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High resolution in-situ observation and analysis of atomic behavior in gold nanorods induced by irradiation with infrared laser pulses

Research Project

Project/Area Number 25289221
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Physical properties of metals/Metal-base materials
Research InstitutionKyushu University

Principal Investigator

Matsumura Syo  九州大学, 工学(系)研究科(研究院), 教授 (60150520)

Co-Investigator(Renkei-kenkyūsha) YASUDA KAZUHIRO  九州大学, 大学院工学研究院, 准教授 (80253491)
Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥18,070,000 (Direct Cost: ¥13,900,000、Indirect Cost: ¥4,170,000)
Fiscal Year 2015: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2014: ¥13,650,000 (Direct Cost: ¥10,500,000、Indirect Cost: ¥3,150,000)
Fiscal Year 2013: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywordsナノ材料 / プラズモニクス / レーザー光 / 高分解能電子顕微鏡 / その場観察 / 原子変位 / 多重双晶粒子
Outline of Final Research Achievements

This study aimed at promoting our understanding of atomic behaviors in gold nanorods under illumination of infrared laser pulses, taking advantage of in-situ high voltage electron microscopy (HVEM) as well as aberration-corrected scanning transmission electron microscopy (STEM). The wavelength of laser pulses was 1064 nm. The single crystalline nanorods was gradually deformed to be a barrel-like shape with {001} and {111} habit surfaces with the number of pulses illuminated when the averaged intensity per pulse was 410 J/m2. If the intensity was twice enhanced to be 820 J/m2, the deformation was much accelerated, and some nanorods were transformed to be multiple twinned particles. Drift-compensated high-angle annular dark field (HAADF) STEM images showed so high precision in locating the atomic columns as ±4 pm. In a deformed twinned particle, substantial displacements of atomic columns on the order of several tens of picometers were localized around multiple twin junctions.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • Research Products

    (17 results)

All 2016 2015 2014 2013

All Journal Article (5 results) (of which Peer Reviewed: 3 results,  Acknowledgement Compliant: 1 results) Presentation (12 results) (of which Int'l Joint Research: 1 results,  Invited: 4 results)

  • [Journal Article] Detection of picometer-order atomic displacements in drift-compesated HAADF-STEM images of gold nanorods2016

    • Author(s)
      K. Aso, K. Shigematsu, T. Yamamoto, S. Matsumura
    • Journal Title

      Microscopy

      Volume: 65

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] An attempt of drift correction and noise reduction of STEM image by using multiple images with a short scanning time2015

    • Author(s)
      K. Shigematsu, K. Aso, T. Yamamoto, K. Yasuda, S. Matsumura
    • Journal Title

      Annual Reports of the Ultramicroscopy Research Center Kyushu University

      Volume: 39 Pages: 30-31

    • Related Report
      2015 Annual Research Report
  • [Journal Article] パルスレーザー照射に伴う金ナノロッド構造変化の高分解能「その場」観察2015

    • Author(s)
      麻生浩平, 重松晃次, 山本知一, 安田和弘, 松村 晶
    • Journal Title

      Annual Reports of the Ultramicroscopy Research Center Kyushu University

      Volume: 39 Pages: 68-69

    • Related Report
      2015 Annual Research Report
  • [Journal Article] In situ observation of structural transformation of gold nanorods under pulsed laser irradiation in an HVEM2014

    • Author(s)
      Nao Sumimoto, Koichiro Nakao, Tomokazu Yamamoto, Kazuhiro Yasuda, Syo Matsumura, and Yasuro Niidome
    • Journal Title

      Microscopy

      Volume: 63 Issue: 4 Pages: 261-268

    • DOI

      10.1093/jmicro/dfu012

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] In-situ observation of structural transformation of gold nano rods under pulsed laser irradiation in an HVEM2014

    • Author(s)
      N. Sumimoto, K. Nakao, T. Yamamoto, K. Yasuda, S. Matsumura, Y. Niidome
    • Journal Title

      Microscopy

      Volume: 63

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Presentation] ナノ秒パレスレーザー光照射に伴う金ナノロッド状態変化の高分解能観察2015

    • Author(s)
      麻生 浩平, 重松 晃次, 山本 知一, 前野 宏志, 安田 和弘, 松村 晶
    • Organizer
      第57回日本顕微鏡学会九州支部総会・学術講演会
    • Place of Presentation
      九州大学
    • Year and Date
      2015-11-21
    • Related Report
      2015 Annual Research Report
  • [Presentation] パルスレーザー光照射下での金ナノロッド変形挙動の高分解能「その場」観察2015

    • Author(s)
      重松 晃次, 麻生 浩平, 山本 知一, 安田 和弘, 松村 晶
    • Organizer
      日本金属学会秋期講演大会2015
    • Place of Presentation
      九州大学
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] Advanced electron microscopy for structural analysis of nanoparticles2015

    • Author(s)
      Syo Matsmura
    • Organizer
      Japan-Spain Joint Symposium on Heterogeneous Catalysis
    • Place of Presentation
      カタルーニャ化学研究所
    • Year and Date
      2015-06-21
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] パルスレーザー光照射した金ナノロッドの原子分解能観察2015

    • Author(s)
      重松 晃次,麻生 浩平,山本 知一,安田 和弘,松村 晶
    • Organizer
      日本金属学会九州支部平成27年度合同学術講演会
    • Place of Presentation
      北九州国際会議場
    • Year and Date
      2015-06-06
    • Related Report
      2015 Annual Research Report
  • [Presentation] In-situ HVEM and HREM observation of structural changes of gold nanorods under infrared pulsed laser irradiation2015

    • Author(s)
      Syo Matsumura
    • Organizer
      International Symposium on New Movements of Electron Microscopy for the Next Generation
    • Place of Presentation
      Naogoya university, Nagoya, Japan
    • Year and Date
      2015-03-05
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] In-situ HVEM observation of structural changes of gold nanorods under near infrared pulsed laser irradiation2014

    • Author(s)
      Syo Matsumura, Nao Sumimoto, Tomokazu Yamamoto, Kazuhiro Yasuda
    • Organizer
      10th Japanese-Polish Joint Seminar on Micro and Nano Analysis
    • Place of Presentation
      Hokkaido university, Sapporo, Japan
    • Year and Date
      2014-10-24 – 2014-10-26
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] In-situ observation of morphological changes of gold nanorods under near infrared pulsed laser irradiation2014

    • Author(s)
      Syo Matsumura, Nao Sumimoto, Tomokazu Yamamoto, Kazuhiro Yasuda, Yasuro Niidome
    • Organizer
      18th International Microscopy Congress
    • Place of Presentation
      The Prague Congress Centre, Prague, Czech Republic
    • Year and Date
      2014-09-07 – 2014-09-12
    • Related Report
      2014 Annual Research Report
  • [Presentation] In-Situ High Resolution Electron Microscope Observation of Gold Nanorods under Irradiation with Near Infrared Pulsed Laser Light2014

    • Author(s)
      Syo Matsumura, Nao Sumimoto, Tomokazu Yamamoto, Kazuhiro Yasuda, Yasuro Niidome
    • Organizer
      nternational Union of Materials Research Societies, 15 th International Conference in Asia (IUMRS-ICA 2014)
    • Place of Presentation
      Fukuoka University, Fukuoka, Japan
    • Year and Date
      2014-08-24 – 2014-08-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] High Resolution Electron Microscope Observation of Gold Nanorods under Irradiation with Pulsed Laser Light2014

    • Author(s)
      Syo Matsumura, Nao Sumimoto, Tomokazu Yamamoto, Kazuhiro Yasuda
    • Organizer
      The 8th International Conference on Advanced Materials Processing (ICAMP-8)
    • Place of Presentation
      the Hotel Grand Chancellor Surfers Paradise, Gold Coast, Queensland, Australia
    • Year and Date
      2014-07-27 – 2014-07-30
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] In-situ observation of morphological changes of gold nanorods under pulsed laser irradiation in HVEM2013

    • Author(s)
      K.Nakao, T.Yamamoto, T.Daio, K.Yasuda, Y.Niidome, S.Matsumura
    • Organizer
      PRICM-8 / Advanced Materials Characterization and Evaluation: Nanomaterials Characterization and Evaluation
    • Place of Presentation
      Waikoloa, Hawaii, USA
    • Related Report
      2013 Annual Research Report
  • [Presentation] In-situ high resolution TEM observation of deformation behavior of gold nanorods under pulsed laser illumination2013

    • Author(s)
      Nao Sumimoto, Tomokazu Yamamoto, Kazuhiro Yasuda, Satoru Yoshioka, Syo Matsumura
    • Organizer
      Frontiers of Electron Microscopy in Materials Science 2013
    • Place of Presentation
      Mantra Lorne, Victoria, Austraria
    • Related Report
      2013 Annual Research Report
  • [Presentation] 金ナノロッド形状変化のレーザー光照射下「その場」観察2013

    • Author(s)
      住本 尚,山本 知一,安田 和弘,松村 晶
    • Organizer
      第55回日本顕微鏡学会 九州支部総会・学術講演会
    • Place of Presentation
      九州大学伊都キャンパス
    • Related Report
      2013 Annual Research Report

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Published: 2013-05-21   Modified: 2019-07-29  

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