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Dynamic Change of Interfacial Tension between Liquid Fe Alloy and Molten Slag Induced by Chemical Reactions

Research Project

Project/Area Number 25289269
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Metal making/Resorce production engineering
Research InstitutionOsaka University

Principal Investigator

Tanaka Toshihiro  大阪大学, 工学(系)研究科(研究院), 教授 (10179773)

Co-Investigator(Kenkyū-buntansha) SUZUKI Masanori  大阪大学, 大学院工学研究科, 助教 (20610728)
Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥19,240,000 (Direct Cost: ¥14,800,000、Indirect Cost: ¥4,440,000)
Fiscal Year 2015: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2014: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2013: ¥15,210,000 (Direct Cost: ¥11,700,000、Indirect Cost: ¥3,510,000)
Keywords界面張力 / 溶鋼 / 溶融スラグ / 粘度 / 酸素吸着 / 化学反応 / 物質移動 / 吸着
Outline of Final Research Achievements

We investigated dynamic change in the interfacial tension with time for various compositions of molten slag and liquid Fe to comprehend the mechanism of the change in interfacial tension between liquid Fe and molten slag over time accompanying reduction/oxidation reactions.
The behavior of the change in the interfacial tension over time can be explained by the adsorption of oxygen at the interface and the diffusion of oxygen from the interface into the bulk of the liquid Fe and molten slag. In addition, we found that the interfacial tension decreases slowly and greatly from its initialvalue to a minimum point and then increases slowly to the final equilibrium state when molten silicate slag with low viscosity is brought into contact with liquid Fe without Al content and some of its SiO2 decomposes and dissolves into the liquid Fe. From these results, we suggest that the detachment of oxygen adsorbed at the interface into the liquid Fe is very slow and may be the rate-limiting step.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • Research Products

    (2 results)

All 2016 2015

All Journal Article (1 results) (of which Peer Reviewed: 1 results,  Open Access: 1 results) Presentation (1 results) (of which Int'l Joint Research: 1 results,  Invited: 1 results)

  • [Journal Article] Dynamic Changes in Interfacial Tension between Liquid Fe Alloy and Molten Slag Induced by Chemical Reactions2016

    • Author(s)
      Toshihiro Tanaka, Hiroki Goto, Masashi Nakamoto, Masanori Suzuki, Masahito Hanao, Masafumi Zeze, Hideaki Yamamura and Takeshi Yoshikawa
    • Journal Title

      ISIJ International

      Volume: 56 Issue: 6 Pages: 944-952

    • DOI

      10.2355/isijinternational.ISIJINT-2015-654

    • NAID

      130005164532

    • ISSN
      0915-1559, 1347-5460
    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access
  • [Presentation] Capillary Metallurgy and its application to the steelmaking Process2015

    • Author(s)
      Toshihiro Tanaka, Masashi Nakamoto, Masahito Watanabe and Masanori Suzuki
    • Organizer
      Asia Steel International Conference 2015
    • Place of Presentation
      Yokohama, Japan
    • Year and Date
      2015-10-05
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited

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Published: 2013-05-21   Modified: 2017-05-10  

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