Structural and morphological control and functionalization of ordered mesoporous carbon

• Project/Area Number: 25289228
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Partial Multi-year Fund
• Section: 一般
• Research Field: Inorganic materials/Physical properties
• Research Institution: Osaka University
• Principal Investigator: Nishiyama Norikazu 大阪大学, 基礎工学研究科, 教授 (10283730)
• Research Collaborator: UCHIDA Yoshiaki 大阪大学, 大学院基礎工学研究科, 准教授 ; HIROTA Yuichiro 大阪大学, 大学院基礎工学研究科, 助教 ; MITOME Takahito 大阪大学, 大学院基礎工学研究科 ; YOSHIDA Nao 大阪大学, 基礎工学部, 学部生
• Project Period (FY): 2013-04-01 – 2017-03-31
• Project Status: Completed (Fiscal Year 2016)
• Budget Amount: ¥16,770,000 (Direct Cost: ¥12,900,000、Indirect Cost: ¥3,870,000); Fiscal Year 2015: ¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000); Fiscal Year 2014: ¥6,240,000 (Direct Cost: ¥4,800,000、Indirect Cost: ¥1,440,000); Fiscal Year 2013: ¥5,980,000 (Direct Cost: ¥4,600,000、Indirect Cost: ¥1,380,000)
• Keywords: メソポーラスカーボン / キャパシタ / 吸着剤 / ナノ細孔 / カーボン / カーボンアロイ触媒

Outline of Final Research Achievements

The objective of this study is to reveal the relationship among the mesoporous carbons with various pore structure and their performance for applications. (1) Ordered mesoporous carbon films prepared by a spin-coating technique have an Im3m structure. Nitrogen-containing ordered mesoporous carbon films were also synthesized using self-assembly of m-aminophenol as a single carbon and nitrogen source and triblock copolymer Pluronic F127. (2) The structure of carbons was changed from the 3D-connected framework to the aggregate of carbon particles. The pore size could be largely changed from 6.8 nm (for the 3D-connected framework structure) to 56 nm (for the carbon particle aggregate structure). (3) New nanoporous carbons were prepared by a carbonization of resorcinol-formaldehyde-Pluronic F127 composite in the presence of KOH. The synthesized nanoporous carbon possess 2.4 nm pores, which could not be obtained by previous reported soft-templating method.

Research Products

• [Journal Article] Porous structure and pore size control of mesoporous carbons using a combination of a soft-templating method and a solvent evaporation technique (2016)
  • Author(s): Takahito Mitome, Yuichiro Hirota, Yoshiaki Uchida, Norikazu Nishiyama
  • Journal Title: Colloids and Surfaces A Volume: 494 Pages: 180-185
  • DOI: 10.1016/j.colsurfa.2016.01.009
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Vapor Infiltration Synthesis of Nitrogen-Containing Ordered Mesoporous Carbon Films and the Electrochemical Properties (2015)
  • Author(s): Takahito Mitome, Yoshiaki Uchida, Norikazu Nishiyama
  • Journal Title: JOURNAL OF CHEMICAL ENGINEERING OF JAPAN Volume: 48 Issue: 3 Pages: 245-251
  • DOI: 10.1252/jcej.14we246
  • NAID: 130004862058
  • ISSN: 0021-9592, 1881-1299
  • Peer Reviewed / Acknowledgement Compliant
• [Presentation] 無溶媒法によるナノポーラスカーボンの合成 (2017)
  • Author(s): 吉田奈央, 廣田雄一朗, 内田幸明, 西山憲和
  • Organizer: 第19回化学工学会学生発表会（豊中大会）
  • Place of Presentation: 大阪大学（大阪府豊中市）
• [Presentation] 直接賦活法を用いた高表面積ナノポーラスカーボンの合成と細孔構造制御 (2015)
  • Author(s): 三留敬人・廣田雄一朗・内田幸明・西山憲和
  • Organizer: 第42回炭素材料学会年会
  • Place of Presentation: 関西大学（大阪府、吹田市）
  • Year and Date: 2015-12-02
• [Presentation] 溶媒揮発法・直接賦活法を用いた高表面積ナノポーラスカーボンの合成 (2015)
  • Author(s): 三留敬人・廣田雄一朗・内田幸明・西山憲和
  • Organizer: 化学工学会第47回秋季大会
  • Place of Presentation: 北海道大学（北海道、札幌市）
  • Year and Date: 2015-09-09
• [Presentation] 高表面積ナノポーラスカーボンを用いた水溶液からのアルコールの吸着分離 (2015)
  • Author(s): Takahito Mitome, Van der Perre Stijn, Baron Gino V., Denayer Joeri F. M., Norikazu Nishiyama
  • Organizer: 化学工学会第47回秋季大会
  • Place of Presentation: 北海道大学（北海道、札幌市）
  • Year and Date: 2015-09-09
• [Presentation] Simple synthesis of nanoporous carbons with a high surface area and their electrochemical double layer capacitance (2015)
  • Author(s): Takahito Mitome, Yoshiaki Uchida, Norikazu Nishiyama
  • Organizer: International Symposium on Zeolite and Microporous Crystals 2015
  • Place of Presentation: Sapporo, Japan
  • Year and Date: 2015-06-28
  • Int'l Joint Research
• [Presentation] Synthesis of nanoporous carbon with high surface area and their adsorption properties (2015)
  • Author(s): Takahito Mitome, Stijn Van der Perre, Gino V. Baron, Joeri F. M. Denayer, Norikazu Nishiyama
  • Organizer: International Symposium on Zeolite and Microporous Crystals 2015
  • Place of Presentation: Sapporo, Japan
  • Year and Date: 2015-06-28
  • Int'l Joint Research
• [Presentation] 直接賦活有機鋳型法によるナノポーラスカーボンの合成とキャパシタ特性 (2015)
  • Author(s): 王 双寧・Fitri Meika Aidil・三留敬人・内田幸明・西山憲和
  • Organizer: 化学工学会第80年会
  • Place of Presentation: 芝浦工業大学
  • Year and Date: 2015-03-18 – 2015-03-20
• [Presentation] 高比表面積ミクロポーラスカーボンの一段階合成とその電気化学特性 (2014)
  • Author(s): 三留敬人・内田幸明・西山憲和
  • Organizer: 第41回炭素材料学会年会
  • Place of Presentation: 大野城まどかぴあ
  • Year and Date: 2014-12-08 – 2014-12-10
• [Presentation] 有機鋳型法を用いた高表面積ミクロポーラスカーボンの合成 (2014)
  • Author(s): 三留敬人・内田幸明・西山憲和
  • Organizer: 第30回ゼオライト研究発表会
  • Place of Presentation: タワーホール船堀
  • Year and Date: 2014-11-26 – 2014-11-27
• [Presentation] 有機鋳型法を用いた窒素含有メソポーラスカーボン薄膜の合成とキャパシタ特性 (2014)
  • Author(s): 三留敬人・内田幸明・江頭靖幸・西山憲和
  • Organizer: 化学工学会第79年会
  • Place of Presentation: 岐阜大学
• [Presentation] 有機鋳型法を用いた窒素含有メソポーラスカーボン薄膜の合成と電気化学特性 (2013)
  • Author(s): 三留敬人・内田幸明・江頭靖幸・西山憲和
  • Organizer: 炭素材料学会第40回年会
  • Place of Presentation: 京都教育文化センター
• [Book] ナノ空間材料ハンドブック (2016)
  • Author(s): 田中俊輔, 西山憲和
  • Total Pages: 5
  • Publisher: エヌ・ティー・エス
• [Patent(Industrial Property Rights)] 多孔質炭素の製造方法 (2016)
  • Inventor(s): 西山憲和, 三留敬人
  • Industrial Property Rights Holder: 大阪大学
  • Industrial Property Rights Type: 特許
  • Industrial Property Number: 2016-086591
  • Filing Date: 2016-04-23