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Development of hydrooxide ion-conductive layred double hydroxides with electron and light functions

Research Project

Project/Area Number 25289230
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Inorganic materials/Physical properties
Research InstitutionHokkaido University

Principal Investigator

Tadanaga Kiyoharu  北海道大学, 工学(系)研究科(研究院), 教授 (90244657)

Co-Investigator(Kenkyū-buntansha) HIGUCHI MIKIO  北海道大学, 大学院工学研究院, 准教授 (40198990)
Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥18,720,000 (Direct Cost: ¥14,400,000、Indirect Cost: ¥4,320,000)
Fiscal Year 2015: ¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2014: ¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2013: ¥8,450,000 (Direct Cost: ¥6,500,000、Indirect Cost: ¥1,950,000)
Keywords層状複水酸化物 / 水酸化物イオン伝導性 / 可視光応答性光触媒 / 酸素還元反応 / アルカリ形燃料電池 / 金属-空気二次電池 / 燃料電池 / 金属-空気電池 / 光触媒
Outline of Final Research Achievements

Zn-Al layered double hydroxide (LDH) thin films intercalated with Eosin Y were prepared by the sol-gel method with hot water treatment. The heat-treated Zn-Al Eosin-Y LDH thin film was confirmed to work as the electrode of a solar cell under visible light irradiation. Powders of Zn-Al layered LDHs intercalated with eosin Y were also found to show the photocatalytic activity under visible light irradiation.
The ionic conductivity of (Ni, Mn)-Al LDHs and (Ni, Mn)-Fe LDHs intercalated with CO32- was found to be higher than that of Ni-Al LDH or Ni-Fe LDH. The addition of LDHs to the catalyst layer of an air-electrode increased the current for oxygen reduction reaction (ORR). H2-O2 fuel cells with Mg-Al LDHs as an electrolyte were confirmed to be operated.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • Research Products

    (25 results)

All 2016 2015 2014 2013

All Journal Article (4 results) (of which Acknowledgement Compliant: 3 results,  Peer Reviewed: 2 results) Presentation (21 results) (of which Int'l Joint Research: 3 results,  Invited: 1 results)

  • [Journal Article] 2.無機水酸化物イオン伝導体の創製と応用2016

    • Author(s)
      忠永清治
    • Journal Title

      Electrochemistry

      Volume: 84 Issue: 1 Pages: 31-34

    • DOI

      10.5796/electrochemistry.84.31

    • NAID

      130005118465

    • ISSN
      1344-3542, 2186-2451
    • Related Report
      2015 Annual Research Report
  • [Journal Article] Preparation of Zn-;Al layered double hydroxide thin films intercalated with Eosin Y by hot water treatment of sol-gel derived precursor films2016

    • Author(s)
      K. Tadanaga, J. Oi, M. Higuchi
    • Journal Title

      J. Sol-Gel Sci. Techn.

      Volume: 未定 Issue: 2 Pages: 303-307

    • DOI

      10.1007/s10971-016-4001-8

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Development of alkaline fuel cells using hydroxide-ion conductive layered double hydroxides2015

    • Author(s)
      K. Tadanaga, K. Igarashi, T. Kubota, A. Miura, M. Higuchi,
    • Journal Title

      ECS Transactions

      Volume: 69 Issue: 17 Pages: 385-389

    • DOI

      10.1149/06917.0385ecst

    • Related Report
      2015 Annual Research Report
    • Acknowledgement Compliant
  • [Journal Article] Photocatalytic O2 evolution from water over Zn-Cr layered double hydroxides intercalated with inorganic anions2015

    • Author(s)
      Naoya Hirata, K. Tadanaga, M. Tatsumisago
    • Journal Title

      Materials Research Bulletin

      Volume: 62 Pages: 1-4

    • DOI

      10.1016/j.materresbull.2014.11.013

    • NAID

      120005553670

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] 再構築法を用いたMg-Al 系LDH 固体電解質の作製2016

    • Author(s)
      五十嵐滉平・三浦章・樋口幹雄・忠永清治
    • Organizer
      日本セラミックス協会2016年年会
    • Place of Presentation
      早稲田大学
    • Year and Date
      2016-03-14
    • Related Report
      2015 Annual Research Report
  • [Presentation] Hydroxide ion conducition in layered double hydroxides and their application to electrochemical devices2016

    • Author(s)
      K. Tadanaga
    • Organizer
      Hokkaido University-University of California Berkeley Joint Symposium on Chemical Sciences and Engineering
    • Place of Presentation
      Sapporo, Japan
    • Year and Date
      2016-01-07
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Mg-Al系層状複水酸化物を固体電解質に用いた燃料電池の構築2015

    • Author(s)
      五十嵐滉平, 三浦章, 樋口幹雄, 忠永清治
    • Organizer
      平成27年度日本セラミックス協会東北北海道支部研究発表会
    • Place of Presentation
      米沢
    • Year and Date
      2015-10-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] Electrochemical Oxygen Separation Using Layered Double Hydroxides As Hydroxide Ion Conductor2015

    • Author(s)
      K. Tadanaga, Y. Arishige, A. Hayashi, and M. Tatsumisago
    • Organizer
      228th ECS Meeting
    • Place of Presentation
      Arizona, USA
    • Year and Date
      2015-10-11
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Development of Alkaline Fuel Cells Using Hydroxide-Ion Conductive Layered Double Hydroxides2015

    • Author(s)
      K. Tadanaga, K. Igarashi, T. Kubota, A. Miura, and M. Higuchi
    • Organizer
      228th ECS Meeting
    • Place of Presentation
      Arizona, USA
    • Year and Date
      2015-10-11
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 遷移金属を含む層状複水酸化物の合成と金属-空気二次電池材料への応用2015

    • Author(s)
      久保田高志・三浦章・樋口幹雄・忠永清治
    • Organizer
      日本セラミックス協会第28回秋季シンポジウム
    • Place of Presentation
      富山大学
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] Mg-Al系層状複水酸化物を固体電解質に用いた水素-酸素燃料電池の構築2015

    • Author(s)
      五十嵐滉平・三浦 章・樋口幹雄・忠永清治
    • Organizer
      2015年電気化学会秋季大会
    • Place of Presentation
      埼玉工業大学
    • Year and Date
      2015-09-11
    • Related Report
      2015 Annual Research Report
  • [Presentation] 層状複水酸化物の電気化学素子への応用2015

    • Author(s)
      忠永清治
    • Organizer
      公開シンポジウム・層状複水酸化物の最新科学
    • Place of Presentation
      慶応大学
    • Year and Date
      2015-07-30
    • Related Report
      2015 Annual Research Report
  • [Presentation] Mg-Al 系層状複水酸化物を固体電解質に用いたアルカリ形燃料電池の構築とその評価2015

    • Author(s)
      五十嵐滉平・三浦 章・樋口幹雄・忠永清治
    • Organizer
      日本化学会北海道支部2015年夏季研究発表会
    • Place of Presentation
      函館
    • Year and Date
      2015-07-18
    • Related Report
      2015 Annual Research Report
  • [Presentation] Ni-Mn-Fe系層状複水酸化物をアイオノマーとして用いた金属-空気二次電池空気極の特性評価2015

    • Author(s)
      久保田 高志,三浦 章,樋口 幹雄,忠永 清治
    • Organizer
      2015年電気化学会第82回大会
    • Place of Presentation
      横浜国立大学
    • Year and Date
      2015-03-15 – 2015-03-17
    • Related Report
      2014 Annual Research Report
  • [Presentation] 温水処理を伴うゾル-ゲル法によるエオシンYを含むZn-Al系層状複水酸化物薄膜の作製と 応用2014

    • Author(s)
      忠永清治・大井隼一郎・樋口幹雄
    • Organizer
      平成 26 年度 日本セラミックス協会東北北海道支部研究発表会
    • Place of Presentation
      秋田市にぎわい交流館AU
    • Year and Date
      2014-11-06 – 2014-11-07
    • Related Report
      2014 Annual Research Report
  • [Presentation] Ni-Mn-Fe及びNi-Mn-Al系層状複水酸化物の合成とアルカリ形燃料電池への応用2014

    • Author(s)
      久保田高志,樋口幹雄,忠永清治
    • Organizer
      2014年電気化学会秋季大会
    • Place of Presentation
      北海道大学
    • Year and Date
      2014-09-27 – 2014-09-28
    • Related Report
      2014 Annual Research Report
  • [Presentation] Hydroxide Ion Conduction in Layered Double Hydroxides and Their Application to Electrochemical Devices2014

    • Author(s)
      Kiyoharu Tadanaga
    • Organizer
      Nagoya Univ.-Tsinghua Univ.-Toyota Motor Corp.-Hokkaido Univ. Joint Symposium
    • Place of Presentation
      北海道大学
    • Year and Date
      2014-07-21 – 2014-07-24
    • Related Report
      2014 Annual Research Report
  • [Presentation] アルカリ形燃料電池への応用に向けたNi, Mn-Al 及びNi, Mn-Fe 系層状複水酸化物の作製と評価2014

    • Author(s)
      久保田高志・樋口幹雄・忠永清治
    • Organizer
      日本化学会北海道支部2014年夏季研究発表会
    • Place of Presentation
      苫小牧高専
    • Year and Date
      2014-07-12
    • Related Report
      2014 Annual Research Report
  • [Presentation] エオシンY を含むZn-Al 系層状複水酸化物薄膜の色素増感太陽電池電極への応用2014

    • Author(s)
      忠永清治、大井隼一郎、樋口幹雄
    • Organizer
      日本セラミックス協会2014年年会
    • Place of Presentation
      慶応大学(横浜市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] エオシンY を含むZn-Al 系層状複水酸化物の光触媒特性2014

    • Author(s)
      平田直也、忠永清治、辰巳砂昌弘
    • Organizer
      日本セラミックス協会2014年年会
    • Place of Presentation
      慶応大学(横浜市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 忠永清治、久保田高志、樋口幹雄2014

    • Author(s)
      Ni-Mn-Fe系層状複水酸化物のイオン導電性評価
    • Organizer
      2014年電気化学会大81回大会
    • Place of Presentation
      関西大学(吹田市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 水酸化物イオン伝導性を有するMg-Al系層状複水酸化物をセパレータ層に用いた金属-空気二次電池の作製2014

    • Author(s)
      有重裕司、窪大樹、忠永清治、林晃敏、辰巳砂昌弘
    • Organizer
      2014年電気化学会大81回大会
    • Place of Presentation
      関西大学(吹田市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 温水処理を伴うゾル-ゲル法によるエオシンYを含むZn-Al系層状複水酸化物薄膜の作製2013

    • Author(s)
      大井隼一郎、樋口幹雄、忠永清治
    • Organizer
      日本セラミックス協会第26回秋季シンポジウム
    • Place of Presentation
      信州大学(長野市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Zn-Cr 系層状複水酸化物による水の光分解2013

    • Author(s)
      平田直也、忠永清治、辰巳砂昌弘
    • Organizer
      日本セラミックス協会第26回秋季シンポジウム
    • Place of Presentation
      信州大学(長野市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Development of All-Solid-State Alkaline Fuel Cells Using Layred Double Hydroxides2013

    • Author(s)
      K. Tadanaga
    • Organizer
      Frontier Chemistry Center The 2nd International Symosium
    • Place of Presentation
      北海道大学(札幌市)
    • Related Report
      2013 Annual Research Report

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Published: 2013-05-21   Modified: 2019-07-29  

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