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Study on high-speed doping mechanism of wet laser processing

Research Project

Project/Area Number 25289105
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Electron device/Electronic equipment
Research InstitutionKyushu University

Principal Investigator

ASANO Tanemasa  九州大学, システム情報科学研究科(研究院, 教授 (50126306)

Co-Investigator(Renkei-kenkyūsha) IKENOUE Hiroshi  九州大学, 大学院システム情報科学研究院, 准教授 (70413862)
IKEDA Akihiro  九州大学, 大学院システム情報科学研究院, 助教 (60315124)
Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥17,680,000 (Direct Cost: ¥13,600,000、Indirect Cost: ¥4,080,000)
Fiscal Year 2015: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Fiscal Year 2014: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2013: ¥9,880,000 (Direct Cost: ¥7,600,000、Indirect Cost: ¥2,280,000)
Keywords炭化シリコン / SiC / レーザープロセッシング / レーザードーピング / 液中レーザー / JBSダイオード / オーミック接触 / パワーデバイス / JBS / 電力用半導体素子 / ドーピング / 4H-SiC
Outline of Final Research Achievements

A new method to dope impurity atoms to silicon carbide (SiC), which is the most promising wide-band gap semiconductor, has been developed. The method uses laser irradiation to SiC immersed in a liquid which contain impurity atoms. Phosphorus, nitrogen, aluminum were found to be doped by irradiating laser in phosphoric acid, liquid nitrogen, and aqueous solution of aluminum chloride, respectively. Doping of Al from laser produce molten Al on the surface of SiC has also been found to effective to obtain a highly doped, deep junction p-type layer.The method has been demonstrated to be able to apply to fabrication of pn junction diode and JBS diode. Formation of low resistance contacts to SiC has been also demonstrated.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • Research Products

    (27 results)

All 2016 2015 2014 2013 Other

All Journal Article (8 results) (of which Peer Reviewed: 8 results,  Acknowledgement Compliant: 5 results) Presentation (14 results) (of which Int'l Joint Research: 3 results) Remarks (2 results) Patent(Industrial Property Rights) (3 results) (of which Overseas: 1 results)

  • [Journal Article] Al Doping from Laser Irradiated Al Film Deposited on 4H-SiC2016

    • Author(s)
      A. Ikeda, R.Sumina, H. Ikenoue, T. Asano
    • Journal Title

      Material Science Forum

      Volume: 824

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Al doping of 4H-SiC by laser irradiation to coated Al film and its application2016

    • Author(s)
      A. Ikeda, R.Sumina, H. Ikenoue, T. Asano
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 55 Issue: 4S Pages: 04ER07-04ER07

    • DOI

      10.7567/jjap.55.04er07

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Extremely Enhanced Diffusion of Nitrogen in 4H-SiC Observed in Liquid-Nitrogen Immersion Irradiation of Excimer Laser2016

    • Author(s)
      A. Ikeda, D. Marui, H. Ikenoue, T. Asano
    • Journal Title

      Material Science Forum

      Volume: 821-823 Pages: 448-445

    • DOI

      10.4028/www.scientific.net/msf.821-823.448

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Nitrogen doping of 4H-SiC by KrF excimer laser irradiation in liquid nitrogen2015

    • Author(s)
      A. Ikeda, D. Marui, H. Ikenoue, T. Asano
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 54 Issue: 4S Pages: 04DP02-04DP02

    • DOI

      10.7567/jjap.54.04dp02

    • NAID

      210000145089

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Aluminum doping of 4H-SiC by irradiation of excimer laser in aluminum chloride solution2014

    • Author(s)
      D. Marui, A. Ikeda, K. Nishi, H. Ikenoue, T. Asano
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 53 Issue: 6S Pages: 06JF03-06JF03

    • DOI

      10.7567/jjap.53.06jf03

    • NAID

      210000144101

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Formation of pn junction in 4H-SiC by irradiation of excimer laser in phosphoric solution2014

    • Author(s)
      D. Marui, K. Nishi, A. Ikeda, H. Ikenoue, T. Asano
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 53

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] n- and p-type doping of 4H-SiC by wet-chemical laser processing2014

    • Author(s)
      K. Nishi, A. Ikeda, D. Marui, H. Ikenoue, T. Asano
    • Journal Title

      Materials Science Forum

      Volume: 778-780 Pages: 645-648

    • DOI

      10.4028/www.scientific.net/msf.778-780.645

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Phosphorus Doping into 4H-SiC by Irradiation of Excimer Laser in Phosphoric Solution2013

    • Author(s)
      K. Nishi, A. Ikeda, D. Marui, H. Ikenoue, T. Asano
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 52 Issue: 6S Pages: 06GF02-06GF02

    • DOI

      10.7567/jjap.52.06gf02

    • NAID

      210000142360

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Presentation] 堆積薄膜へのレーザ照射による4H-SiCへのAlのドーピング特性2016

    • Author(s)
      角名 陸歩, 池田 晃裕, 池上 浩, 浅野 種正
    • Organizer
      第63回応用物理学会春季学術講演会
    • Place of Presentation
      東京
    • Year and Date
      2016-03-21
    • Related Report
      2015 Annual Research Report
  • [Presentation] SiNx膜レーザーアブレーションによる4H-SiCへの窒素ドーピングと窒素拡散機構に関する研究2016

    • Author(s)
      小島 遼太, 池上 浩, 諏訪 輝, 池田 晃裕, 中村 大輔, 浅野 種正, 岡田 龍雄
    • Organizer
      第63回応用物理学会春季学術講演会
    • Place of Presentation
      東京
    • Year and Date
      2016-03-21
    • Related Report
      2015 Annual Research Report
  • [Presentation] Improvement in contact resistance of 4H-SiC by excimer laser doping using silicon nitride films2016

    • Author(s)
      R. Kojima, H. Ikenoue, T. Suwa, A. Ikeda, Daisuke Nakamura, T. Asano, Tatsuo Okada
    • Organizer
      SPIE Photonics West
    • Place of Presentation
      San Francisco
    • Year and Date
      2016-02-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] SiNx膜レーザーアブレーションによる4H-SiCへの窒素ドーピング及び電気特性評価2016

    • Author(s)
      小島 遼太, 池上 浩, 諏訪 輝, 池田 晃裕, 中村 大輔, 浅野 種正, 岡田 龍雄
    • Organizer
      レーザー学会学術講演会第 36 回年次大会
    • Place of Presentation
      名古屋
    • Year and Date
      2016-01-10
    • Related Report
      2015 Annual Research Report
  • [Presentation] 堆積Al薄膜へのレーザー照射による4H-SiCへのAlドーピング2015

    • Author(s)
      角名 陸歩, 池田 晃裕, 浅野 種正
    • Organizer
      薄膜材料デバイス研究会
    • Place of Presentation
      京都
    • Year and Date
      2015-10-30
    • Related Report
      2015 Annual Research Report
  • [Presentation] Al doping from laser irradiated Al film deposited on 4H‐SiC2015

    • Author(s)
      A. Ikeda, R. Sumina, H. Ikenoue, T. Asano
    • Organizer
      16th International Conference on Silicon Carbide and Related Materials
    • Place of Presentation
      Giardini Naxos
    • Year and Date
      2015-10-05
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Al Doping of 4H-SiC by Laser Irradiation to Coated Film and Its Application to Junction Barrier Schottky Diode2015

    • Author(s)
      A. Ikeda, R. Sumina, H. Ikenoue, T. Asano
    • Organizer
      Int. Conf. Solid State Devices and Materials
    • Place of Presentation
      札幌
    • Year and Date
      2015-09-28
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Local nitrogen doping in 4H-SiC by laser irradiation in atmospheric-pressure plasma2015

    • Author(s)
      R. Kojima, H. Ikenoue, Yosuke Watanabe, A. Ikeda, Daisuke Nakamura, T. Asano, T. Okada
    • Organizer
      SPIE Photonics West
    • Place of Presentation
      サンフランシスコ
    • Year and Date
      2015-02-11
    • Related Report
      2014 Annual Research Report
  • [Presentation] Extremely Enhanced Diffusion of Nitrogen in 4H-SiC Observed in Liquid-Nitrogen Immersion Irradiation of Excimer Laser2014

    • Author(s)
      A. Ikeda, D. Marui, H. Ikenoue, T. Asano
    • Organizer
      10th European Conference on Silicon Carbide and Related Materials
    • Place of Presentation
      グルノーブル
    • Year and Date
      2014-09-22
    • Related Report
      2014 Annual Research Report
  • [Presentation] Nitrogen doping of 4H-SiC by excimer laser irradiation in liquid nitrogen2014

    • Author(s)
      A. Ikeda, D. Marui, H. Ikenoue, T. Asano
    • Organizer
      2014 Int'l. Conf. Solid State Devices and Materials
    • Place of Presentation
      つくば市
    • Year and Date
      2014-09-09
    • Related Report
      2014 Annual Research Report
  • [Presentation] Characteristic of pn Junction Formed in 4H-SiC by using Excimer-laser Processing in Phosphoric Solution

    • Author(s)
      A. Ikeda, K. Nishi, D. Marui, H. Ikenoue, T. Asano
    • Organizer
      13th International Workshop on Junction Technology
    • Place of Presentation
      Kyoto
    • Related Report
      2013 Annual Research Report
  • [Presentation] Formation of pn junction in 4H-SiC by irradiation of excimer laser in phosphoric solution

    • Author(s)
      K. Nishi, A. Ikeda, D. Marui, H. Ikenoue, T. Asano
    • Organizer
      2013 Asia-Pacific Workshop on Fundamentals and Applications of Advanced Semiconductor Devices
    • Place of Presentation
      Seoul
    • Related Report
      2013 Annual Research Report
  • [Presentation] n- and p-type doping of 4H-SiC by wet-chemical laser processing

    • Author(s)
      K. Nishi, A. Ikeda, D. Marui, H. Ikenoue, T. Asano
    • Organizer
      International Conference on Silicon Carbide and Related Materials 2013
    • Place of Presentation
      Miyazaki
    • Related Report
      2013 Annual Research Report
  • [Presentation] Aluminum Doping of 4H-SiC using Chemical Wet Laser Processing

    • Author(s)
      D. Marui, K. Nishi, A. Ikeda, H. Ikenoue, T. Asano
    • Organizer
      26th International Microprocesses and Nanotechnology Conference
    • Place of Presentation
      Sapporo
    • Related Report
      2013 Annual Research Report
  • [Remarks] 九州大学研究者情報

    • URL

      http://hyoka.ofc.kyushu-u.ac.jp/search/details/K002917/index.html

    • Related Report
      2015 Annual Research Report 2014 Annual Research Report
  • [Remarks] 研究者情報

    • URL

      http://hyoka.ofc.kyushu-u.ac.jp/search/details/K002917/index.html

    • Related Report
      2013 Annual Research Report
  • [Patent(Industrial Property Rights)] 不純物導入装置、不純物導入方法及び半導体素子の製造方法2015

    • Inventor(s)
      池田晃裕,池上浩,浅野種正 井口研一,中澤治雄,関康和
    • Industrial Property Rights Holder
      富士電機,九州大学
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2015-035615
    • Filing Date
      2015-02-25
    • Related Report
      2014 Annual Research Report
  • [Patent(Industrial Property Rights)] レーザドーピング装置及びレーザドーピング方法2015

    • Inventor(s)
      大久保智幸,池上浩,池田晃裕,浅野種正,若林理
    • Industrial Property Rights Holder
      ギガフォトン,九州大学
    • Industrial Property Rights Type
      特許
    • Filing Date
      2015-03-30
    • Related Report
      2014 Annual Research Report
    • Overseas
  • [Patent(Industrial Property Rights)] 不純物導入方法及び半導体素子の製造方法2014

    • Inventor(s)
      池上浩,池田晃裕,浅野種正 井口研一、中澤治雄、関康和、松村徹
    • Industrial Property Rights Holder
      富士電機,九州大学
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2014-174567
    • Filing Date
      2014-08-28
    • Related Report
      2014 Annual Research Report

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Published: 2013-05-21   Modified: 2019-07-29  

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