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Chemical Synthesis of Bulk Thermoelectric Materials with Superlattice Structures

Research Project

Project/Area Number 25289226
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Inorganic materials/Physical properties
Research InstitutionToyota Physical and Chemical Research Institute (2014-2015)
Nagoya University (2013)

Principal Investigator

Koumoto Kunihito  公益財団法人豊田理化学研究所, その他部局等, フェロー (30133094)

Co-Investigator(Kenkyū-buntansha) WAN Chunlei  名古屋大学, 大学院工学研究科, 助教 (10641441)
Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥18,850,000 (Direct Cost: ¥14,500,000、Indirect Cost: ¥4,350,000)
Fiscal Year 2015: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2014: ¥8,840,000 (Direct Cost: ¥6,800,000、Indirect Cost: ¥2,040,000)
Fiscal Year 2013: ¥8,970,000 (Direct Cost: ¥6,900,000、Indirect Cost: ¥2,070,000)
Keywords熱電変換材料 / 超格子
Outline of Final Research Achievements

Synthetic process to obtain large-area films or fois of TiS2/organic hybrid superlattice materials through mechanical intercalation, liquid-exfoliation, and self-assembly of nanosheets.The resulting films or foils are extremely flexible and were found to exhibit higher thermoelectric performance than pristine TiS2 single crystals. A prototype of thin-film thermoelectric device was constructed by combining our newly developed n-type material with p-type organic material, PEDOT:PSS, and it's power generation characteristics was found to be improved compared to a p-type unileg device. In contrast, drastic improvement in thermoelectric performance of SrTiO3 (STO) materials was not achieved, though we succeeded in constructing 3D superlattice ceramics by self-assembling STO nanocubes with Nb-doped surfaces.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • Research Products

    (41 results)

All 2016 2015 2014 2013 Other

All Int'l Joint Research (4 results) Journal Article (13 results) (of which Int'l Joint Research: 3 results,  Peer Reviewed: 8 results,  Acknowledgement Compliant: 2 results) Presentation (21 results) (of which Int'l Joint Research: 10 results,  Invited: 11 results) Book (2 results) Patent(Industrial Property Rights) (1 results)

  • [Int'l Joint Research] University of Colorado Boulder(米国)

    • Related Report
      2015 Annual Research Report
  • [Int'l Joint Research] Tsinghua University/Nanjing Tech(China)

    • Related Report
      2015 Annual Research Report
  • [Int'l Joint Research] Calfornia Institute of Technology/University of Colorado Boulder(米国)

    • Related Report
      2014 Annual Research Report
  • [Int'l Joint Research] Nanjing Tech(China)

    • Related Report
      2014 Annual Research Report
  • [Journal Article] Thermoelectric properties of Nb-doped (Nd0.55Li0.36)TiO3 bulk ceramics with superlattice structure2016

    • Author(s)
      ⑩Y. S. Ba, Y. F. Wang, C. L. Wan, W. Norimatsu, M. Kusunoki, D. C. Ba, K. Koumoto
    • Journal Title

      J. Alloys Compd.

      Volume: 664 Pages: 487-491

    • DOI

      10.1016/j.jallcom.2015.12.231

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] On the effects of substitution, intercalation, non-stoichiometry and block layer concept in TiS2 based thermoelectrics2015

    • Author(s)
      E. Guilmeau, A. Maignan, C. L. Wan, K. Koumoto
    • Journal Title

      Phys. Chem. Chem. Phys.

      Volume: 17 Issue: 38 Pages: 24541-24541

    • DOI

      10.1039/c5cp01795e

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Dielectric Mismatch Mediates Carrier Mobility in Organic-Intercalated Layered TiS22015

    • Author(s)
      ⑨C. L. Wan, Y. Kodama, M. Kondo, R. Sasai, X. Qian, X. K. Gu, K. Koga, K. Yabuki, R. G. Yang, K. Koumoto
    • Journal Title

      Nano Lett.

      Volume: 15 Issue: 10 Pages: 6302-6308

    • DOI

      10.1021/acs.nanolett.5b01013

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] 無機/有機複合超格子熱電変換材料の創製2015

    • Author(s)
      河本邦仁
    • Journal Title

      日本熱電学会誌

      Volume: 12 Pages: 2-3

    • Related Report
      2015 Annual Research Report
  • [Journal Article] 無機/有機複合超格子熱電変換材料2015

    • Author(s)
      河本邦仁、万春磊
    • Journal Title

      セラミックデータブック

      Volume: 43 Pages: 55-60

    • Related Report
      2015 Annual Research Report
  • [Journal Article] Flexible n-type thermoelectric materials by organic intercalation of layered transition metal2015

    • Author(s)
      Chunlei Wan, Xiaokun Gu, Feng Dang, Tomohiro Itoh, Yifeng Wang, Hitoshi
    • Journal Title

      Nature Materials

      Volume: 14 Issue: 6 Pages: 622627-622627

    • DOI

      10.1038/nmat4251

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] 二硫化チタン系自然超格子の構築および熱電特性2014

    • Author(s)
      万 春磊、伊藤智裕、小柳津教之、河本邦仁
    • Journal Title

      工業材料

      Volume: 2014 Pages: 30-33

    • Related Report
      2014 Annual Research Report
  • [Journal Article] 熱電変換材料開発の概観2014

    • Author(s)
      河本邦仁
    • Journal Title

      高分子

      Volume: 63 Pages: 775-775

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] "Effects of transition metal substitution on the thermoelectric properties of metallic (BiS)1.2(TiS2)2 misfit layer sulfide"2013

    • Author(s)
      Y. E. Putri, C. Wan, F. Dang, T. Mori, Y. Ozawa, W. Norimatsu, M. Kusunoki, and K Koumoto
    • Journal Title

      J. Elec. Mater.

      Volume: ー Issue: 6 Pages: 1-5

    • DOI

      10.1007/s11664-013-2894-3

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enhanced Thermoelectric Performance of Nanostructured SrTiO3: Self-assembled Film of Nanocubes2013

    • Author(s)
      F. Dang, C. L. Wan, N. H. Park, K. Tsuruta, W. S. Seo, K. Koumoto
    • Journal Title

      ACS Appl. Mater. & Interfaces

      Volume: 5 Issue: 21 Pages: 10933-10937

    • DOI

      10.1021/am403112n

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enhanced thermoelectric performance of Nb-doped SrTiO3 by nano-inclusion with low thermal conductivity2013

    • Author(s)
      N. Wang, H. J. Chen, H. C. He, W. Norimatsu, M. Kusunoki and K. Koumoto
    • Journal Title

      Sci. Rep.

      Volume: 3 Pages: 3449-3449

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 高効率熱電変換材料の開発とシステムへの応用2013

    • Author(s)
      河本邦仁
    • Journal Title

      応用物理

      Volume: 82 Pages: 936-939

    • NAID

      130007718316

    • Related Report
      2013 Annual Research Report
  • [Journal Article] TiS2系2次元超格子構造化合物の熱電性能2013

    • Author(s)
      河本邦仁、万春磊
    • Journal Title

      J. Soc. Inorg. Mater. Jpn.

      Volume: 21 Pages: 3-5

    • Related Report
      2013 Annual Research Report
  • [Presentation] Inorganic/Organic Nanohybridization for TE Materials Design2016

    • Author(s)
      K. Koumoto, R. M. Tian, C. L. Wan
    • Organizer
      ICOT2016
    • Place of Presentation
      Kyoto, Japan
    • Year and Date
      2016-01-20
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Flexible tandem thermoelectric foil for future energy harvesting2015

    • Author(s)
      R. M. Tian, A. B. Azizi, C. L. Wan, K. Koumoto
    • Organizer
      CICC-9
    • Place of Presentation
      Guilin, China
    • Year and Date
      2015-11-07
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Nano-Length-Scale Inorganic/Organic Hybridization for Thermoelectric Materials2015

    • Author(s)
      K. Koumoto, R. Tian, C. L. Wan
    • Organizer
      228th ECS Meeting
    • Place of Presentation
      Phoenix, USA
    • Year and Date
      2015-10-14
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] hermoelectrics – Dream Technology for Renewable Energy Harvesting2015

    • Author(s)
      K. Koumoto, C. L. Wan, R. G. Yang
    • Organizer
      IAMS Workshop on Renewable Energies
    • Place of Presentation
      Taipei, Taiwan
    • Year and Date
      2015-08-27
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Inorganic/Organic Hybridization – New Strategy for Next-Generation Thermoelectrics2015

    • Author(s)
      K. Koumoto, C. L. Wan, R. G. Yang
    • Organizer
      ICT&ECT2015
    • Place of Presentation
      Dresden, Germany
    • Year and Date
      2015-06-30
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Carrier Mobility Enhancement and Ultralow Thermal Conductivity in TiS2-based Inorg/Org Superlattices2014

    • Author(s)
      K. Koumoto, C.L. Wan, T. Ito, M. Kondo, Y. Kodama, R. G. Yang, K. Yabuki, K. Koga
    • Organizer
      MRS Fall Meeting
    • Place of Presentation
      Boston, USA
    • Year and Date
      2014-12-02
    • Related Report
      2014 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Next-Generation Thermoelectric Materials and Devices2014

    • Author(s)
      K. Koumoto, C.L. Wan, T. Ito, M. Kondo, Y. Kodama, R. G. Yang, K. Yabuki, K. Koga
    • Organizer
      AFM-AMEC 2014
    • Place of Presentation
      Shanghai, China
    • Year and Date
      2014-10-28
    • Related Report
      2014 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Optimizing TiS2-Based Organic/Inorganic Superlattices for Higher Thermoelectric Performance2014

    • Author(s)
      C. L. Wan
    • Organizer
      ICC-5
    • Place of Presentation
      Beijing, China
    • Year and Date
      2014-08-20
    • Related Report
      2014 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Versatile TiS2-based Inorganic/Organic Superlattices for Thermolectrics2014

    • Author(s)
      K. Koumoto, C. L. Wan, T. Ito, M. Kondo, Y. Kodama, K. Yabuki, K. Koga
    • Organizer
      ICT2014
    • Place of Presentation
      Nashville, USA
    • Year and Date
      2014-07-08
    • Related Report
      2014 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Unconventional Superlattice-structured Bulk Thermoelectric Materials2014

    • Author(s)
      K. Koumoto
    • Organizer
      CIMTEC-FNM 2014
    • Place of Presentation
      Montecatini Terme, Italy
    • Year and Date
      2014-06-17
    • Related Report
      2014 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Nb/La-SrTiO3ナノ粒子膜の自己組織的形成による高熱電発電能の実現2014

    • Author(s)
      鶴田一樹、党 鋒、万春磊, 河本邦仁
    • Organizer
      日本セラミックス協会2014年会
    • Place of Presentation
      慶應義塾大学日吉キャンパス
    • Related Report
      2013 Annual Research Report
  • [Presentation] 無機/有機ハイブリッド超格子のステージ構造制御による高熱電性能化2014

    • Author(s)
      近藤真美、万春磊, 河本邦仁
    • Organizer
      日本セラミックス協会2014年会
    • Place of Presentation
      慶應義塾大学日吉キャンパス
    • Related Report
      2013 Annual Research Report
  • [Presentation] TiS2-based Organic/Inorganic Superlattice – A Flexible Thermoelectric Material2013

    • Author(s)
      C. L. Wan, T. Itou, H. Sasaki, F. Dang, K. Koumoto
    • Organizer
      PacRim8
    • Place of Presentation
      San Diego, USA
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Recent Progress in Exploitation of High-Efficiency Thermoelectric Materials through Nanostructure Design2013

    • Author(s)
      K. Koukoto
    • Organizer
      32nd International Conference on Thermoelectrics (ICT2013)
    • Place of Presentation
      神戸国際会議場
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Thermoelectric Materials and Devices for Solar Energy Harvesting2013

    • Author(s)
      K. Koumoto
    • Organizer
      The International Symposium on Inorganic and Environmental Materials 2013 (ISIEM 2013)
    • Place of Presentation
      Rennes, France
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] TiS2-based inorganic/organic superlattice: a new type of hybrid thermoelectric material2013

    • Author(s)
      C. L. Wan, Hitoshi Sasaki, Tomohiro Ito, Feng Dang, Kunihito Koumoto
    • Organizer
      ICT2013
    • Place of Presentation
      神戸国際会議場
    • Related Report
      2013 Annual Research Report
  • [Presentation] Effects of Chromium-doping on Thermoelectric Properties of (BiS)1.2(TiS2)2 Misfit Layer Sulfide2013

    • Author(s)
      Yulia Eka Putri, Chunlei Wan, Wataru Norimatsu, Michiko Kusunoki, Tsunehiro Takeuchi, Ruizhi Zhang, Takao Mori, and Kunihito Koumoto
    • Organizer
      ICT2013
    • Place of Presentation
      神戸国際会議場
    • Related Report
      2013 Annual Research Report
  • [Presentation] TiS2を用いた無機/有機ハイブリッド超格子の熱電性能2013

    • Author(s)
      伊藤智裕・佐々木仁嗣・近藤真美・万春磊・河本邦仁
    • Organizer
      日本セラミックス協会2013秋季シンポジウム
    • Place of Presentation
      長野市
    • Related Report
      2013 Annual Research Report
  • [Presentation] 液相プロセスによって剥離されたTiS2二次元ナノシートの熱電特性2013

    • Author(s)
      小柳津教之・万春磊・河本邦仁
    • Organizer
      日本セラミックス協会2013秋季シンポジウム
    • Place of Presentation
      長野市
    • Related Report
      2013 Annual Research Report
  • [Presentation] TiS2を用いた無機/有機ハイブリッド超格子の熱電性能2013

    • Author(s)
      伊藤智裕・佐々木仁嗣・近藤真美・万春磊・河本邦仁
    • Organizer
      第10回日本熱電学会学術講演会
    • Place of Presentation
      名古屋大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] 液相プロセスによって剥離されたTiS2二次元ナノシートの熱電特性2013

    • Author(s)
      小柳津教之・万春磊・河本邦仁
    • Organizer
      第10回日本熱電学会学術講演会
    • Place of Presentation
      名古屋大学
    • Related Report
      2013 Annual Research Report
  • [Book] Thermoelectric Nanomaterials2013

    • Author(s)
      C. L. Wan, Y. F. Wang, Y. E. Putri and K. Koumoto
    • Total Pages
      387
    • Publisher
      Springer-Verlag
    • Related Report
      2013 Annual Research Report
  • [Book] Thermoelectric Nanomaterials2013

    • Author(s)
      R. Z. Zhang and K. Koumoto
    • Total Pages
      387
    • Publisher
      Springer-Verlag
    • Related Report
      2013 Annual Research Report
  • [Patent(Industrial Property Rights)] 無機有機複合熱電変換材料とその製造方法2014

    • Inventor(s)
      河本邦仁、万 春磊
    • Industrial Property Rights Holder
      河本邦仁、万 春磊
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2014-216416
    • Filing Date
      2014-10-23
    • Related Report
      2014 Annual Research Report

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Published: 2013-05-21   Modified: 2022-01-27  

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