Electrode reaction mechanism analysis using hetero junction boundary length control between ionic conductors.
| Project/Area Number |
25289246
|
|---|
| Research Category |
Grant-in-Aid for Scientific Research (B)
|
| Allocation Type | Partial Multi-year Fund |
|---|
| Section | 一般 |
|---|
| Research Field |
Structural/Functional materials
|
|---|
| Research Institution | Tohoku University |
|---|
Principal Investigator |
|
|---|
| Co-Investigator(Kenkyū-buntansha) |
AMEZAWA KOJI 東北大学, 多元物質科学研究所, 教授 (90263136)
IGUCHI FUMITADA 東北大学, 工学研究科, 准教授 (00361113)
NAKAMURA TAKASHI 東北大学, 多元物質科学研究所, 助教 (20643232)
|
|---|
| Co-Investigator(Renkei-kenkyūsha) |
KAWADA Tatsuya 東北大学, 環境科学研究科, 教授 (10271983)
|
|---|
| Project Period (FY) |
2013-04-01 – 2016-03-31
|
| Project Status |
Completed (Fiscal Year 2015)
|
| Budget Amount *help |
¥19,240,000 (Direct Cost: ¥14,800,000、Indirect Cost: ¥4,440,000)
Fiscal Year 2015: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Fiscal Year 2014: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Fiscal Year 2013: ¥13,910,000 (Direct Cost: ¥10,700,000、Indirect Cost: ¥3,210,000)
|
|---|
| Keywords | パターン電極 / 固体酸化物形燃料電池 / 電極反応経路 / 酸化物空気極 / 二相界面反応 / 三相界面反応 / SOFC / PCFC / 空気極 / 電極反応メカニズム / 混合導電体 / 薄膜 / 三相界面長 / 電極反応 / イオン電子混合導電体 |
|---|
| Outline of Final Research Achievements |
Recently, composite SOFC (solid state fuel cells) cathodes between the mixed conducting oxides and electrolyte materials are widely examined due to the expectation of reaction site enhancement on triple phase boundary, However, evaluation of quantitative reactivity at triple phase boundary and the detail analysis of reaction process were not enough examined for the mix conducting cathodes. In this study, pattern electrode formation technologies is established to give a quantitative evaluation of activity at triple phase boundary by controlling of the triple phase boundary length and electrode area. As the results, it was found out that interfacial conductivity of La0.6Sr0.4CoO3-d(LSC) cathode on a CeO2 based oxide ionic conductor depended on the area specific triple phase boundary length below 873K. Additionally, it was also discovered that cathodic reaction sites of LSC cathode on a proton conducting electrolyte were mainly triple phase boundaries.
|
Report
(4 results)
Research Products
(25 results)
-
-
-
-
-
-
-
-
-
-
-
[Presentation] The electrode reaction mechanism analysis and electrode design on SOFC cathode2016
Author(s)
Shin-ichi Hashimoto, Riyan Achmad Budiman, Yuya Uzumaki, Kota Suzuki, Honami Kudo, Issei Susuta, Syunsuke Noda, Takaya Hoshi, Keiji Yashiro, Tatsuya Kawada
Organizer
40th International Conference and Expo on Advanced Ceramics and Composites
Place of Presentation
Daytona Beach, USA
Year and Date
2016-01-24
Related Report
Int'l Joint Research / Invited
-
-
-
-
-
-
-
-
-
-
-
-
-
-
