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Direct formation of the high-quality nanowire Si from metallurgical Si source based on the plasma and nanotechnology science

Research Project

Project/Area Number 25289016
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Production engineering/Processing studies
Research InstitutionOsaka University

Principal Investigator

Ohmi Hiromasa  大阪大学, 工学(系)研究科(研究院), 助教 (00335382)

Co-Investigator(Kenkyū-buntansha) YASUTAKE Kiyoshi  大阪大学, 大学院工学研究科, 教授 (80166503)
Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥17,420,000 (Direct Cost: ¥13,400,000、Indirect Cost: ¥4,020,000)
Fiscal Year 2015: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2014: ¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2013: ¥8,190,000 (Direct Cost: ¥6,300,000、Indirect Cost: ¥1,890,000)
Keywordsナノワイヤ / シリコン / 太陽電池 / プラズマ / 水素 / 精製 / ナノマイクロ加工 / 精製プロセス
Outline of Final Research Achievements

Toward the improvement of conversion efficiency and the reduction of production cost of solar cell, we have achieved the formation of nanowire Si (NW-Si) film by atmospheric pressure plasma enhanced chemical transport technique which can chemically prepare the Si film without toxic and dangerous source gases, such as SiH4. In particular, it was founded that the type of catalyst metal, the suppression of atomic hydrogen etching, and the optimization of Si precursor flux are required to prepare the NW-Si film in the high density hydrogen plasma. Furthermore, the formation of NW-Si film from metallurgical Si source was achieved by remote type plasma enhanced chemical transport technique.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • Research Products

    (17 results)

All 2015 2014 2013

All Journal Article (1 results) (of which Peer Reviewed: 1 results,  Acknowledgement Compliant: 1 results) Presentation (14 results) (of which Int'l Joint Research: 2 results,  Invited: 1 results) Book (1 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Selective deposition of a crystalline Si film by a chemical sputtering process in a high pressure hydrogen plasma2015

    • Author(s)
      Hiromasa Ohmi, Hiroaki Kakiuchi, and Kiyoshi Yasutake
    • Journal Title

      Journal of Applied Physics

      Volume: 118 Issue: 4 Pages: 045301-045301

    • DOI

      10.1063/1.4926849

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] Impact of catalytic metal element on silicon nanowire growth by high-pressure hydrogen plasma chemical transport2015

    • Author(s)
      H. Takemoto, Y. Ishikawa, H. Kakiuchi, K. Yasutake and H. Ohmi
    • Organizer
      TACT 2015 International Thin Films Conference
    • Place of Presentation
      National Cheng Kung University, Tainan, Taiwan
    • Year and Date
      2015-11-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 高圧水素プラズマ化学輸送法によるシリコンナノワイヤ形成における金属触媒の影響2015

    • Author(s)
      竹本啓輝,垣内弘章,安武潔,大参宏昌
    • Organizer
      第76回 応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋国際会議場
    • Year and Date
      2015-09-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] 準大気圧雰囲気での水素プラズマ化学輸送法を用いたシリコンナノワイヤの形成2015

    • Author(s)
      竹本啓輝,垣内弘章,安武潔,大参宏昌
    • Organizer
      精密工学会 2015年度関西地方定期学術講演会
    • Place of Presentation
      京都工芸繊維大学
    • Year and Date
      2015-06-23
    • Related Report
      2015 Annual Research Report
  • [Presentation] Nucleation for Si film selective growth using GeO2 solution and high-pressure plasma2015

    • Author(s)
      Hiromasa Ohmi, Akihiro Goto, Yuji Onoshita, Hiroaki Kakiuchi, Kiyoshi Yasutake
    • Organizer
      20th international colloquium of plasma processes
    • Place of Presentation
      Saint-Etienne, France
    • Year and Date
      2015-06-01
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 低純度Si精製に向けたジボラン(B2H6)選択除去手法の開発とその特性評価2014

    • Author(s)
      大参宏昌,垣内弘章,安武潔
    • Organizer
      第75回 応用物理学会秋季学術講演会
    • Place of Presentation
      北海道大学
    • Year and Date
      2014-09-17 – 2014-09-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] 水素プラズマによる金属の蒸発促進と高速成膜への応用2014

    • Author(s)
      大参宏昌,垣内弘章,安武潔
    • Organizer
      第75回 応用物理学会秋季学術講演会
    • Place of Presentation
      北海道大学
    • Year and Date
      2014-09-17 – 2014-09-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] SiH4 conversion rate in Si etching reaction induced by high-pressure hydrogen plasma2014

    • Author(s)
      Hiromasa Ohmi, Hiroaki Kakiuchi, and Kiyoshi Yasutake
    • Organizer
      13th European Vacuum Conference
    • Place of Presentation
      Aveiro, Portugal
    • Year and Date
      2014-09-08 – 2014-09-12
    • Related Report
      2014 Annual Research Report
  • [Presentation] 大気圧近傍の非平衡水素プラズマを用いた材料変換プロセスの開発2014

    • Author(s)
      大参宏昌
    • Organizer
      第68回マテルアルズ・テーラリング研究会
    • Place of Presentation
      軽井沢研修所
    • Year and Date
      2014-07-24 – 2014-07-26
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Boron Elimination Filter from SiH4 and B2H6 Gas Mixture for Purification of Metallurgical Si2014

    • Author(s)
      H. Ohmi, H. Kakiuchi, and K. Yasutake
    • Organizer
      225th ECS Meeting
    • Place of Presentation
      Orlando, FL, USA
    • Year and Date
      2014-05-11 – 2014-05-15
    • Related Report
      2014 Annual Research Report
  • [Presentation] 高圧水素プラズマによる液体金属の蒸発促進と金属膜の超高速形成2014

    • Author(s)
      大参宏昌,垣内弘章,安武潔
    • Organizer
      2014年度 精密工学会春季大会学術講演会
    • Place of Presentation
      東京
    • Related Report
      2013 Annual Research Report
  • [Presentation] 水素プラズマ化学輸送法によるシリコンナノワイヤ成長2014

    • Author(s)
      石川祥博,垣内弘章,安武潔,大参宏昌
    • Organizer
      2014年度 精密工学会春季大会学術講演会
    • Place of Presentation
      東京
    • Related Report
      2013 Annual Research Report
  • [Presentation] selective formation of silicon film by chemical transport technique using a high-pressure narrow-gap hydrogen plasma2013

    • Author(s)
      H.Ohmi, H. Kakiuchi, K. Yasutake
    • Organizer
      19th International Vacuum Congress IVC-19
    • Place of Presentation
      Paris, France
    • Related Report
      2013 Annual Research Report
  • [Presentation] Printable formation of Ge film using a GeO2 solution by high-pressure hydrogen plasma reduction treatment2013

    • Author(s)
      H.Ohmi, H. Kakiuchi, K. Yasutake
    • Organizer
      TACT 2013 International Thin Films Conference
    • Place of Presentation
      Taipei,Taiwan
    • Related Report
      2013 Annual Research Report
  • [Presentation] 水溶性Geを用いたプリンタブル核形成処理による選択的Si膜形成技術の開発2013

    • Author(s)
      石川祥博,垣内弘章,安武潔,大参宏昌
    • Organizer
      精密工学会 2013年度関西地方定期学術講演会
    • Place of Presentation
      大阪
    • Related Report
      2013 Annual Research Report
  • [Book] 超精密加工と表面科学 -原子レベルの生産技術-「大気圧プラズマ化学輸送法」2014

    • Author(s)
      大参宏昌
    • Total Pages
      9
    • Publisher
      大阪大学出版会
    • Related Report
      2014 Annual Research Report
  • [Patent(Industrial Property Rights)] 成膜方法および成膜装置2013

    • Inventor(s)
      大参宏昌
    • Industrial Property Rights Holder
      大阪大学
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2013-215103
    • Filing Date
      2013-10-15
    • Related Report
      2013 Annual Research Report

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Published: 2013-05-21   Modified: 2019-07-29  

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