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Study on reaction site formation at the interface of metal and mixed ionic and electronic conductive oxides and their application to electrochemical devices

Research Project

Project/Area Number 25289284
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Catalyst/Resource chemical process
Research InstitutionThe University of Tokyo

Principal Investigator

Ryuji KIKUCHI  東京大学, 工学(系)研究科(研究院), 准教授 (40325486)

Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥18,200,000 (Direct Cost: ¥14,000,000、Indirect Cost: ¥4,200,000)
Fiscal Year 2015: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2014: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2013: ¥13,910,000 (Direct Cost: ¥10,700,000、Indirect Cost: ¥3,210,000)
Keywords資源・エネルギー有効利用技術 / 混合伝導体 / 燃料電池 / 三相界面 / 反応場 / エネルギー効率化 / 電子伝導性 / イオン伝導性 / ペロブスカイト型酸化物 / パイロクロア型酸化物 / イオン電導性 / ペロブスカイト酸化物 / チタン酸カルシウム / 酸化セリウム
Outline of Final Research Achievements

The effect of transport properties of mixed ionic and electronic conductors (MIEC) on reaction site formation at the interface of metal and MIEC was studied and their application to anodes of fuel cells was conducted. To clarify the influences of MIEC transport properties on anodic reaction characteristics, several types of MIEC with different particle sizes and crystallinity were investigated systematically for the anodes with various mixing ratio of metals to MIEC. It was found that the anodic overpotential was decreased for the increase in the electric conductivity of MIEC when the oxygen ion conductivity remained sufficiently high. In addition, MIEC oxides of high electronic conductivity realized a new method for anode fabrication by infiltration of Ni into a scaffold of the MIEC.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • Research Products

    (15 results)

All 2016 2015 2014 2013

All Journal Article (4 results) (of which Peer Reviewed: 3 results,  Acknowledgement Compliant: 2 results) Presentation (10 results) (of which Int'l Joint Research: 2 results) Book (1 results)

  • [Journal Article] Low Ni-Containing Anodes Using Titanate-Based Perovskite for Methane Direct Internal Reforming Power Generation2015

    • Author(s)
      R. Kikuchi, D. Minori, A. Takagaki, T. Sugawara, S.T. Oyama
    • Journal Title

      ECS Trans.

      Volume: 68 Pages: 1489-1498

    • NAID

      40020511181

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Low Ni-containing anodes using titanate-based perovskites for methane direct internal reforming power generation2015

    • Author(s)
      R. Kikuchi, D. Minori, A. Takagaki, T. Sugawara, S.T. Oyama
    • Journal Title

      ECS Trans.

      Volume: 印刷中

    • NAID

      40020511181

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] ペロブスカイト型酸化物を用いた直接内部改質型SOFCアノード材料の検討2015

    • Author(s)
      菊地隆司
    • Journal Title

      触媒

      Volume: 印刷中

    • Related Report
      2014 Annual Research Report
  • [Journal Article] Fabrication of Low Ni-Containing SOFC Anode Using Mixed Ionic and Electronic Conductors2013

    • Author(s)
      R. Kikuchi, T. Minami, A. Takagaki, T. Sugawara, S.T. Oyama
    • Journal Title

      ECS Trans.

      Volume: 57 Pages: 1201-1210

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Presentation] Solid Oxide Fuel Cell Anode Materials for Methane Direct Dry Reforming Operation2016

    • Author(s)
      R. Kikuchi, K. Miya, T. Mishina, T. Sugawara, A. Takagaki, S.T. Oyama
    • Organizer
      the 5th Asian Conference on Innovative Energy and Environmental Chemical Engineering (ASCON-IEEChE 2016)
    • Place of Presentation
      ホテルニューグランデ、神奈川県横浜市
    • Year and Date
      2016-11-13
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 直接CO2改質発電固体酸化物形燃料電池の燃料極の検討2015

    • Author(s)
      菊地隆司、味谷和之、高垣 敦、菅原 孝、Oyama S. Ted
    • Organizer
      第45回石油・石油化学討論会
    • Place of Presentation
      ウィンクあいち、愛知県名古屋市
    • Year and Date
      2015-11-05
    • Related Report
      2015 Annual Research Report
  • [Presentation] 燃料電池排熱有効利用を目的としたドライリフォーミング触媒の研究2015

    • Author(s)
      関栞、菊地隆司、高垣敦、菅原孝、Oyama, S. Ted
    • Organizer
      化学工学会第47回秋季大会
    • Place of Presentation
      北海道大学、北海道札幌市
    • Year and Date
      2015-09-09
    • Related Report
      2015 Annual Research Report
  • [Presentation] Low Ni-Containing Anodes Using Titanate-Based Perovskites for Methane Direct Internal Reforming Power Generation2015

    • Author(s)
      R. Kikuchi, D. Minori, A. Takagaki, T. Sugawara, and S. T. Oyama
    • Organizer
      ECS Conference on Electrochemical Energy Conversion & Storage with SOFC-XIV
    • Place of Presentation
      Glasgow, Scotland
    • Year and Date
      2015-07-26
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] パイロクロア酸化物を用いた新規SOFCアノードの検討2015

    • Author(s)
      哘崎 智仁、菊地 隆司、高垣 敦、菅原 孝、S. Ted Oyama
    • Organizer
      化学工学会第80年会
    • Place of Presentation
      芝浦工業大学 東京
    • Year and Date
      2015-03-19 – 2015-03-21
    • Related Report
      2014 Annual Research Report
  • [Presentation] パイロクロア酸化物を用いたSOFC新規アノードの検討2014

    • Author(s)
      哘崎 智仁、菊地 隆司、高垣 敦、菅原 孝、S. Ted Oyama
    • Organizer
      第23回SOFC研究発表会
    • Place of Presentation
      科学技術館 サイエンスホール 東京
    • Year and Date
      2014-12-16 – 2014-12-17
    • Related Report
      2014 Annual Research Report
  • [Presentation] ペロブスカイト型酸化物を用いた直接内部改質型SOFCアノード材料の検討2014

    • Author(s)
      法雨 大佑・菊地 隆司・高垣 敦・菅原 孝・S. Ted Oyama
    • Organizer
      化学工学会第79年会
    • Place of Presentation
      岐阜大学、岐阜県
    • Related Report
      2013 Annual Research Report
  • [Presentation] チタン酸塩複合酸化物を用いた固体酸化物形燃料電池アノードの研究2013

    • Author(s)
      哘﨑 智仁・南 辰志・法雨 大佑・菊地 隆司・高垣 敦・菅原 孝・S.Ted Oyama
    • Organizer
      第22回SOFC研究発表会
    • Place of Presentation
      科学技術館サイエンスホール, 東京
    • Related Report
      2013 Annual Research Report
  • [Presentation] Fabrication of Low Ni-Containing SOFC Anode Using Mixed Ionic and Electronic Conductors2013

    • Author(s)
      R. Kikuchi, T. Minami, A. Takagaki, T. Sugawara, S.T. Oyama
    • Organizer
      13th International Symposium on Solid Oxide Fuel Cells
    • Place of Presentation
      Okinawa Convention Center, Okinawa prefecture
    • Related Report
      2013 Annual Research Report
  • [Presentation] チタン酸塩複合酸化物を用いた固体酸化物形燃料電池アノードの研究2013

    • Author(s)
      哘﨑 智仁・南 辰志・菊地 隆司・高垣 敦・菅原 孝・S. Ted Oyama
    • Organizer
      石油学会第62回研究発表会
    • Place of Presentation
      タワーホール船堀、東京
    • Related Report
      2013 Annual Research Report
  • [Book] 次世代燃料電池開発の最前線2013

    • Author(s)
      南辰志、菊地隆司
    • Total Pages
      220
    • Publisher
      シーエムシー出版
    • Related Report
      2013 Annual Research Report

URL: 

Published: 2013-05-21   Modified: 2019-07-29  

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