      T. Shiono, M. Sugimoto, T. Hasan, Z. Cai
    • Journal Title

      Macromol. Chem. Phys.

      Volume: 214 Issue: 19 Pages: 2239-2244

    • DOI

      10.1002/macp.201300347

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Copolymerization of Norbornene with omega-Alkenylaluminum as a Precursor Comonomer for Introduction of Carbonyl Moieties2013

    • Author(s)
      J.-W. Lee, S. Jantasee, B. Jongsomjit, R. Tanaka, Y. Nakayama, T. Shiono
    • Journal Title

      J. Polym. Sci. PART A, Polym. Chem.

      Volume: 51 Issue: 23 Pages: 5085-5090

    • DOI

      10.1002/pola.26940

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Presentation] Novel cycloolefin copolymers synthesized by ansa-dimethylsilylene(fluorenyl)(amido)titanium based catalysts2015

    • Author(s)
      Takeshi Shiono
    • Organizer
      Asian Polyolefin Workshop (APO 2015)
    • Place of Presentation
      Tokyo Metropolitan University
    • Year and Date
      2015-11-27
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Evaluation of cocatalyst synthesized from boronic acid and trimethylaluminum for the propylene polymerization using the Me2Si(Flu)(t-BuN)TiMe22015

    • Author(s)
      Takaaki Hirose, Ryo Tanaka, Yuushou Nakayama, Takeshi Shiono
    • Organizer
      Asian Polyolefin Workshop (APO 2015)
    • Place of Presentation
      Tokyo Metropolitan University
    • Year and Date
      2015-11-26
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Stereospecific polymerization of 1,3-butadiene with a monocyclopentadienyl titanium(IV) complex bearing a pendant phosphanyl group2015

    • Author(s)
      Mizuki Shuto,Ryo Tanaka, Yuushou Nakayama, Takeshi Shiono
    • Organizer
      Asian Polyolefin Workshop (APO 2015)
    • Place of Presentation
      Tokyo Metropolitan University
    • Year and Date
      2015-11-26
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Effect of Me3Al in MAO on supported cocatalyt for propylene polymerization by ansa-fluorenylamidotitanium catalyst2015

    • Author(s)
      Taiki Tabuchi,Ryo Tanaka, Yuushou Nakayama, Takeshi Shiono
    • Organizer
      Asian Polyolefin Workshop (APO 2015)
    • Place of Presentation
      Tokyo Metropolitan University
    • Year and Date
      2015-11-26
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Chain-walking polymerization of 2-hexene and 2-octene catalyzed by α-diimine nickel catalysts/MMAO: living/controlled behavior, branch structure, and mechanism2015

    • Author(s)
      Fuzhou Wang,Ryo Tanaka, Yuushou Nakayama, Takeshi Shiono
    • Organizer
      Asian Polyolefin Workshop (APO 2015)
    • Place of Presentation
      Tokyo Metropolitan University
    • Year and Date
      2015-11-26
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Me2Si(η3-C29H36)(NtBu)TiMe2触媒を用いたポリオレフィングラフト共重合体の合成2015

    • Author(s)
      佐々木 茜, 田中 亮,中山 祐正,塩野 毅
    • Organizer
      第30回中国四国地区高分子若手研究会
    • Place of Presentation
      道後温泉にぎたつ会館
    • Year and Date
      2015-11-05
    • Related Report
      2015 Annual Research Report
  • [Presentation] プロピレンのイソ特異的リビング重合を指向した新規架橋フルオレニルアミジナートチタン錯体の合成2015

    • Author(s)
      恒成 順平,田中 亮,中山 祐正,塩野 毅
    • Organizer
      第30回中国四国地区高分子若手研究会
    • Place of Presentation
      道後温泉にぎたつ会館
    • Year and Date
      2015-11-05
    • Related Report
      2015 Annual Research Report
  • [Presentation] Tailor-Made Cycloolefin Copolymers Using ansa-Dimethylsilylene(fluorenyl)(amido)titanium-Based Catalysts2015

    • Author(s)
      Takeshi Shiono
    • Organizer
      IUPAC 11th International Conference on Advanced Polymers via Macromolecular Engineering
    • Place of Presentation
      Yokohama
    • Year and Date
      2015-10-21
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] シンプルなモノマーから高性能ポリマーを!-チタン錯体触媒によるノルボルネン-1-アルケン共重合と光学樹脂への応用-2015

    • Author(s)
      塩野 毅
    • Organizer
      第5回CSJ化学フェスタ
    • Place of Presentation
      タワーホール船堀
    • Year and Date
      2015-10-15
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Functionalization of Cycloolefin Copolymers Using omega-Akenylaluminium or omega-Akenylboron as a Reactive Comonomer2015

    • Author(s)
      Takeshi Shiono
    • Organizer
      Malaysia Scientific Association International Symposium on Materials Science and Nanotechnology in International Congress on Science and Nature
    • Place of Presentation
      Kuala Lumpur (Malaysia)
    • Year and Date
      2015-09-23
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Precise Synthesis of Cyclic Olefin Copolymers Using ansa-dimethylsilylene(fluorenyl)(amido)dimethyltitanium-Based Catalysts2015

    • Author(s)
      Takeshi Shiono
    • Organizer
      250th ACS Meeting
    • Place of Presentation
      Boston (USA)
    • Year and Date
      2015-08-17
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 計算科学的手法を用いたフルオレニルアミドチタン錯体によるプロピレン重合の機構解析2015

    • Author(s)
      田中 亮,中山祐正,塩野 毅
    • Organizer
      第10回次世代ポリオレフィン総合研究会
    • Place of Presentation
      首都大学東京秋葉原サテライトキャンパス
    • Year and Date
      2015-08-07
    • Related Report
      2015 Annual Research Report
  • [Presentation] 重合技術によるポリプロピレンの高性能化・高機能化2015

    • Author(s)
      塩野 毅
    • Organizer
      第4回高分子学会グリーンケミストリー研究会シンポジウム
    • Place of Presentation
      日本大学理工学部駿河台校舎
    • Year and Date
      2015-08-07
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 配位重合触媒の基礎と最前線2015

    • Author(s)
      塩野 毅
    • Organizer
      第60回高分子夏季大学
    • Place of Presentation
      朱鷺メッセ
    • Year and Date
      2015-07-09
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 錯体触媒によるシクロオレフィン共重合体の精密合成2015

    • Author(s)
      塩野 毅
    • Organizer
      第64回高分子年次大会
    • Place of Presentation
      札幌コンベンションセンター
    • Year and Date
      2015-05-27
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 計算化学的手法によるフルオレニルアミドチタン錯体を用いたプロピレンの重合機構解析2015

    • Author(s)
      田中 亮, 柳瀬 千絵, 蔡 正国, 中山祐正, 塩野 毅
    • Organizer
      第64回高分子学会年次大会
    • Place of Presentation
      札幌コンベンションセンター
    • Year and Date
      2015-05-27
    • Related Report
      2015 Annual Research Report
  • [Presentation] フルオレニルアミドチタン触媒を用いたプロピレン重合におけるシリカ担持有機アルミニウムの添加効果2015

    • Author(s)
      田淵 太基,田中 亮, 中山祐正, 塩野 毅
    • Organizer
      第64回高分子学会年次大会
    • Place of Presentation
      札幌コンベンションセンター
    • Year and Date
      2015-05-27
    • Related Report
      2015 Annual Research Report
  • [Presentation] ペンダントホスファニル基を有するハーフチタノセン錯体を用いた立体特異的1,3-ブタジエン重合2015

    • Author(s)
      首藤 瑞貴,田中 亮, 中山祐正, 塩野 毅
    • Organizer
      第64回高分子学会年次大会
    • Place of Presentation
      札幌コンベンションセンター
    • Year and Date
      2015-05-27
    • Related Report
      2015 Annual Research Report
  • [Presentation] Synthesis of highly branched polyolefins using a phenyl substituted α-diimine Ni(II) catalyst2015

    • Author(s)
      王 福周,塩野 毅,中山祐正, 田中 亮
    • Organizer
      第64回高分子学会年次大会
    • Place of Presentation
      札幌コンベンションセンター
    • Year and Date
      2015-05-27
    • Related Report
      2015 Annual Research Report
  • [Presentation] 新規架橋フルオレニルアミジナートチタン錯体の合成とプロピレン重合への応用2015

    • Author(s)
      恒成 順平,塩野 毅,中山祐正, 田中 亮
    • Organizer
      第64回高分子学会年次大会
    • Place of Presentation
      札幌コンベンションセンター
    • Year and Date
      2015-05-27
    • Related Report
      2015 Annual Research Report
  • [Presentation] Me2Si(η3-C29H36)(NtBu)TiMe2を用いた4-メチル-1-ペンテンの重合2015

    • Author(s)
      佐々木 茜,塩野 毅,中山祐正, 田中 亮
    • Organizer
      第64回高分子学会年次大会
    • Place of Presentation
      札幌コンベンションセンター
    • Year and Date
      2015-05-27
    • Related Report
      2015 Annual Research Report
  • [Presentation] Me2Si(Flu)(t-BuN)TiMe2 錯体を用いたボロン酸/トリメチルアルミニウム反応物のオレフィン重合助触媒能評価2015

    • Author(s)
      廣瀬貴彰,塩野 毅,田中 亮, 中山祐正
    • Organizer
      第64回高分子学会年次大会
    • Place of Presentation
      札幌コンベンションセンター
    • Year and Date
      2015-05-27
    • Related Report
      2015 Annual Research Report
  • [Presentation] オレフィン重合におけるシリカ担持有機アルミニウムの添加効果2014

    • Author(s)
      田淵 太基, 田中 亮, 中山 祐正, 塩野 毅
    • Organizer
      第29回中国四国地区高分子若手研究会
    • Place of Presentation
      サンポートホール高松, 香川
    • Year and Date
      2014-10-31
    • Related Report
      2014 Annual Research Report
  • [Presentation] CpTiCl3-MAO系における配位性化合物を用いたリビングポリブタジエンの立体規則性制御2014

    • Author(s)
      首藤 瑞貴, 田中 亮, 中山 祐正, 塩野 毅
    • Organizer
      第29回中国四国地区高分子若手研究会
    • Place of Presentation
      サンポートホール高松, 香川
    • Year and Date
      2014-10-30
    • Related Report
      2014 Annual Research Report
  • [Presentation] Co- and terpolymerization of ethylene, propylene and cycloolefin by ansa-dimethylsilylene(fluorenyl)(amido)dimethyltitanium-based catalyst2014

    • Author(s)
      Takeshi Shiono
    • Organizer
      International Workshop on Catalytic Olefin Polymerization & High Performance Polyolefins
    • Place of Presentation
      Shanghai, China
    • Year and Date
      2014-10-25
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 架橋フルオレニルアミドジメチルチタン‐シリカ担持メチルアルミノキサン触媒によるプロピレン重合における分子量・分子量分布の制御2014

    • Author(s)
      川原 友泰, 田淵 太基, 田中 亮, 中山 祐正, 塩野 毅
    • Organizer
      第44回石油・石油化学討論会
    • Place of Presentation
      旭川グランドホテル, 北海道
    • Year and Date
      2014-10-16
    • Related Report
      2014 Annual Research Report
  • [Presentation] Synthesis of salicylaldimine-based binuclear nickel(II) complexes and their application to polymerization catalysis2014

    • Author(s)
      Fuzhou Wang, Ryo Tanaka, Yuushou Nakayama, Takeshi Shiono
    • Organizer
      第114回触媒討論会
    • Place of Presentation
      広島大学, 広島
    • Year and Date
      2014-09-27
    • Related Report
      2014 Annual Research Report
  • [Presentation] 修飾メチルアルミノキサンの助触媒能に対するフェノキシアルミニウム化合物の添加効果2014

    • Author(s)
      山下 高幸, 田中 亮, 中山 祐正, 塩野 毅
    • Organizer
      第114回触媒討論会
    • Place of Presentation
      広島大学, 広島
    • Year and Date
      2014-09-27
    • Related Report
      2014 Annual Research Report
  • [Presentation] アルキルアルミニウムのアルキル基が修飾メチルアルミノキサンの助触媒能に及ぼす影響2014

    • Author(s)
      山下 高幸, 田中 亮, 中山 祐正, 塩野 毅
    • Organizer
      第63回高分子討論会
    • Place of Presentation
      長崎大学, 長崎
    • Year and Date
      2014-09-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] 修飾メチルアルミノキサン担持助触媒系を用いたプロピレン重合における分子量・分子量分布の制御2014

    • Author(s)
      川原 友泰, 塩野 毅, 中山 祐正, 田中 亮
    • Organizer
      第63回高分子討論会
    • Place of Presentation
      長崎大学, 長崎
    • Year and Date
      2014-09-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] オレフィン重合における担持有機アルミニウムの添加効果2014

    • Author(s)
      田淵 太基, 田中 亮, 中山 祐正, 塩野 毅
    • Organizer
      第63回高分子討論会
    • Place of Presentation
      長崎大学, 長崎
    • Year and Date
      2014-09-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] Precise Synthesis of Cyclic Olefin Copolymers Using a Ti-Based Catalyst2014

    • Author(s)
      Takeshi Shiono
    • Organizer
      18th International Symposium on Advanced Display Materials and Devices (ADMD2014)
    • Place of Presentation
      Sendai, Japan
    • Year and Date
      2014-07-25
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 配位重合による炭化水素系ポリマーの精密合成2014

    • Author(s)
      塩野 毅
    • Organizer
      高分子学会講演会:精密重合が創り出す未来
    • Place of Presentation
      東京工業大学蔵前会館, 東京
    • Year and Date
      2014-07-24
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Controlled Copolymerization of Norbornene and 1‐Alkene with Ansa‐Dimethylsylilene(Fluorenyl)(Alkylamido) Dimethyltitanium Derivatives2014

    • Author(s)
      Takeshi Shiono, Chie Yanase, Ryo Tanaka, Yuushou Nakayama
    • Organizer
      IUPAC Macro 2014
    • Place of Presentation
      Chiang Mai, Thailand
    • Year and Date
      2014-07-08
    • Related Report
      2014 Annual Research Report
  • [Presentation] フルオレニルアミドチタン錯体を用いたノルボルネンとω-アルケニルボランとのリビングランダム共重合2014

    • Author(s)
      田中 亮, 中山 祐正, 塩野 毅
    • Organizer
      第63回高分子学会年次大会
    • Place of Presentation
      名古屋国際会議場, 愛知
    • Year and Date
      2014-05-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] (η5-Me5C5)TiBn3-B(C6F5)3/Oct3Al触媒系によるシンジオタクチックポリスチレン連鎖を有するブロック共重合体の合成2014

    • Author(s)
      首藤 瑞貴, 田中 亮, 中山 祐正, 塩野 毅
    • Organizer
      第63回高分子学会年次大会
    • Place of Presentation
      名古屋国際会議場, 愛知
    • Year and Date
      2014-05-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] ルイス酸担持助触媒を用いたプロピレン重合におけるアルミノキサンの添加効果2014

    • Author(s)
      川原 友泰, 田中 亮, 中山 祐正, 塩野 毅
    • Organizer
      第63回高分子学会年次大会
    • Place of Presentation
      名古屋国際会議場, 愛知
    • Year and Date
      2014-05-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] フェノキシアルミニウム化合物による修飾メチルアルミノキサンの助触媒能の向上2014

    • Author(s)
      山下 高幸, 田中 亮, 中山 祐正, 塩野 毅
    • Organizer
      第63回高分子学会年次大会
    • Place of Presentation
      名古屋国際会議場, 愛知
    • Year and Date
      2014-05-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] 担持助触媒の組み合わせによるプロピレン重合の制御2014

    • Author(s)
      田淵 太基, 田中 亮, 中山 祐正, 塩野 毅
    • Organizer
      第63回高分子学会年次大会
    • Place of Presentation
      名古屋国際会議場, 愛知
    • Year and Date
      2014-05-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] Precise Synthesis of Cycloolefin Copolymers with Novel Ti-based Catalysts2013

    • Author(s)
      T. Shiono
    • Organizer
      The Royal Golden Jubilee Ph.D. Program Congress XIV, “Basic Research for Sustainable Development”
    • Place of Presentation
      Jomtien Palm Beach Hotel & Resort, Pattaya, Chonburi, Thailand
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] フルオレニルアミドチタン錯体を用いたプロピレン重合におけるシリカ担持助触媒の調製方法の影響

    • Author(s)
      川原 友泰, 田中 亮, 中山 祐正, 塩野 毅
    • Organizer
      第28回中国四国地区高分子若手研究会
    • Place of Presentation
      アークホテル岡山, 岡山
    • Related Report
      2013 Annual Research Report
  • [Presentation] プロピレンのリビング重合系を用いたフェノール変性修飾メチルアルミノキサンの助触媒能評価

    • Author(s)
      山下 高幸, 田中 亮, 中山 祐正, 塩野 毅
    • Organizer
      第28回中国四国地区高分子若手研究会
    • Place of Presentation
      アークホテル岡山, 岡山
    • Related Report
      2013 Annual Research Report
  • [Presentation] シリカ担持メチルアルミノキサン助触媒の均一性

    • Author(s)
      川原 友泰, 矢野 晴紀, 田中 亮, 中山 祐正, 塩野 毅
    • Organizer
      第43回石油・石油化学討論会
    • Place of Presentation
      北九州国際会議場, 北九州
    • Related Report
      2013 Annual Research Report
  • [Presentation] Synthesis and Properties of Block Copolymers Containing Poly(norbornene-ran-1-octene) as Hard Segments

    • Author(s)
      Takuya Suenaga, Ryo Tanaka, Zhengguo Cai, Yuushou Nakayama, Takeshi Shiono
    • Organizer
      Asian Polyolefin Workshop 2013
    • Place of Presentation
      Beijing, China
    • Related Report
      2013 Annual Research Report
  • [Presentation] Copolymerization of norbornene and 1-alkene with ansa-dimethylsilylene(fluorenyl)(cumylamido)dimethyltitanium complex

    • Author(s)
      Chie Yanase, Ryo Tanaka, Zhengguo Cai, Yuushou Nakayama, Takeshi Shiono
    • Organizer
      Asian Polyolefin Workshop 2013
    • Place of Presentation
      Beijing, China
    • Related Report
      2013 Annual Research Report
  • [Presentation] Terpolymerization of ethene, 1-octene and norbornene with ansa-dimethylsilylene(fluorenyl)(t-butylamido) dimethyltitanium complex

    • Author(s)
      IssKamei, Ryo Tanaka, Yuushou Nakayama, Takeshi Shiono
    • Organizer
      Asian Polyolefin Workshop 2013
    • Place of Presentation
      Beijing, China
    • Related Report
      2013 Annual Research Report
  • [Presentation] Polymerization of 4-methyl-1-pentene with ansa-dimethylsilylene(fluorenyl)(t-butylamido)dimethyltitanium catalyst

    • Author(s)
      Manami Goda, Ryo Tanaka, Yuushou Nakayama, Takeshi Shiono
    • Organizer
      Asian Polyolefin Workshop 2013
    • Place of Presentation
      Beijing, China
    • Related Report
      2013 Annual Research Report
  • [Presentation] Cocatalyst ability of modified methylaluminoxane (MMAO) treated with bulky phenol derivatives

    • Author(s)
      Takayuki Yamashita, Ryo Tanaka, Yuushou Nakayama, Takeshi Shiono
    • Organizer
      Asian Polyolefin Workshop 2013
    • Place of Presentation
      Beijing, China
    • Related Report
      2013 Annual Research Report
  • [Presentation] Block Copolymerization of Propylene and Epoxides by Titanium-Aluminum Dual Catalyst System

    • Author(s)
      Ryo Tanaka, Yuushou Nakayama, Takeshi Shiono
    • Organizer
      Asian Polyolefin Workshop 2013
    • Place of Presentation
      Beijing, China
    • Related Report
      2013 Annual Research Report
  • [Presentation] フルオレニルアミドチタン錯体を用いたプロピレンと極性モノマーとのブロック共重合

    • Author(s)
      田中 亮, 中山 祐正, 塩野 毅
    • Organizer
      第62回高分子討論会
    • Place of Presentation
      金沢大学角間キャンパス, 金沢
    • Related Report
      2013 Annual Research Report
  • [Presentation] ジメチルシリレン架橋(フルオレニル)(t-ブチルアミド)ジメチルチタン錯体によるエチレン―1-オクテン―ノルボルネン三元共重合体の合成とその性質

    • Author(s)
      亀井 一成, 田中 亮, 中山 祐正, 塩野 毅
    • Organizer
      第62回高分子討論会
    • Place of Presentation
      金沢大学角間キャンパス, 金沢
    • Related Report
      2013 Annual Research Report
  • [Presentation] ジメチルシリレン架橋(フルオレニル)(クミルアミド)ジメチルチタン錯体によるノルボルネンと1-アルケンの共重合

    • Author(s)
      柳瀬 千絵, 田中 亮, 蔡 正国, 中山 祐正, 塩野 毅
    • Organizer
      第62回高分子討論会
    • Place of Presentation
      金沢大学角間キャンパス, 金沢
    • Related Report
      2013 Annual Research Report
  • [Presentation] ジメチルシリレン架橋(フルオレニル)(t-ブチルアミド)ジメチルチタン錯体による4-メチル-1-ペンテンのリビング重合

    • Author(s)
      合田 真奈美, 田中 亮, 中山 祐正, 塩野 毅
    • Organizer
      第62回高分子討論会
    • Place of Presentation
      金沢大学角間キャンパス, 金沢
    • Related Report
      2013 Annual Research Report
  • [Presentation] フルオレニルアミドチタン錯体を用いたプロピレン重合におけるSiO2担持助触媒の調製方法の影響

    • Author(s)
      川原 友泰, 田中 亮, 中山 祐正, 塩野 毅
    • Organizer
      第62回高分子討論会
    • Place of Presentation
      金沢大学角間キャンパス, 金沢
    • Related Report
      2013 Annual Research Report
  • [Presentation] プロピレンのリビング重合によるフェノール変性修飾メチルアルミノキサンの助触媒能評価と変性機構

    • Author(s)
      山下 高幸, 田中 亮, 中山 祐正, 塩野 毅
    • Organizer
      第62回高分子討論会
    • Place of Presentation
      金沢大学角間キャンパス, 金沢
    • Related Report
      2013 Annual Research Report
  • [Presentation] プロピレンおよび極性モノマーからなるブロック共重合体の合成とその性質

    • Author(s)
      田中 亮, 中山 祐正, 塩野 毅
    • Organizer
      第8回次世代ポリオレフィン総合研究
    • Place of Presentation
      首都大学東京秋葉原サテライトキャンパス, 東京
    • Related Report
      2013 Annual Research Report
  • [Presentation] Synthesis and Properties of A-B-A Block Copolymers Containing Poly(norbornen-ran-1-octene) as Hard Segments

    • Author(s)
      Takuya Suenaga, Ryo Tanaka, Zhengguo Cai, Yuushou Nakayama, Takeshi Shiono
    • Organizer
      The 17th International Symposium on Advanced Display Materials and Devices
    • Place of Presentation
      Shanghai, China
    • Related Report
      2013 Annual Research Report
  • [Presentation] ジメチルシリレン架橋(フルオレニル)(t-ブチルアミド)ジメチルチタン錯体によるノルボルネンと嵩高い1-アルケンの共重合

    • Author(s)
      合田 真奈美, 田中 亮, 中山 祐正, 塩野 毅
    • Organizer
      第62回高分子学会年次大会
    • Place of Presentation
      京都国際会館, 京都
    • Related Report
      2013 Annual Research Report
  • [Presentation] ジメチルシリレン架橋(フルオレニル)(t-ブチルアミド)ジメチルチタン錯体を用いたエチレン-1-アルケン-ノルボルネン三元共重合

    • Author(s)
      亀井 一成, 田中 亮, 中山 祐正, 塩野 毅
    • Organizer
      第62回高分子学会年次大会
    • Place of Presentation
      京都国際会館, 京都
    • Related Report
      2013 Annual Research Report
  • [Presentation] ジメチルシリレン架橋(フルオレニル)(クミルアミド)ジメチルチタン錯体によるプロピレンとノルボルネンとの共重合

    • Author(s)
      柳瀬 千絵, 田中 亮, 中山 祐正, 塩野 毅
    • Organizer
      第62回高分子学会年次大会
    • Place of Presentation
      京都国際会館, 京都
    • Related Report
      2013 Annual Research Report
  • [Presentation] フルオレニルアミドチタン錯体を用いたメタクリル酸メチルの重合およびオレフィン類とのブロック共重合

    • Author(s)
      田中 亮, 中山 祐正, 塩野 毅
    • Organizer
      第62回高分子学会年次大会
    • Place of Presentation
      京都国際会館, 京都
    • Related Report
      2013 Annual Research Report
  • [Presentation] 嵩高いフェノール誘導体より変性した修飾メチルアルミノキサンの重合助触媒能

    • Author(s)
      山下 高幸, 田中 亮, 中山 祐正, 塩野 毅
    • Organizer
      第62回高分子学会年次大会
    • Place of Presentation
      京都国際会館, 京都
    • Related Report
      2013 Annual Research Report
  • [Presentation] メチルアルミノキサン(MAO)と修飾メチルアルミノキサン(MMAO)の担持助触媒効果

    • Author(s)
      川原 友泰, 田中 亮, 中山 祐正, 塩野 毅
    • Organizer
      第62回高分子学会年次大会
    • Place of Presentation
      京都国際会館, 京都
    • Related Report
      2013 Annual Research Report
  • [Book] 精密重合が拓く高分子合成-高度な制御と進む実用化2016

    • Author(s)
      塩野 毅(分担)
    • Publisher
      化学同人
    • Related Report
      2015 Annual Research Report

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Published: 2013-05-21   Modified: 2019-07-29  

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