Zero-emission synthesis of biofuel from unused oil source
| Project/Area Number |
25289281
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Partial Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Reaction engineering/Process system
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| Research Institution | Sojo University |
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Principal Investigator |
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| Co-Investigator(Kenkyū-buntansha) |
SAKOGUCHI Akihiro 崇城大学, 工学部, 教授 (30196141)
SAKURAGI Mina 崇城大学, 工学部, 助教 (90646829)
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| Project Period (FY) |
2013-04-01 – 2016-03-31
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| Project Status |
Completed (Fiscal Year 2015)
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| Budget Amount *help |
¥17,550,000 (Direct Cost: ¥13,500,000、Indirect Cost: ¥4,050,000)
Fiscal Year 2015: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2014: ¥5,850,000 (Direct Cost: ¥4,500,000、Indirect Cost: ¥1,350,000)
Fiscal Year 2013: ¥8,060,000 (Direct Cost: ¥6,200,000、Indirect Cost: ¥1,860,000)
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| Keywords | バイオディーゼル / トリグリセリド / エステル交換反応 / 溶媒抽出 / 反応分離 / 共炭化 / 脂肪酸メチルエステル / 洗浄処理 / 炭化 / 抽出 / エステル交換 / 曇り点 / パーム油 / ラバーシード |
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| Outline of Final Research Achievements |
A co-production process of biodiesel and activated carbon from rubber seed was proposed. Biodiesel was synthesized by in-situ transesterification of the oil extracted from rubber seed in n-hexane. The fatty acid methyl ester (FAME) yield reached 98 % after 15 min-reaction due to the low extraction of free fatty acids (FFA) from the rubber seed in n-hexane. Co-carbonization of the rubber seed residue after the in-situ transesterification and the crude glycerin containing KOH improved the pore properties of activated carbon product, which indicated methylene blue adsorption ability. Water washing treatment of the synthesized crude palm oil based biodiesel was carried out at 303-343 K to remove saturated FAME selectively. When the ratio of saturated FAME to unsaturated FAME in the biodiesel became the minimum value at the washing temperature of 323 K, the minimum temperature of the cloud point was 279 K.
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Report
(4 results)
Research Products
(19 results)
