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Development of a catalyst and reaction field for conversion of unused fossil resources into lighter fuels

Research Project

Project/Area Number 25289277
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Reaction engineering/Process system
Research InstitutionTokyo Institute of Technology (2015)
Hokkaido University

Principal Investigator

Tago Teruoki  東京工業大学, 理工学研究科, 教授 (20304743)

Co-Investigator(Kenkyū-buntansha) FUJITSUKA Hiroyasu  東京工業大学, 理工学研究科, 助教 (90757105)
MASUDA Takao  北海道大学, 大学院工学研究院, 教授 (20165715)
NAKASAKA Yuta  北海道大学, 大学院工学研究院, 助教 (30629548)
Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥17,550,000 (Direct Cost: ¥13,500,000、Indirect Cost: ¥4,050,000)
Fiscal Year 2015: ¥5,720,000 (Direct Cost: ¥4,400,000、Indirect Cost: ¥1,320,000)
Fiscal Year 2014: ¥5,980,000 (Direct Cost: ¥4,600,000、Indirect Cost: ¥1,380,000)
Fiscal Year 2013: ¥5,850,000 (Direct Cost: ¥4,500,000、Indirect Cost: ¥1,350,000)
Keywords非在来型原油 / 超重質油 / ビチュメン / 酸化鉄 / チタニア / ジルコニア / 亜臨界水 / ランピングモデル / 化学工学 / 触媒・化学プロセス / 反応工学 / 石油精製 / 資源・エネルギー / 石油化学 / 固体酸触媒
Outline of Final Research Achievements

From the perspective of diversification of energy resources, a technological development which can convert unused fossil resources into useful fuels has been required. Especially, oil sand bitumen is one of the promising candidates, of which the deposit is larger than that of the petroleum. Consequently, we have developed iron oxide (FeOx) composite catalysts which can convert heavy oil into lighter fuel.  In this study, Ti-Fe and Ti-Zr mixed-oxide catalysts were newly developed for oxidative and acid-catalyzed cracking of oil sand bitumen into lighter fuels, respectively. Moreover, it was revealed that the sub-critical water condition was efficient for suppressing coke formation. We also investigated the major reaction pathways for decomposition of bitumen over FeOx-based catalyst under sub-critical water condition, by the numerical simulation based on the lamping model.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • Research Products

    (27 results)

All 2016 2015 2014 2013

All Journal Article (13 results) (of which Peer Reviewed: 9 results) Presentation (14 results) (of which Int'l Joint Research: 1 results)

  • [Journal Article] Catalytic cracking of heavy oil over TiO2-ZrO2 catalysts under superheated steam conditions2016

    • Author(s)
      H. Kondoh, K. Tanaka; Y. Nakasaka, T. Tago, T. Masuda
    • Journal Title

      Fuel

      Volume: 167 Pages: 288-294

    • DOI

      10.1016/j.fuel.2015.11.075

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Upgrading of oil sand bitumen over an iron oxide catalyst using sub- and super-critical water2016

    • Author(s)
      H. Kondoh, Y. Nakasaka, T. Kitaguchi, T. Yoshikawa, T. Tago, Takao Masuda
    • Journal Title

      Fuel Processing Technology

      Volume: 145 Pages: 96-101

    • DOI

      10.1016/j.fuproc.2016.01.030

    • NAID

      120006462278

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 亜臨界水/超臨界水を用いた酸化鉄系触媒による重質油の軽質燃料化2015

    • Author(s)
      近藤永樹,中坂佑太,多湖輝興,増田隆夫
    • Journal Title

      エネルギー学会誌

      Volume: 94 Pages: 67-73

    • Related Report
      2015 Annual Research Report 2014 Annual Research Report
  • [Journal Article] 2段階反応を用いたリグニンからのフェノール類製造プロセス開発2014

    • Author(s)
      中坂佑太,吉川琢也,多湖輝興,増田隆夫
    • Journal Title

      アロマティックス

      Volume: 66 Pages: 1-10

    • Related Report
      2014 Annual Research Report
  • [Journal Article] Conversion of cacao pod husks by pyrolysis and catalytic reaction to produce useful chemicals2014

    • Author(s)
      Dieni Mansur, Teruoki Tago, Takao Masuda, Haznan Abimanyu
    • Journal Title

      Biomass & Bioenergy

      Volume: 66 Pages: 275-285

    • DOI

      10.1016/j.biombioe.2014.03.065

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Conversion of glycerol into useful chemicals over iron oxide-based catalyst2014

    • Author(s)
      Teruoki Tago, Yuta Nakasaka, Takao Masuda
    • Journal Title

      Journal of the Japan Petroleum Institute

      Volume: 57 Pages: 197-2007

    • NAID

      130004713212

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Production of phenols from lignin-derived Slurry Liquid using Iron Oxide Catalyst2014

    • Author(s)
      T. Yoshikawa, S. Shinohara, T. Yagi, N. Ryumon, Y. Nakasaka, T. Tago, T. Masuda
    • Journal Title

      Appl. Catal. B. Environ.

      Volume: 146 Pages: 289-297

    • DOI

      10.1016/j.apcatb.2013.03.010

    • NAID

      120005372322

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Conversion of Glycerol into Allyl Alcohol over Potassium-Supported Zirconia-Iron Oxide Catalyst2014

    • Author(s)
      Aya Konaka, Teruoki Tago, Takuya Yoshikawa, Ayaka Nakamura, and Takao Masuda
    • Journal Title

      Applied Catalysis B: Environmental

      Volume: 146 Pages: 267-273

    • DOI

      10.1016/j.apcatb.2013.03.007

    • NAID

      120005372320

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 酸化鉄系触媒による含水非可食バイオマスの石油関連有用化学物質への転換反応2013

    • Author(s)
      多湖輝興, 吉川琢也, 中坂佑太,増田隆夫
    • Journal Title

      触媒

      Volume: 55 Pages: 270-275

    • NAID

      10031200227

    • Related Report
      2013 Annual Research Report
  • [Journal Article] 高含水バイオマス破棄物からの石油関連有用化学物質製造の可能性2013

    • Author(s)
      増田隆夫, 多湖 輝興, 中坂佑太, 大庭潔
    • Journal Title

      化学工学会誌

      Volume: 77 Pages: 862-866

    • Related Report
      2013 Annual Research Report
  • [Journal Article] Conversion of Biodiesel-Derived Crude Glycerol into Useful Chemicals over a Zirconia-Iron Oxide Catalyst2013

    • Author(s)
      A. Konaka, T. Tago, T. Yoshikawa, H. Shitara, Y. Nakasaka, T. Masuda
    • Journal Title

      Ind. Eng. Chem. Res.

      Volume: 52 Issue: 44 Pages: 15225-15684

    • DOI

      10.1021/ie4006645

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Production of phenols from lignin via depolymerization and catalytic cracking2013

    • Author(s)
      Takuya Yoshikawa
    • Journal Title

      Fuel Processing Technology

      Volume: Vol. 108 Pages: 69-75

    • DOI

      10.1016/j.fuproc.2012.05.003

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Conversion of ethanol stillage into aliphatc ketones by two-step process of hydrothermal treatment and catalytic reaction2013

    • Author(s)
      Dieni Mansur, Mana Shimokawa, Kiyoshi Oba, Yuta Nakasaka, Teruoki Tago, Takao Masuda
    • Journal Title

      Fuel Processing Technology

      Volume: 108 Pages: 139-145

    • DOI

      10.1016/j.fuproc.2012.05.026

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Presentation] TiO2-ZrO2系触媒による加熱水蒸気を用いた重質油のアップグレーディング2015

    • Author(s)
      長谷川夏未,近藤永樹,中坂佑太,多湖輝興,増田隆夫
    • Organizer
      第45回石油・石油化学討論会
    • Place of Presentation
      ウインクあいち 名古屋市
    • Year and Date
      2015-11-05
    • Related Report
      2015 Annual Research Report
  • [Presentation] Catalytic Cracking Reaction Of Heavy Oil In The Presence Of TiO2-ZrO2 Catalysts In A Superheated Steam Condition2015

    • Author(s)
      H. Kondoh, K. Tanaka, N. Hasegawa, Y. Nakasaka, T. Tago, T. Masuda
    • Organizer
      The 16th Asian Pacific Confederation of Chemical Engineering
    • Place of Presentation
      Melbourne Convention and Exhibition Centre, Melbourne, Australia
    • Year and Date
      2015-09-27
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] FeOx-TiO2系触媒を用いた過熱水蒸気雰囲気下での重質油の接触分解反応2015

    • Author(s)
      近藤永樹,武田祐磨,中坂佑太,多湖輝興,増田隆夫
    • Organizer
      第116回触媒討論会
    • Place of Presentation
      三重大学 津市
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] 過熱水蒸気中のFe-Ti系触媒存在下における重質油の接触分解反応2015

    • Author(s)
      近藤永樹,武田祐磨,中坂佑太,多湖輝興,増田隆夫
    • Organizer
      第58回石油学会
    • Place of Presentation
      タワーホール船堀 東京都
    • Year and Date
      2015-05-26
    • Related Report
      2015 Annual Research Report
  • [Presentation] 重質油アップグレーディングのための TiO2-ZrO2触媒への第三成分の添加効果2014

    • Author(s)
      近藤永樹,田中久美子,武田祐磨,中坂佑太,多湖輝興,増田隆夫
    • Organizer
      第44回石油・石油化学討論会
    • Place of Presentation
      旭川グランドホテル (旭川)
    • Year and Date
      2014-10-16 – 2014-10-17
    • Related Report
      2014 Annual Research Report
  • [Presentation] Recovery of Lighter fuel from oil sand bitumen using FeOx-based catalyst under sub/supercritical water conditions2014

    • Author(s)
      Hisaki Kondoh, Tatsuya Kitaguchi, Yusuke Sato, Yuta Nakasaka, Teruoki Tago, Takao Masuda
    • Organizer
      The 23rd International symposium on Chemical Reaction Engineering (ISCRE23)
    • Place of Presentation
      Centra Grand & Bangkok Convention Centre, Bangkok (Thailand)
    • Year and Date
      2014-09-07 – 2014-09-10
    • Related Report
      2014 Annual Research Report
  • [Presentation] Catalytic cracking of heavy oil over TiO2-ZrO2 catalyst under a superheated steam2014

    • Author(s)
      Hisaki Kondoh, Kumiko Tanaka, Yuma Takeda, Yuta Nakasaka, Teruoki Tago, Takao Masuda
    • Organizer
      The 8th International Conference on Environmental Catalysis
    • Place of Presentation
      The Grove Park Inn, Asheville, NC (USA)
    • Year and Date
      2014-08-24 – 2014-08-27
    • Related Report
      2014 Annual Research Report
  • [Presentation] TiO2-ZrO2系触媒を用いた水蒸気雰囲気下での重質油の軽質燃料化2014

    • Author(s)
      近藤永樹,田中久美子,武田祐磨,中坂佑太,多湖輝興,増田隆夫
    • Organizer
      第23回日本エネルギー学会大会
    • Place of Presentation
      九州大学(福岡)
    • Year and Date
      2014-07-19 – 2014-07-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] Application of TiO2-ZrO2-based catalyst to decomposition for heavy oil recovery under superheated steam condition2014

    • Author(s)
      Hisaki Kondoh, Kumiko Tanaka, Yuma Takeda, Yuta Nakasaka, Teruoki Tago, Takao Masuda
    • Organizer
      The 7th Tokyo Conference on Advanced Catalytic Science and Technology
    • Place of Presentation
      Kyoto Terrsa (Kyoto city)
    • Year and Date
      2014-06-01 – 2014-06-06
    • Related Report
      2014 Annual Research Report
  • [Presentation] 重質油分解軽質化におけるTiO2-ZrO2系触媒の効果2014

    • Author(s)
      近藤永樹・田中久美子・武田祐磨・中坂佑太・多湖輝興・増田隆夫
    • Organizer
      化学系学協会北海道支部2014年冬季研究発表会
    • Place of Presentation
      北海道大学(札幌)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 過熱水蒸気雰囲気下におけるCe-Fe-Ti系触媒を用いた未利用重質油軽質燃料化2014

    • Author(s)
      武田祐磨・田中久美子・近藤永樹・中坂佑太・多湖輝興・増田隆夫
    • Organizer
      化学系学協会北海道支部2014年冬季研究発表会
    • Place of Presentation
      北海道大学(札幌)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Fe-Ti系触媒を用いた過熱水蒸気雰囲気下における重質油の分解軽質化2014

    • Author(s)
      近藤永樹・武田祐磨・田中久美子・中坂佑太・多湖輝興・増田隆夫
    • Organizer
      化学工学会第79年会
    • Place of Presentation
      岐阜大学(岐阜)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 重質油モデル物質のTiO2-ZrO2系触媒による分解挙動2013

    • Author(s)
      近藤永樹,田中久美子,武田祐磨,中坂佑太, 多湖輝興,増田隆夫
    • Organizer
      化学工学会第45回秋季大会
    • Place of Presentation
      岡山大学(岡山)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Fe-Ti系触媒を用いた過熱水蒸気雰囲気下における重質油の分解軽質化2013

    • Author(s)
      "武田祐磨・田中久美子・近藤永樹・中坂佑太・ 多湖輝興・増田隆夫"
    • Organizer
      化学工学会第45回秋季大会
    • Place of Presentation
      岡山大学(岡山)
    • Related Report
      2013 Annual Research Report

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Published: 2013-05-21   Modified: 2019-07-29  

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