| Budget Amount *help |
¥17,680,000 (Direct Cost: ¥13,600,000、Indirect Cost: ¥4,080,000)
Fiscal Year 2015: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Fiscal Year 2014: ¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2013: ¥9,490,000 (Direct Cost: ¥7,300,000、Indirect Cost: ¥2,190,000)
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| Outline of Final Research Achievements |
In this study, we have developed highly active catalysts and efficient catalytic reaction systems for realizing environmentally-friendly new oxidation reactions using molecular oxygen as the terminal oxidant. By utilizing the acid and oxidation properties of heteropoly acids, thiadiazole synthesis through oxidative dimerization of thioamides and regioselective oxidative cyanation of quinolines have been developed. We have developed oxidative α-functionalization of amines and oxidative nucleophilic strategy for functionalization of thiols. Furthermore, several dehydrogenative cross-coupling reactions have been realized by using supported gold catalysts.
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