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Phase equilibria and thermodynamic analysis of anomalous microstructure formation at low temperatures by heavy deformation and heat treatment processes

Research Project

Project/Area Number 25289216
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Physical properties of metals/Metal-base materials
Research InstitutionNational Institute for Materials Science (2015)
Tohoku University

Principal Investigator

OHNUMA IKUO  国立研究開発法人物質・材料研究機構, 理論計算科学ユニット, 主席研究員 (20250714)

Co-Investigator(Kenkyū-buntansha) ISHIDA Kiyohito  東北大学, 工学研究科, 名誉教授 (20151368)
Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥18,460,000 (Direct Cost: ¥14,200,000、Indirect Cost: ¥4,260,000)
Fiscal Year 2015: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2014: ¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2013: ¥7,410,000 (Direct Cost: ¥5,700,000、Indirect Cost: ¥1,710,000)
Keywords相平衡 / 相変態 / CALPHAD / 鉄鋼材料 / 組織制御 / 状態図 / 熱力学 / 金属間化合物 / 整合・非整合
Outline of Final Research Achievements

Fe-Mn and Fe-Ni alloys, which are important systems for steel materials, were powdered by a gas-atomize method. Then, the powder samples were severely deformed by a converge milling process and heat-treated at temperatures between 700℃ and 450℃ (below the melting point of pure iron) to obtain the γ(fcc)+α(bcc) microstructure. Equilibrium compositions of the γ and α phases at low temperatures were measured by FE-EPMA. As a result, it is suggested that the solubility of Mn and Ni in the αFe at temperatures below 600℃ is larger than that in the literature. Similar experiments were performed on the Fe-Al binary alloys to obtain A2/B2/D03 order-disorder immiscible microstructures. As a result, it is suggested that equilibrium compositions among A2, B2 and D03 phases depend on the coherency at the inter-phase boundaries. Al-rich portion of the phase diagram of the Fe-Al binary system was also determined in this research subject.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • Research Products

    (10 results)

All 2016 2015 2014

All Journal Article (1 results) (of which Peer Reviewed: 1 results) Presentation (9 results) (of which Int'l Joint Research: 3 results,  Invited: 1 results)

  • [Journal Article] Experimental determination of phase equilibria of Al-rich portion in the Al-Fe binary system2016

    • Author(s)
      Kwangsik Han, Ikuo Ohnuma and Ryosuke Kainuma
    • Journal Title

      Journal of Alloys and Compounds

      Volume: 668 Pages: 97-106

    • DOI

      10.1016/j.jallcom.2016.01.215

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Presentation] Experimental Determination of Phase Equilibria in the Al-rich Portion of the Al-Fe Binary System2016

    • Author(s)
      Ikuo Ohnuma
    • Organizer
      TOFA2016
    • Place of Presentation
      Santos, Brazil
    • Year and Date
      2016-09-04
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Experimental Determination of Phase Diagram of the Zn-Fe Binary System2016

    • Author(s)
      Kwangsik Han
    • Organizer
      CALPHAD XLV
    • Place of Presentation
      淡路市,兵庫
    • Year and Date
      2016-05-29
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Experimental Determination of Phase Equilibria in the Al-rich Portion of the Al-Fe Binary System2016

    • Author(s)
      Kwangsik Han
    • Organizer
      日本金属学会2016年春期講演大会
    • Place of Presentation
      東京理科大学,東京
    • Year and Date
      2016-03-23
    • Related Report
      2015 Annual Research Report
  • [Presentation] Experimental Investigation of Miscibility Gap between Antiferromagnetic and Paramagnetic Phases in the NiMn-NiZn Pseudo-Binary System2015

    • Author(s)
      Ikuo Ohnuma
    • Organizer
      CALPHAD XLIV
    • Place of Presentation
      Luana, Italy
    • Year and Date
      2015-05-31
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Fe-Al2元系におけるBCC相の相分離組織形成と相平衡2014

    • Author(s)
      大沼郁雄
    • Organizer
      日本学術振興会合金状態図第172委員会
    • Place of Presentation
      名古屋大学, 名古屋
    • Year and Date
      2014-10-28 – 2014-10-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] Fe-C-Ni系炭素組成傾斜拡散対におけるγ/α変態と局所平衡2014

    • Author(s)
      中川 卓也, 大沼 郁雄
    • Organizer
      日本鉄鋼協会第168回秋季講演大会
    • Place of Presentation
      名古屋大学, 名古屋
    • Year and Date
      2014-09-24 – 2014-09-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] γ/α transformation behaviors in C composition gradient diffusion couples in the Fe-C-Mn system2014

    • Author(s)
      Takuya Nakagawa, Ikuo Ohnuma
    • Organizer
      TOFA2014
    • Place of Presentation
      Brno, Czech Republic
    • Year and Date
      2014-09-08 – 2014-09-11
    • Related Report
      2014 Annual Research Report
  • [Presentation] γ/α transformation behaviors in C composition gradient diffusion couples in the Fe-C-Mn system2014

    • Author(s)
      Ikuo Ohnuma
    • Organizer
      TMS2014
    • Place of Presentation
      米国サンディエゴ
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] γ/α transformation behaviors in C composition gradient diffusion couples in the Fe-C-Ni system2014

    • Author(s)
      Ikuo Ohnuma
    • Organizer
      ALEMI2015
    • Place of Presentation
      京都
    • Related Report
      2013 Annual Research Report

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Published: 2013-05-21   Modified: 2019-07-29  

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