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Simulation experiments on failure of Zircaloy cladding due to a coolant loss, and oxidation behaviors of Zircaloy at temperatures through the transition temperatures of ZrO2

Research Project

Project/Area Number 25289236
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Composite materials/Surface and interface engineering
Research InstitutionAkita University

Principal Investigator

Kaneko Hiroyuki  秋田大学, その他部局等, 名誉教授 (20006688)

Co-Investigator(Kenkyū-buntansha) 福本 倫久  秋田大学, 工学(系)研究科(研究院), 准教授 (20343064)
原 基  秋田大学, 工学(系)研究科(研究院), 教授 (50156494)
Project Period (FY) 2013-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥18,330,000 (Direct Cost: ¥14,100,000、Indirect Cost: ¥4,230,000)
Fiscal Year 2015: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Fiscal Year 2014: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Fiscal Year 2013: ¥12,480,000 (Direct Cost: ¥9,600,000、Indirect Cost: ¥2,880,000)
Keywordsジルカロイ / 水蒸気酸化 / 酸素センサー / 水素センサー / 酸素ポンプセンサー
Outline of Final Research Achievements

At an initial stage of the Fukushima nuclear accident, a Zircaloy cladding was destroyed and a hydrogen explosion occurred. To analyze this phenomenon, a simulation experiment and a steam oxidation experiment of the Zircaloy were carried out. An electric heating wire was inserted in a Zircaloy-4 tube instead of a nuclear fuel. Using a hydrogen sensor, hydrogen generation due to a coolant loss was successfully surveyed. The oxidation behavior of the metal was investigated at high temperatures in a flowing Ar-H2O mixed gas using hydrogen and oxygen sensors. The sensor was useful for surveying hydrogen generation due to steam decomposition. The oxidation rate of the metal from generated hydrogen amount is in agreement with one measured thermogravimetrically.A change of oxidation rate was clearly detected at a monoclinic tetragonal transition temperature of ZrO2. Above results show that the gas sensing method is useful to survey oxidation process of the metal due to steam water.

Report

(5 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • Research Products

    (15 results)

All 2017 2016 2015 2014

All Journal Article (5 results) (of which Peer Reviewed: 2 results,  Acknowledgement Compliant: 2 results,  Open Access: 1 results) Presentation (10 results)

  • [Journal Article] Analysis of Water Vapor Oxidation of Metals by Measuring the Partial Pressures of Hydrogen and Oxygen2016

    • Author(s)
      Michihisa Fukumoto, Hiroshi Sonobe, Motoi Hara, Hiroyuki Kaneko
    • Journal Title

      Oxidation of Metals

      Volume: 84 Pages: 11-11

    • Related Report
      2016 Annual Research Report
  • [Journal Article] 水素センサーおよび酸素センサーを用いた酸素を含む水蒸気雰囲気中でのジルカロイの水蒸気酸化挙動の検討2016

    • Author(s)
      福本倫久,園部 博,原 基,金児紘征
    • Journal Title

      日本金属学会誌

      Volume: 80 Pages: 231-239

    • NAID

      130005138653

    • Related Report
      2016 Annual Research Report
  • [Journal Article] Formation of the α-NiAl containing Hf by the Simultaneous Electrodeposition of Al and Hf using a Molten-Salt and the Cyclic Oxidation Behaviot2016

    • Author(s)
      Michihisa Fukumoto, Ai Yokobori and Motoi Hara
    • Journal Title

      Oxidation of Metals

      Volume: 85 Pages: 17-28

    • Related Report
      2016 Annual Research Report
  • [Journal Article] Hydrogen Generation Monitoring and Mass Gain Analysis during the Steam Oxidation for Zircaloy Using Hydrogen and Oxygen Sensors2015

    • Author(s)
      福本倫久、櫻庭拓也、原基、金児紘征
    • Journal Title

      Journal of the Japan Institute of Metals and Materials

      Volume: 79 Issue: 7 Pages: 362-371

    • DOI

      10.2320/jinstmet.J2015002

    • NAID

      130005084807

    • ISSN
      0021-4876, 1880-6880, 2433-7501
    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] 水素センサーおよび酸素センサーを用いたジルカロイの水蒸気酸化過程における水素発生の検出と酸化増量の解析2015

    • Author(s)
      福本倫久,櫻庭拓也,原 基,金児紘征
    • Journal Title

      日本金属学会誌

      Volume: 7

    • NAID

      130005084807

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Presentation] 水素センサーおよび酸素ポンプ・センサーを用いたNi基合金の水蒸気酸化挙動の検討2017

    • Author(s)
      福本倫久
    • Organizer
      日本金属学会春季講演大会
    • Place of Presentation
      東京都立大学
    • Year and Date
      2017-03-15
    • Related Report
      2016 Annual Research Report
  • [Presentation] 水素センサーおよび酸素センサーを用いたNi-Cr 合金の水蒸気酸化挙動2016

    • Author(s)
      福本倫久
    • Organizer
      日本金属学会秋期大会
    • Place of Presentation
      大阪大学豊中キャンパス
    • Year and Date
      2016-09-22
    • Related Report
      2016 Annual Research Report
  • [Presentation] 酸素ポンプ・センサーを用いる金属の高温酸化研究2016

    • Author(s)
      金児紘征
    • Organizer
      日本金属学会秋期大会
    • Place of Presentation
      大阪大学豊中キャンパス
    • Year and Date
      2016-09-22
    • Related Report
      2016 Annual Research Report
  • [Presentation] 水素センサーおよび酸素センサーを用いたFe-Cr 合金の水蒸気酸化挙動2016

    • Author(s)
      福本倫久、赤堀昴太、園部博、原基、金児紘征
    • Organizer
      日本金属学会
    • Place of Presentation
      東京理科大学葛飾キャンパス(東京都)
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] 900℃以下におけるジルカロイの水蒸気酸化過程の解析2016

    • Author(s)
      金児紘征、福本倫久、園部博、原基
    • Organizer
      日本金属学会春期大会
    • Place of Presentation
      東京理科大学葛飾キャンパス(東京都)
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] 酸素を少量含む水蒸気下でのジルカロイの酸化挙動の検討2015

    • Author(s)
      福本倫久、原基、金児紘征
    • Organizer
      日本金属学会
    • Place of Presentation
      九州大学伊都キャンパス(福岡市)
    • Year and Date
      2015-09-17
    • Related Report
      2015 Annual Research Report
  • [Presentation] 酸素ポンプ・センサーによる金属の水蒸気酸化過程の解析2015

    • Author(s)
      金児紘征、福本倫久、園部博、原基
    • Organizer
      日本金属学会
    • Place of Presentation
      九州大学伊都キャンパス(福岡市)
    • Year and Date
      2015-09-17
    • Related Report
      2015 Annual Research Report
  • [Presentation] 水素センサーおよび酸素センサーを用いたジルカロイの水蒸気酸化に及ぼす温度変化の検討2015

    • Author(s)
      福本倫久,原 基,金児紘征
    • Organizer
      日本金属学会春季講演大会
    • Place of Presentation
      東京大学
    • Year and Date
      2015-03-18 – 2015-03-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] 酸素を少量含む水蒸気中でのジルカロイの酸化挙動の検討2014

    • Author(s)
      福本倫久,原 基,金児紘征
    • Organizer
      日本金属学会秋季講演大会
    • Place of Presentation
      名古屋大学
    • Year and Date
      2014-09-24 – 2014-09-26
    • Related Report
      2013 Annual Research Report
  • [Presentation] 水素センサーおよび酸素センサーを用いたジルカロイの水蒸気酸化挙動の検討2014

    • Author(s)
      福本倫久,櫻庭拓也,原 基,金児紘征
    • Organizer
      日本金属学会春季講演大会
    • Place of Presentation
      東京工業大学
    • Year and Date
      2014-03-21 – 2014-03-23
    • Related Report
      2013 Annual Research Report

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Published: 2013-05-21   Modified: 2025-11-19  

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