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Combining area-selective preparation of active surfaces with the inkjet technology to form functional nanostructures

Research Project

Project/Area Number 25288107
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Inorganic industrial materials
Research InstitutionKyoto University

Principal Investigator

Hirao Kazuyuki  京都大学, 工学(系)研究科(研究院), 教授 (90127126)

Co-Investigator(Kenkyū-buntansha) NISHI Masayuki  京都大学, 大学院工学(系)研究科(研究院), 講師 (50402962)
Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥18,850,000 (Direct Cost: ¥14,500,000、Indirect Cost: ¥4,350,000)
Fiscal Year 2015: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Fiscal Year 2014: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Fiscal Year 2013: ¥12,350,000 (Direct Cost: ¥9,500,000、Indirect Cost: ¥2,850,000)
Keywords金ナノ粒子 / 無電解 / シリコン / 集束イオンビーム / ナノ粒子
Outline of Final Research Achievements

Gold nanostructures have attracted increasing attention because of their size-dependent properties including Localized surface plasmon resonance. Localized surface plasmon resonance is, for example, important for surface enhanced Raman spectroscopy and sensors. Tailoring the size, the shape, and the integrated structure of gold nanostructures is necessary to utilize such properties efficiently. We demonstrated that gold nanostructures selectively grow on focused ion beam (FIB)-irradiated areas of a silicon substrate when the substrate is exposed to pure HAuCl4 solution. We revealed the mail mechanism of this new area-selective electroless deposition. We also combined the area-selective deposition with the inkjet technology to further control the growth of gold.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • Research Products

    (26 results)

All 2016 2015 2014 2013 Other

All Journal Article (3 results) (of which Peer Reviewed: 3 results,  Acknowledgement Compliant: 1 results) Presentation (20 results) (of which Int'l Joint Research: 3 results,  Invited: 4 results) Remarks (1 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] Area-Selective Electroless Deposition of Gold Nanostructures on SiC Using Focused-Ion-Beam Preprocessing2015

    • Author(s)
      Hiroki Itasaka, Masayuki Nishi, Masahiro Shimizu and Kazuyuki Hirao
    • Journal Title

      MRS Proceedings

      Volume: 1748

    • DOI

      10.1557/opl.2015.74

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Role of solvent in direct growth of gold nanostructures at the interface between FIB-amorphized silicon and Au ion-containing solution2014

    • Author(s)
      Hiroki Itasaka, Masayuki Nishi*, and Kazuyuki Hirao
    • Journal Title

      Journal of Applied Physics

      Volume: 印刷中

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Selective growth of gold nanostructures on locally amorphized silicon2014

    • Author(s)
      Hiroki Itasaka, Masayuki Nishi*, Yasuhiko Shimotsuma, Kiyotaka Miura, Masashi Watanabe, Himanshu Jain, and Kazuyuki Hirao
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: 印刷中

    • NAID

      130004950965

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Presentation] Area-Selective Electroless Deposition of Gold Nanostructures with Various Morphologies on Silicon Assisted By Focused Ion Beam Irradiation2016

    • Author(s)
      Hiroki Itasaka, Masayuki Nishi, Masahiro Shimizu, and Kazuyuki Hirao
    • Organizer
      229th ECS Meeting
    • Place of Presentation
      San Diego, USA
    • Year and Date
      2016-06-01
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] シリコンナノ探針先端への局所選択的無電解金ナノ構造成長2016

    • Author(s)
      板坂浩樹、西正之、清水雅弘、平尾一之
    • Organizer
      粉体粉末冶金協会平成28年度春季大会
    • Place of Presentation
      京都工芸繊維大学
    • Year and Date
      2016-05-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] SiC基板表面での局所選択的無電解Auナノ構造成長2016

    • Author(s)
      板坂浩樹、西正之、清水雅弘、平尾一之
    • Organizer
      日本セラミックス協会2016年年会
    • Place of Presentation
      早稲田大学
    • Year and Date
      2016-03-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] Silver Growth on AFM Tip Apexes from Silver Nitrate Solutions Triggered by Focused-Ion-Beam Irradiation2015

    • Author(s)
      Masayuki Nishi, Daisuke Teranishi, Hiroki Itasaka, Masahiro Shimizu, and Kazuyuki Hirao
    • Organizer
      2015 MRS Fall Meeting & Exhibit
    • Place of Presentation
      Boston, USA
    • Year and Date
      2015-11-30
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 集束イオンビーム照射Si表面における無電解Auナノ構造成長2015

    • Author(s)
      板坂浩樹、西正之、清水雅弘、平尾一之
    • Organizer
      日本化学会秋季事業 第5回CSJ科学フェスタ2015
    • Place of Presentation
      タワーホール船堀
    • Year and Date
      2015-10-14
    • Related Report
      2015 Annual Research Report
  • [Presentation] シリコン‐溶液界面での電子移動を利用した局所選択的金属ナノ構造成長2015

    • Author(s)
      西正之、平尾一之
    • Organizer
      日本セラミックス協会第28回秋季シンポジウム
    • Place of Presentation
      富山大学
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Area-selective electroless deposition of gold on AFM tip apexes for tip-enhanced Raman spectroscopy2015

    • Author(s)
      Hiroki Itasaka, Masayuki Nishi, Masahiro Shimizu, and Kazuyuki Hirao
    • Organizer
      Single-Molecule Microscopy and Spectroscopy: Faraday Discussion
    • Place of Presentation
      London, UK
    • Year and Date
      2015-09-14
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 新規無電解法によるSi基板局所表面へのAuナノ構造成長2015

    • Author(s)
      板坂浩樹、西正之、清水雅弘、平尾一之
    • Organizer
      第10回日本セラミックス協会関西支部学術講演会
    • Place of Presentation
      京都大学
    • Year and Date
      2015-07-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] AFMチップ先端に咲くAuナノフラワー2015

    • Author(s)
      板坂浩樹, 西正之, 清水雅弘, 平尾一之, 中田靖、中庸行
    • Organizer
      日本セラミックス協会2015年年会 顕微鏡写真展
    • Place of Presentation
      岡山大学
    • Year and Date
      2015-03-18 – 2015-03-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] FIB照射Si表面での無電解Agナノ構造成長とインクジェット法による成長制御2015

    • Author(s)
      森川真理絵、西正之、板坂浩樹、清水雅弘、平尾一之
    • Organizer
      日本セラミックス協会2015年年会
    • Place of Presentation
      岡山大学
    • Year and Date
      2015-03-18 – 2015-03-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] Area-Selective Electroless Deposition of Gold Nanostructures on SiC Using Focused-Ion-Beam Preprocessing2014

    • Author(s)
      Hiroki Itasaka, Masayuki Nishi, Masahiro Shimizu, and Kazuyuki Hirao
    • Organizer
      2014 MRS Fall Meeting & Exhibit
    • Place of Presentation
      ボストン、アメリカ合衆国
    • Year and Date
      2014-11-30 – 2014-12-05
    • Related Report
      2014 Annual Research Report
  • [Presentation] 集束イオンビーム照射Si表面での無電解金属ナノ構造成長メカニズム2014

    • Author(s)
      西正之、平尾一之
    • Organizer
      2014年度セラミックス総合研究会
    • Place of Presentation
      松島一の坊
    • Year and Date
      2014-11-13 – 2014-11-14
    • Related Report
      2014 Annual Research Report
  • [Presentation] FIB誘起アモルファスSi表面でのAuナノ構造成長メカニズム2014

    • Author(s)
      板坂浩樹、西正之、平尾一之
    • Organizer
      日本セラミックス協会2014年年会
    • Place of Presentation
      慶應義塾大学
    • Year and Date
      2014-03-17 – 2014-03-19
    • Related Report
      2013 Annual Research Report
  • [Presentation] Selective growth of gold nanostructures on external field-induced amorphous silicon surface2013

    • Author(s)
      H. Itasaka, M. Nishi*, Y. Shimotsuma, K. Miura, M. Watanabe, H. Jain, and K. Hirao
    • Organizer
      The 10th MicRO Alliance Meeting and Nanomics Sympsium
    • Place of Presentation
      京都大学
    • Year and Date
      2013-11-21 – 2013-11-22
    • Related Report
      2013 Annual Research Report
  • [Presentation] 局所誘起アモルファスSi表面での選択的金属ナノ構造成長2013

    • Author(s)
      西 正之、平尾 一之
    • Organizer
      2013年度セラミックス総合研究会
    • Place of Presentation
      ホテルウェルシーズン浜名湖
    • Year and Date
      2013-11-14 – 2013-11-15
    • Related Report
      2013 Annual Research Report
  • [Presentation] 局所誘起アモルファスSi表面での選択的金属ナノ構造成長2013

    • Author(s)
      西 正之
    • Organizer
      低温合成法による新機能性材料の創製(第10回)
    • Place of Presentation
      京都大学
    • Year and Date
      2013-11-13
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Patterned Growth of Gold Nanostructures on Silicon via Reaction between Induced Silicon Dangling Bonds and Protic Solvent2013

    • Author(s)
      H. Itasaka, M. Nishi,* and K. Hirao
    • Organizer
      26th International Microprocesses and Nanotechnology Conference
    • Place of Presentation
      ロイトン札幌ホテル
    • Year and Date
      2013-11-05 – 2013-11-08
    • Related Report
      2013 Annual Research Report
  • [Presentation] Selective Growth of Ag Nanostructures on FIB-induced Amorphous Silicon2013

    • Author(s)
      E. Nakamura, M. Nishi*, H. Itasaka, T. Matsuoka, Y. Shimotsuma, K. Miura, and K. Hirao
    • Organizer
      26th International Microprocesses and Nanotechnology Conference
    • Place of Presentation
      ロイトン札幌
    • Year and Date
      2013-11-05 – 2013-11-08
    • Related Report
      2013 Annual Research Report
  • [Presentation] Si基板表面での局所選択的金属ナノ構造成長とそのメカニズム2013

    • Author(s)
      西 正之
    • Organizer
      日本セラミックス協会関西支部 第16回 若手フォーラム
    • Place of Presentation
      関西セミナーハウス修学院きらら山荘
    • Year and Date
      2013-10-25 – 2013-10-26
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Si基板の局所アモルファス化を利用した金属ナノ構造パターン形成2013

    • Author(s)
      西 正之
    • Organizer
      第131回ニューガラス研究会
    • Place of Presentation
      大阪キャッスルホテル
    • Year and Date
      2013-10-24
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Remarks] Hirao Laboratory

    • URL

      http://www1.kuic.kyoto-u.ac.jp

    • Related Report
      2015 Annual Research Report 2014 Annual Research Report 2013 Annual Research Report
  • [Patent(Industrial Property Rights)] ラマン散乱光測定装置、探針及び探針の製造方法2016

    • Inventor(s)
      板坂浩樹、西正之、平尾一之、奥野 義人、中田靖、中庸行
    • Industrial Property Rights Holder
      国立大学法人京都大学、株式会社堀場製作所
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2015-050026
    • Filing Date
      2016-03-14
    • Related Report
      2015 Annual Research Report
  • [Patent(Industrial Property Rights)] 探針の製造方法及び探針2015

    • Inventor(s)
      西正之、平尾一之、板坂浩樹、奥田晃士、森川真理絵、中田靖、中庸行
    • Industrial Property Rights Holder
      国立大学法人京都大学、株式会社堀場製作所
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2015-043766
    • Filing Date
      2015-03-05
    • Related Report
      2014 Annual Research Report

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Published: 2013-05-21   Modified: 2017-05-10  

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