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Zero-emission synthesis of biofuel from unused oil source

Research Project

Project/Area Number 25289281
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Reaction engineering/Process system
Research InstitutionSojo University

Principal Investigator

KUSAKABE Katsuki  崇城大学, 工学部, 教授 (30153274)

Co-Investigator(Kenkyū-buntansha) SAKOGUCHI Akihiro  崇城大学, 工学部, 教授 (30196141)
SAKURAGI Mina  崇城大学, 工学部, 助教 (90646829)
Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥17,550,000 (Direct Cost: ¥13,500,000、Indirect Cost: ¥4,050,000)
Fiscal Year 2015: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2014: ¥5,850,000 (Direct Cost: ¥4,500,000、Indirect Cost: ¥1,350,000)
Fiscal Year 2013: ¥8,060,000 (Direct Cost: ¥6,200,000、Indirect Cost: ¥1,860,000)
Keywordsバイオディーゼル / トリグリセリド / エステル交換反応 / 溶媒抽出 / 反応分離 / 共炭化 / 脂肪酸メチルエステル / 洗浄処理 / 炭化 / 抽出 / エステル交換 / 曇り点 / パーム油 / ラバーシード
Outline of Final Research Achievements

A co-production process of biodiesel and activated carbon from rubber seed was proposed. Biodiesel was synthesized by in-situ transesterification of the oil extracted from rubber seed in n-hexane. The fatty acid methyl ester (FAME) yield reached 98 % after 15 min-reaction due to the low extraction of free fatty acids (FFA) from the rubber seed in n-hexane. Co-carbonization of the rubber seed residue after the in-situ transesterification and the crude glycerin containing KOH improved the pore properties of activated carbon product, which indicated methylene blue adsorption ability. Water washing treatment of the synthesized crude palm oil based biodiesel was carried out at 303-343 K to remove saturated FAME selectively. When the ratio of saturated FAME to unsaturated FAME in the biodiesel became the minimum value at the washing temperature of 323 K, the minimum temperature of the cloud point was 279 K.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • Research Products

    (19 results)

All 2015 2014 2013 Other

All Int'l Joint Research (1 results) Journal Article (8 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 8 results,  Acknowledgement Compliant: 2 results) Presentation (10 results) (of which Int'l Joint Research: 1 results,  Invited: 1 results)

  • [Int'l Joint Research] ペトロナス工科大学(マレーシア)

    • Related Report
      2015 Annual Research Report
  • [Journal Article] Selective Removal of Saturated Fatty Acid Methyl Ester from Biodiesel Fuel by Hot Water Treatment2015

    • Author(s)
      K.Kusakabe, M. Ezaki, M. Nishida
    • Journal Title

      International Journal of Biomass & Renewables

      Volume: 4 Pages: 1-4

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Co-Production of Biodiesel and Activated Carbon from Rubber Seed2015

    • Author(s)
      K. Kusakabe, M. Ezaki, K. Akiyoshi, Y. Kawano, W. Michida, Y. Yamada, G. Guan, Y. Uemura, S. Yusup
    • Journal Title

      International Journal of Biomass & Renewables

      Volume: 4 Pages: 5-9

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Biodiesel production from waste cooking oil using calcined scallop shell as catalyst2015

    • Author(s)
      S. Sirisomboonchai, M. Abuduwayiti, G. Guan, C. Samart, S. Abliz, X. Hao, K. Kusakabe, A. Abudula
    • Journal Title

      Energy Conversion and Management

      Volume: 95 Pages: 242-247

    • DOI

      10.1016/j.enconman.2015.02.044

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Review on Extraction and Characterization of Castor Seed Oil2014

    • Author(s)
      Muhamed Fitri Jamil, Yoshimitsu Uemura, Noridah Osman, Katsuki Kusakabe, Suzana Yusup
    • Journal Title

      Applied Mecahnics and Materials

      Volume: 625 Pages: 916-919

    • DOI

      10.4028/www.scientific.net/amm.625.916

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Study on Extraction and Characterization of Rubber seed Oil2014

    • Author(s)
      Bashir Abubaker Abdulkadir, Yoshimitsu Uemura, Anita Ramil, Noridah Osman, Katsuki Kusakabe, Suzana Yusup
    • Journal Title

      Australian Journal of Basic and Applied Science

      Volume: 83 Pages: 445-451

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Steam Co-Gasification of Brown Seawood and Land-based Biomass2014

    • Author(s)
      Malinee Kaewpanha, Guoqing Guan, Zhongde Wang, Yutaka Kasai, Katsuki Kusakabe, Abulti Abudula
    • Journal Title

      Fue Processing Technology

      Volume: 120 Pages: 106-112

    • DOI

      10.1016/j.fuproc.2013.12.013

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Transesterification of Palm Oil in a Millichannel Reactor2013

    • Author(s)
      W.N.W.A Rashid, Y. Uemura, K. Kusakabe, N.B. Osman, B. Abdullah
    • Journal Title

      Journal of Japan Institute of Energy

      Volume: 92 Pages: 905-908

    • NAID

      130004741216

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effects of reaction parameters on two-step alkali-alkali transesterification2013

    • Author(s)
      M. Yaacob, Y. Uemura, K.M. Sabil, T. Kai, K. Kusakabe, S.S.M. Affandi, S.M. Siti, N.B. Osman
    • Journal Title

      Journal of Japan Institute of Energy

      Volume: 92 Pages: 702-706

    • NAID

      130004741212

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Presentation] Characterization of Castor Seed Plant (Ricinus Communis L.) as a Potential Feedstock for Biodiesel Production2015

    • Author(s)
      M.F. Jamil, Y. Uemura, N.B. Osman, S.B. Yusup, K. Kusakabe, N.M.N.A. Majid
    • Organizer
      5th SOJO-UTP Joint Seminar on Nano and Bio Reseach
    • Place of Presentation
      熊本市西区、崇城大学
    • Year and Date
      2015-09-03
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] マイクロを基盤としたバイオディーゼル油の研究2015

    • Author(s)
      草壁克己
    • Organizer
      第6回マイクロ化学プロセス分科会討論交流会
    • Place of Presentation
      広島県竹原市、かんぽの宿竹原
    • Year and Date
      2015-06-20
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Single step batchwise alkali transesterification of castor seed oil2014

    • Author(s)
      Muhammad Fitri Jamil, Yoshimitsu Uemura, Noridah B Osman, Nik Muhamad Nik Ab Majid, Katsuki Kusakabe, Takami Kai, Suzana Yusup
    • Organizer
      27th Internasional Symposium on Chemical engineering
    • Place of Presentation
      Kuala Lumpur, Malaysia
    • Year and Date
      2014-12-05 – 2014-12-07
    • Related Report
      2014 Annual Research Report
  • [Presentation] バイオディーゼル油の低温固化特性の改善2014

    • Author(s)
      草壁克己、道田 航
    • Organizer
      化学工学会第46回秋季大会
    • Place of Presentation
      九州大学伊都キャンパス(福岡県福岡市)
    • Year and Date
      2014-09-17 – 2014-09-19
    • Related Report
      2014 Annual Research Report
  • [Presentation] ゴムの実のin situ トランスエステル化によるバイオディーゼル製造2014

    • Author(s)
      Abubakar Bashir、上村 芳三、Ramli Anita、Osman Noridah、草壁 克己、甲斐 敬美
    • Organizer
      化学工学会第46回秋季大会
    • Place of Presentation
      九州大学伊都キャンパス(福岡県福岡市)
    • Year and Date
      2014-09-17 – 2014-09-19
    • Related Report
      2014 Annual Research Report
  • [Presentation] Selective Removal of Saturated Fatty Acid MethylEster from Biodiesel Fuel by Hot Water Treatment2014

    • Author(s)
      Katsuki Kusakabe, Katsuya Ohnishi, Wataru Michida, Masato Ezaki
    • Organizer
      4th Sojo-UTP Jpint Seminar on Nano and Bio Research
    • Place of Presentation
      Perak, Malaysia
    • Year and Date
      2014-08-21
    • Related Report
      2014 Annual Research Report
  • [Presentation] 陽イオン交換樹脂による遊離脂肪酸のエステル化反応の速度解析2013

    • Author(s)
      甲斐敬美、古川博恵、中里 勉、高梨啓和、草壁克己
    • Organizer
      化学工学会第44回秋季大会
    • Place of Presentation
      岡山市岡山大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] Biodiesel production into two serially connected microtube reactors2013

    • Author(s)
      H. Miyazaki, K. Kusakabe
    • Organizer
      2013 Joint of Taiwan/Japan/Korea Chemical Engineering Conference
    • Place of Presentation
      熊本市市民会館崇城大学ホール
    • Related Report
      2013 Annual Research Report
  • [Presentation] Effects of methanol to oil ratio, temperature, and rubber seeds size on the FAME yield by in situ transesterification from rubber seeds (Hevea brasiliensis)2013

    • Author(s)
      B.A. Abdulkadira, Y. Uemurab, A. Ramlia, N.B. Osman, K. Kusakabe, T. Kai
    • Organizer
      26th Internasional Symposium on Chemical Engineering
    • Place of Presentation
      韓国釜山市釜山国際展示場
    • Related Report
      2013 Annual Research Report
  • [Presentation] A two-step process for biodiesel production in microtube reactors2013

    • Author(s)
      H. Miyazaki, K. Kusakabe
    • Organizer
      26th Internasional Symposium on Chemical Engineering
    • Place of Presentation
      韓国釜山市釜山国際展示場
    • Related Report
      2013 Annual Research Report

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Published: 2013-05-21   Modified: 2019-07-29  

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