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Development of high-performance solid-state electrochemical gas sensors by controlling their catalytic activities.

Research Project

Project/Area Number 25288109
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Inorganic industrial materials
Research InstitutionKyushu University

Principal Investigator

MIURA Norio  九州大学, 産学連携センター, 教授 (70128099)

Co-Investigator(Renkei-kenkyūsha) IKEDA Hiroshi  九州大学, 産学連携センター, 助教 (80621599)
Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥17,420,000 (Direct Cost: ¥13,400,000、Indirect Cost: ¥4,020,000)
Fiscal Year 2015: ¥7,410,000 (Direct Cost: ¥5,700,000、Indirect Cost: ¥1,710,000)
Fiscal Year 2014: ¥7,410,000 (Direct Cost: ¥5,700,000、Indirect Cost: ¥1,710,000)
Fiscal Year 2013: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Keywords安定化ジルコニア / 固体電解質 / ガスセンサ / 混成電位 / 環境汚染ガス / 固体電気化学 / 揮発性有機化合物 / 炭化水素
Outline of Final Research Achievements

This research aims to develop high-performance solid-state electrochemical gas sensors for monitoring automobile exhausts and air pollutants. We fabricated various kinds of gas sensors by using an yttria-stabilized zirconia (YSZ) as a solid electrolyte as well as various oxides (or metal nanoparticles) as sensing electrodes (SE) which were designed their microscopic structures, chemical compositions and crystal structures. As a result, novel high-performance electrochemical gas sensors were developed by controlling catalytic activities of electrochemical reactions at the SE/YSZ interface as well as gas-phase reactions in the SE layer.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • Research Products

    (47 results)

All 2016 2015 2014 2013

All Journal Article (13 results) (of which Peer Reviewed: 13 results,  Acknowledgement Compliant: 6 results,  Open Access: 1 results) Presentation (34 results) (of which Int'l Joint Research: 4 results,  Invited: 2 results)

  • [Journal Article] Sensing Characteristics of YSZ-based Oxygen Sensors Attached with BaxSr1-xFeO3 Sensing-electrode2016

    • Author(s)
      Ayumi Iio, Hiroshi Ikeda, Sri Ayu Anggraini, Norio Miura
    • Journal Title

      Solid State Ionics

      Volume: 285 Pages: 234-238

    • DOI

      10.1016/j.ssi.2015.04.015

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Acceleration of the Aging Process of YSZ-based H2 Sensor Using Zn-Ta-O Sensing-electrode2016

    • Author(s)
      Sri Ayu Anggraini, Hiroshi Ikeda, Norio Miura
    • Journal Title

      Sensors and Actuators B: Chemical

      Volume: 223 Pages: 738-742

    • DOI

      10.1016/j.snb.2015.09.150

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Tuning H2 Sensing Performance of Zirconia-based Sensor using ZrSiO4(+Au) Sensing-electrode2015

    • Author(s)
      Sri Ayu Anggraini, Hiroshi Ikeda, Norio Miura
    • Journal Title

      Electrochimica Acta

      Volume: 171 Pages: 7-12

    • DOI

      10.1016/j.electacta.2015.05.007

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mixed-potential Type Zirconia-based NH3 Sensor Using SnO2-disk Sensing-electrode Attached with Sputtered Au2014

    • Author(s)
      Tomoaki Sato, Hiroshi Ikeda, Norio Miura
    • Journal Title

      ECS Electrochemistry Letters

      Volume: 3 Issue: 6 Pages: B13-B15

    • DOI

      10.1149/2.004406eel

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] A Review of Mixed-potential Type Zirconia-based Gas Sensors2014

    • Author(s)
      Norio Miura, Tomoaki Sato, Sri Ayu Anggraini, Hiroshi Ikeda, Serge Zhuiykov
    • Journal Title

      Ionics

      Volume: 20 Issue: 7 Pages: 901-925

    • DOI

      10.1007/s11581-014-1140-1

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Sensing Performance of Zirconia-based Gas Sensor Using Titania Sensing-electrode Added with Palladium2014

    • Author(s)
      Yuki Fujio, Tomoaki Sato, Norio Miura
    • Journal Title

      Solid State Ionics

      Volume: 262 Pages: 266-269

    • DOI

      10.1016/j.ssi.2013.08.028

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Novel Zirconia-based NO2 Sensor Attached with Carbon Sensing-electrode2014

    • Author(s)
      Tomoaki Sato, Hiroshi Ikeda, Norio Miura
    • Journal Title

      Electrochemistry Communications

      Volume: 46 Pages: 60-62

    • DOI

      10.1016/j.elecom.2014.06.010

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Cobalt-based Solid Reference-electrode Usable in Zirconia-based Sensors for Detection of Oxygen or Volatile Organic Compounds2014

    • Author(s)
      Yuki Tanaka, Tomoaki Sato, Hiroshi Ikeda, Norio Miura
    • Journal Title

      Sensors and Actuators B: Chemical

      Volume: 203 Pages: 899-903

    • DOI

      10.1016/j.snb.2014.07.072

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Potentiometric YSZ-based Oxygen Sensor Using BaFeO3 Sensing-electrode2014

    • Author(s)
      Ayumi Iio, Hiroshi Ikeda, Sri Ayu Anggraini, Norio Miura
    • Journal Title

      Electrochemistry Communications

      Volume: 48 Pages: 134-137

    • DOI

      10.1016/j.elecom.2014.09.004

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] The Adsorption of NO on YSZ(111) and Oxygen-enriched YSZ(111) Surfaces2014

    • Author(s)
      Michael Breedon, Michelle J. S. Spencer, Norio Miura
    • Journal Title

      Chemical Physics Letters

      Volume: 593 Issue: 24 Pages: 61-68

    • DOI

      10.1021/jp310016r

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Reduction in Ethanol Interference of Zirconia-based Sensor for Selective Detection of Volatile Organic Compounds2013

    • Author(s)
      Tomoaki Sato, Michael Breedon, Norio Miura
    • Journal Title

      Journal of The Electrochemical Society

      Volume: 160(9) Issue: 9 Pages: B146-B151

    • DOI

      10.1149/2.007309jes

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of Sintering Temperature on Hydrogen Sensing Characteristics of Zirconia Sensor Utilizing Zn-Ta-O-based Sensing Electrode2013

    • Author(s)
      Sri Ayu Anggraini, Michael Breedon, Norio Miura
    • Journal Title

      Journal of The Electrochemical Society

      Volume: 160 Issue: 9 Pages: B164-B169

    • DOI

      10.1149/2.091309jes

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Insight into the Aging Effect on Enhancement of Hydrogen-sensing Characteristics of a Zirconia-based Sensor Utilizing a Zn-Ta-O-based Sensing Electrode2013

    • Author(s)
      Sri Ayu Anggraini, Michael Breedon, Hiroshi Ikeda, Norio Miura
    • Journal Title

      ACS Applied Materials Interfaces

      Volume: 5 Issue: 22 Pages: 12099-12106

    • DOI

      10.1021/am403952w

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Presentation] Zirconia-based Sensor Attached with CuCrFeO4 and CoCrFeO4 Electrodes for Selective CO Detection2016

    • Author(s)
      Sri Ayu Anggraini, 池田 弘, 三浦 則雄
    • Organizer
      第54回セラミックス基礎科学討論会
    • Place of Presentation
      アバンセ, 佐賀県佐賀市
    • Year and Date
      2016-01-07
    • Related Report
      2015 Annual Research Report
  • [Presentation] Amperometric Zirconia-based Sensor Attached with NiFe2O4 Sensing-electrode for Selective NO2 Detection2015

    • Author(s)
      Soichiro Yoshida, Hiroshi Ikeda, Sri Ayu Anggraini, Norio Miura
    • Organizer
      The 2015 International Chemical Congress of Pacific Basin Societies (Pacifichem2015)
    • Place of Presentation
      Hawaii Convention Center, Honolulu USA
    • Year and Date
      2015-12-16
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Potentiometric YSZ-based Gas Sensor by Using Graphite as a Novel Sensing-electrode2015

    • Author(s)
      Toshiki Fujii, Hiroshi Ikeda, Sri Ayu Anggraini, Norio Miura
    • Organizer
      The 2015 International Chemical Congress of Pacific Basin Societies (Pacifichem2015)
    • Place of Presentation
      Hawaii Convention Center, Honolulu USA
    • Year and Date
      2015-12-16
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Selective CO Detection Using YSZ-based Sensor with a Combination of CuCrFeO4 and CoCrFeO4 Electrodes2015

    • Author(s)
      Sri Ayu Anggraini, Hiroshi Ikeda, Norio Miura
    • Organizer
      The 11th Asian Conference on Chemical Sensors (ACCS2015)
    • Place of Presentation
      Shangri-La's Rasa Sayang Resort & Spa, Penang Malaysia
    • Year and Date
      2015-11-17
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] High Performance Solid-State Electrochemical Gas Sensors2015

    • Author(s)
      Norio Miura
    • Organizer
      The 11th Asian Conference on Chemical Sensors (ACCS2015)
    • Place of Presentation
      Shangri-La's Rasa Sayang Resort & Spa, Penang Malaysia
    • Year and Date
      2015-11-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] YSZにグラファイト検知極を付加した固体電気化学式NO2センサ2015

    • Author(s)
      藤井 利輝, Sri Ayu Anggraini, 池田 弘, 三浦 則雄
    • Organizer
      第59回化学センサ研究発表会
    • Place of Presentation
      埼玉工業大学, 埼玉県深谷市
    • Year and Date
      2015-09-12
    • Related Report
      2015 Annual Research Report
  • [Presentation] スピネル型酸化物を検知極に用いた電流検出型ジルコニアセンサによる選択的NO2検知2015

    • Author(s)
      吉田 宗一郎, 池田 弘, Sri Ayu Anggraini, 三浦 則雄
    • Organizer
      第59回化学センサ研究発表会
    • Place of Presentation
      埼玉工業大学, 埼玉県深谷市
    • Year and Date
      2015-09-12
    • Related Report
      2015 Annual Research Report
  • [Presentation] YSZにグラファイト検知極を付加した混成電位型ガスセンサ2015

    • Author(s)
      藤井 利輝, 池田 弘, Sri Ayu Anggraini, 三浦 則雄
    • Organizer
      第52回化学関連支部合同九州大会
    • Place of Presentation
      北九州国際会議場, 北九州市
    • Year and Date
      2015-06-27
    • Related Report
      2015 Annual Research Report
  • [Presentation] NiFe2O4検知極を用いた電流検出型ジルコニアセンサによるNO2検知2015

    • Author(s)
      吉田 宗一郎, 池田 弘, Sri Ayu Anggraini, 三浦 則雄
    • Organizer
      第52回化学関連支部合同九州大会
    • Place of Presentation
      北九州国際会議場, 北九州市
    • Year and Date
      2015-06-27
    • Related Report
      2015 Annual Research Report
  • [Presentation] BaFeO3検知極とMn系固体参照極を組み合わせたジルコニア酸素センサ2015

    • Author(s)
      飯尾 歩美, Sri Ayu Anggraini, 池田 弘, 三浦 則雄
    • Organizer
      第58回化学センサ研究発表会
    • Place of Presentation
      横浜国立大学, 横浜市
    • Year and Date
      2015-03-15
    • Related Report
      2014 Annual Research Report
  • [Presentation] Au/Ta2O5積層検知極を用いたプレナー型YSZセンサの水素検知特性2015

    • Author(s)
      一川 莉乃, Sri Ayu Anggraini, 池田 弘, 三浦 則雄
    • Organizer
      第58回化学センサ研究発表会
    • Place of Presentation
      横浜国立大学, 横浜市
    • Year and Date
      2015-03-15
    • Related Report
      2014 Annual Research Report
  • [Presentation] 高性能固体電気化学式ガスセンサの開発2015

    • Author(s)
      三浦 則雄
    • Organizer
      第58回化学センサ研究発表会
    • Place of Presentation
      横浜国立大学, 横浜市
    • Year and Date
      2015-03-15
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 鉄系ペロブスカイト型酸化物を新規検知極としたジルコニア酸素センサ2014

    • Author(s)
      飯尾 歩美, Sri Ayu Anggraini, 池田 弘, 三浦 則雄
    • Organizer
      第40回固体イオニクス討論会
    • Place of Presentation
      東京工業大学, 東京都
    • Year and Date
      2014-11-18
    • Related Report
      2014 Annual Research Report
  • [Presentation] Aging Effect and Mechanism in Enhancing Sensi-tivity and Selectivy of Zirconia-based H2 Sensors Using Zn-Ta-O Sensing Electrode2014

    • Author(s)
      Sri Ayu Anggraini, 池田 弘, 三浦 則雄
    • Organizer
      第40回固体イオニクス討論会
    • Place of Presentation
      東京工業大学, 東京都
    • Year and Date
      2014-11-18
    • Related Report
      2014 Annual Research Report
  • [Presentation] ペロブスカイト型酸化物を検知極とした新規ジルコニア酸素センサ2014

    • Author(s)
      飯尾 歩美, 池田 弘, 三浦 則雄
    • Organizer
      第57回化学センサ研究発表会
    • Place of Presentation
      北海道大学, 札幌市
    • Year and Date
      2014-09-27
    • Related Report
      2014 Annual Research Report
  • [Presentation] Au/Ta2O5検知極を用いた混成電位型ジルコニアセンサの水素検知特性2014

    • Author(s)
      一川 莉乃, Sri Ayu Anggraini, 池田 弘, 三浦 則雄
    • Organizer
      第57回化学センサ研究発表会
    • Place of Presentation
      北海道大学, 札幌市
    • Year and Date
      2014-09-27
    • Related Report
      2014 Annual Research Report
  • [Presentation] YSZにAu/Ta2O5検知極を付加した固体電気化学式水素センサ2014

    • Author(s)
      一川莉乃, Sri Ayu Anggraini, 池田 弘, 三浦 則雄
    • Organizer
      第51回化学関連支部合同九州大会
    • Place of Presentation
      北九州国際会議場, 北九州市
    • Year and Date
      2014-06-28
    • Related Report
      2014 Annual Research Report
  • [Presentation] 酸化物系新規検知極材料を用いたジルコニア酸素センサの特性評価2014

    • Author(s)
      飯尾歩美, 池田 弘, 三浦 則雄
    • Organizer
      第51回化学関連支部合同九州大会
    • Place of Presentation
      北九州国際会議場, 北九州市
    • Year and Date
      2014-06-28
    • Related Report
      2014 Annual Research Report
  • [Presentation] Stabilization process acceleration during the aging of YSZ-based H2 sensor2014

    • Author(s)
      Sri Ayu Anggraini, 池田 弘, 三浦 則雄
    • Organizer
      第51回化学関連支部合同九州大会
    • Place of Presentation
      北九州国際会議場, 北九州市
    • Year and Date
      2014-06-28
    • Related Report
      2014 Annual Research Report
  • [Presentation] ディップコート法による酸化物検知極を用いたジルコニアセンサの炭化水素検知特性2014

    • Author(s)
      和田 信利, 佐藤 伴光, 池田 弘, 三浦 則雄
    • Organizer
      第52回セラミックス基礎科学討論会
    • Place of Presentation
      ウインクあいち, 名古屋市
    • Related Report
      2013 Annual Research Report
  • [Presentation] Zirconia-based gas sensor using carbon sensing-electrode for sensitive and selective detection of NOx2014

    • Author(s)
      Tmoaki Sato, Hiroshi Ikeda, Norio Miura
    • Organizer
      15th international meeting on chemical sensors
    • Place of Presentation
      The Convention Center of UCA, Buenos Aires, Argentina
    • Related Report
      2013 Annual Research Report
  • [Presentation] ペロブスカイト型酸化物を検知極としたジルコニア酸素センサ2014

    • Author(s)
      飯尾 歩美, 池田 弘, 三浦 則雄
    • Organizer
      第56回化学センサ研究発表会
    • Place of Presentation
      関西大学, 大阪府
    • Related Report
      2013 Annual Research Report
  • [Presentation] Acceleration of Stabilization Process for YSZ-based Highly-selective H2 sensor using Zn-Ta-O-based Sensing Electrode2014

    • Author(s)
      Anggraini Sri Ayu, Hiroshi Ikeda, Norio Miura
    • Organizer
      第56回化学センサ研究発表会
    • Place of Presentation
      関西大学, 大阪府
    • Related Report
      2013 Annual Research Report
  • [Presentation] Effect of Pd Addition to Rod-shaped TiO2 Sensing Electrode on Hydrocarbon Sensing Performance of Zirconia-based Gas Sensor2013

    • Author(s)
      Yuki Fujio, Tomoaki Sato, Norio Miura
    • Organizer
      The 19th International Conference on Solid State Ionics
    • Place of Presentation
      京都国際会議場, 京都市
    • Related Report
      2013 Annual Research Report
  • [Presentation] Effect of Aging on Sensing Performance of YSZ-based H2 Sensor Using Zn-Ta-based Oxide as Sensing Electrode2013

    • Author(s)
      Sri Ayu Anggraini, Michael Breedon, Norio Miura
    • Organizer
      The 19th International Conference on Solid State Ionics
    • Place of Presentation
      京都国際会議場, 京都市
    • Related Report
      2013 Annual Research Report
  • [Presentation] ディップコート法で形成した酸化物検知極を用いたジルコニア系炭化水素センサ2013

    • Author(s)
      和田信利, 佐藤伴光, Norio Miura
    • Organizer
      第50回化学関連支部合同九州大会
    • Place of Presentation
      北九州国際会議場, 北九州市
    • Related Report
      2013 Annual Research Report
  • [Presentation] Influence of Aging Process in Enhancing Sensitivity and Selectivity Toward H2 for YSZ-based Sensor Using Zn-Ta-O-based Oxide Sensing-electrode2013

    • Author(s)
      Sri Ayu Anggraini, Norio Miura
    • Organizer
      第50回化学関連支部合同九州大会
    • Place of Presentation
      北九州国際会議場, 北九州市
    • Related Report
      2013 Annual Research Report
  • [Presentation] ジルコニアセンサの新規固体参照極用酸化物系電極の特性評価2013

    • Author(s)
      田中裕己, Han Jin, Norio Miura
    • Organizer
      第50回化学関連支部合同九州大会
    • Place of Presentation
      北九州国際会議場, 北九州市
    • Related Report
      2013 Annual Research Report
  • [Presentation] 緻密な金属酸化物ディスクを検知極としたジルコニアセンサのガス検知特性2013

    • Author(s)
      佐藤伴光, Norio Miura
    • Organizer
      第50回化学関連支部合同九州大会
    • Place of Presentation
      北九州国際会議場, 北九州市
    • Related Report
      2013 Annual Research Report
  • [Presentation] Aging Impact on H2 Sensing Characteristic for Zirconia-based Sensor Using Zn-Ta-O Sensing Electrode2013

    • Author(s)
      Sri Ayu Anggraini, Hiroshi Ikeda, Norio Miura
    • Organizer
      第55回化学センサ研究発表会
    • Place of Presentation
      東京工業大学, 東京都
    • Related Report
      2013 Annual Research Report
  • [Presentation] 酸化物/YSZ界面へのAuスパッタによるガス検知特性への影響2013

    • Author(s)
      佐藤 伴光, 池田 弘, 三浦 則雄
    • Organizer
      第55回化学センサ研究発表会
    • Place of Presentation
      東京工業大学, 東京都
    • Related Report
      2013 Annual Research Report
  • [Presentation] Aging Phenomena of YSZ-based H2 Sensor Utilizing Zn-Ta-O Oxide Sensing Electrode2013

    • Author(s)
      Sri Ayu Anggraini, Hiroshi Ikeda, Norio Miura
    • Organizer
      The 10th Asian Conference on Chemical Sensors
    • Place of Presentation
      The Empress Hotel, Chiang Mai, Thailand
    • Related Report
      2013 Annual Research Report
  • [Presentation] Gas Sensing Characteristics of Zirconia-based Sensor Using SnO2/Au Sensing-electrode2013

    • Author(s)
      Tomoaki Sato, Hiroshi Ikeda, Norio Miura
    • Organizer
      The 10th Asian Conference on Chemical Sensors
    • Place of Presentation
      The Empress Hotel, Chiang Mai, Thailand
    • Related Report
      2013 Annual Research Report
  • [Presentation] 酸化物系材料を用いたYSZセンサ用新規個体参照極2013

    • Author(s)
      田中 裕己, 佐藤 伴光, 池田 弘, 三浦 則雄
    • Organizer
      第39回固体イオニクス討論会
    • Place of Presentation
      くまもと県民交流館パレア, 熊本市
    • Related Report
      2013 Annual Research Report

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Published: 2013-05-21   Modified: 2019-07-29  

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