Generation of novel hierarchical microporous and mesoporous composite materials and elucidation of their catalytic functionality

• Project/Area Number: 25289286
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Partial Multi-year Fund
• Section: 一般
• Research Field: Catalyst/Resource chemical process
• Research Institution: Mie University
• Principal Investigator: Ishihara Atsushi 三重大学, 工学(系)研究科(研究院), 教授 (60212908)
• Co-Investigator(Kenkyū-buntansha): NASU Hiroyuki 三重大学, 大学院工学研究科, 准教授 (20189179) ; HASHIMOTO Tadanori 三重大学, 大学院工学研究科, 准教授 (10271016)
• Project Period (FY): 2013-04-01 – 2016-03-31
• Project Status: Completed (Fiscal Year 2015)
• Budget Amount: ¥18,330,000 (Direct Cost: ¥14,100,000、Indirect Cost: ¥4,230,000); Fiscal Year 2015: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000); Fiscal Year 2014: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000); Fiscal Year 2013: ¥12,480,000 (Direct Cost: ¥9,600,000、Indirect Cost: ¥2,880,000)
• Keywords: 石油精製 / メソ細孔 / 階層構造 / ゼオライト / 接触分解 / 重質炭素資源 / 油脂 / 高オクタン価ガソリン / 階層構造触媒 / ゲル骨格補強法 / ゼオライト含有触媒 / キュリーポイントパイロライザー法 / 減圧軽油 / 常圧残油 / Catalytic cracking / Vacuum gas oil / Atmospheric residue / Large mesopore / Curie point pyrolyzer / Zeolite / Hierarchical structure / ミクロ-メソ-メソ階層構造 / マトリックス

Outline of Final Research Achievements

Zeolite containing mesoporous SiO2-Al2O3 catalysts with three layered-hierarchical structures were prepared using the gel skeletal reinforcement methods. Catalytic cracking of soybean oil was performed using Curie point pyrolyzer (CPP) which was demonstrated as a promising method for estimation of processing of heavy hydrocarbon resources. It was found that the multi/single branch ratios and conversion were improved with increasing hierarchical structure because the catalysts had the larger space.
The gel skeletal reinforcement (GSR) method was developed to prepare silica-aluminas (GSR-SA) with different sizes of large mesopores. The effects of mesopore sizes of catalysts on catalytic cracking of vacuum gas oil (VGO) and atmospheric residue (AR) by CPP method were investigated using the mixed catalysts with zeolite and GSR-SA. It was found that the conversions of VGO increased with increasing pore size of catalysts while the effect of pore size on the conversion of AR was only slight.

Research Products

• [Journal Article] Catalytic cracking reaction of vacuum gas oil and atmospheric residue by zeolite-containing microporous andmesoporous composites using Curie point pyrolyzer (2016)
  • Author(s): Thanita Sonthisawate, Takehiro Nakanishi, Hiroyuki Nasu, Tadanori Hashimoto, Atsushi Ishihara
  • Journal Title: Fuel Processing Technology Volume: 142 Pages: 337-344
  • DOI: 10.1016/j.fuproc.2015.10.016
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Preparation of SiO2 and SiO2-Al2O3 catalysts by gel skeletal reinforcement using hexamethyldisiloxane and acetic anhydride system and elucidation of their catalytic cracking properties as matrices (2016)
  • Author(s): Atsushi Ishihara, Hiroaki Oono, Tadanori Hashimoto and Hiroyuki Nasu
  • Journal Title: Microporous and Mesoporous Materials Volume: 230 Pages: 163-170
  • DOI: 10.1016/j.micromeso.2016.01.025
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Preparation and Photocatalytic Activity of Porous Bi2O3 polymorphism (2016)
  • Author(s): Tadanori Hashimoto, Honami Ohta, Hiroyuki Nasu and Atsushi Ishihara
  • Journal Title: International Journal of Hydrogen Energy Volume: 41 Issue: 18 Pages: 7388-7392
  • DOI: 10.1016/j.ijhydene.2016.03.109
  • Peer Reviewed
• [Journal Article] Catalytic cracking reaction of soybean oil by zeolite-containing microporous and mesoporous mixed catalysts using Curie point pyrolyzer (2016)
  • Author(s): Thanita Sonthisawate, Hiroyuki Nasu, Tadanori Hashimoto and Atsushi Ishihara
  • Journal Title: Journal of the Japan Petroleum Institute Volume: 59
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] 時評[「認定トライみたいなもの」 (2016)
  • Author(s): 石原 篤
  • Journal Title: ペトロテック Volume: 39 Pages: 83-83
  • Open Access
• [Journal Article] Effects of Types of Metal Oxides on Hydrothermal Gasification of Phenol over Novel Metal Oxide–carbon Composite Supported Ni Catalysts Prepared by Sol-gel Method (2015)
  • Author(s): Atsushi Ishihara, Kenta Imanishi, Tadanori Hashimoto, Hiroyuki Nasu
  • Journal Title: Journal of the Japan Petroleum Institute Volume: 58 Issue: 5 Pages: 302-311
  • DOI: 10.1627/jpi.58.302
  • NAID: 130005106837
  • ISSN: 1346-8804, 1349-273X
  • Year and Date: 2015-09-01
  • Peer Reviewed / Open Access
• [Journal Article] Catalytic Cracking of VGO by Zeolite–kaolin Mixed Catalysts Using Curie Point Pyrolyzer (2015)
  • Author(s): Atsushi Ishihara, Kentarou Kimura, Tadanori Hashimoto, Hiroyuki Nasu
  • Journal Title: Journal of the Japan Petroleum Institute Volume: 58 Issue: 3 Pages: 169-175
  • DOI: 10.1627/jpi.58.169
  • NAID: 130005085439
  • ISSN: 1346-8804, 1349-273X
  • Year and Date: 2015-05-01
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] Preparation of Alumina-supported Cobalt–molybdenum Catalysts by Sol-gel Method and Hydrodesulfurization Activities (2015)
  • Author(s): Atsushi Ishihara, Shohei Tanaka, Mina Aiba, Tadanori Hashimoto, Hiroyuki Nasu
  • Journal Title: Journal of the Japan Petroleum Institute Volume: 58 Issue: 2 Pages: 103-109
  • DOI: 10.1627/jpi.58.103
  • NAID: 130005068512
  • ISSN: 1346-8804, 1349-273X
  • Year and Date: 2015-03-01
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Hydrothermal gasification of phenol water on novel carbon-supported Ni catalysts prepared by the sol-gel method using tartaric acid and alminum tri-sec-butoxide (2015)
  • Author(s): Atsushi Ishihara, Tatsuya Imai, Tadanori Hashimoto, Hiroyuki Nasu
  • Journal Title: Fuel Processing Technology Volume: 136 Pages: 34-40
  • DOI: 10.1016/j.fuproc.2014.07.040
  • Peer Reviewed
• [Journal Article] Drastic Dependence of the pH Sensitivity of Fe2O3-Bi2O3-B2O3 Hydrophobic Glasses with Composition (2015)
  • Author(s): Tadanori Hashimoto, Fumiya Murayama, Masashi Nakao, Hiroyuki Nasu, Atsushi Ishihara and Yuji Nishio
  • Journal Title: Materials Volume: 8 Issue: 12 Pages: 8624-8629
  • DOI: 10.3390/ma8125480
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] Preparation and properties of sol-gel derived CuFeO2 thin films by dip-coating technique (2015)
  • Author(s): Hiroyuki Nasu、Masayuki Hasegawa, Tadanori Hashimoto Atsushi Ishihara, Koji Fujita and Katsuhisa Tanaka
  • Journal Title: J. Ceram. Soc. Jpn. Volume: 123 Pages: 448-451
  • NAID: 130005068654
  • Peer Reviewed
• [Journal Article] 接触分解触媒のための新しいメソ孔材料の調製とそれらの重質炭素資源接触分解反応特性 (2015)
  • Author(s): 石原 篤
  • Journal Title: 触媒 Volume: 57 Pages: 87-93
  • Acknowledgement Compliant
• [Journal Article] 時評「スマホがほしい」 (2015)
  • Author(s): 石原 篤
  • Journal Title: 触媒 Volume: 57 Pages: 189-189
• [Journal Article] Catalytic Cracking of Soybean Oil by Hierarchical Zeolite Containing Mesoporous Silica-Aluminas Using a Curie Point Pyrolyzer (2015)
  • Author(s): Atsushi Ishihara Daisuke Kawaraya Thanita, Sonthisawate Kentaro Kimura Tadanori Hashimoto Hiroyuki Nasu
  • Journal Title: Journal of Molecular Catalysis A: Chemical Volume: 396 Pages: 310-318
  • DOI: 10.1016/j.molcata.2014.10.010
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] 7.Effects of Types of Metal Oxides on Hydrothermal Gasification of Phenol over Novel Metal Oxide-Carbon Composite Supported Ni Catalysts Prepared by Sol-Gel Method (2015)
  • Author(s): Atsushi Ishihara, Kenta Imanishi, Tadanori Hashimoto, Hiroyuki Nasu
  • Journal Title: Journal of the Japan Petroleum Institute Volume: 58 Pages: 0-1
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] 接触分解触媒のための新しいメソ孔材料の調製とそれらの重質炭素資源接触分解 (2015)
  • Author(s): 石原 篤
  • Journal Title: 触媒 Volume: 57 Pages: 87-93
  • Acknowledgement Compliant
• [Journal Article] Preparation of amorphous silica-alumina using polyethylene glycol and its role for matrix in catalytic cracking of n-dodecane (2014)
  • Author(s): Atsushi Ishihara, Takanori Wakamatsu, Hiroyuki Nasu, Tadanori Hashimoto
  • Journal Title: Applied Catalysis A: General Volume: 478 Pages: 58-65
  • DOI: 10.1016/j.apcata.2014.03.016
  • Peer Reviewed
• [Journal Article] Hydrocracking of soybean oil using zeolite-alumina composite supported NiMo catalysts (2014)
  • Author(s): Atsushi Ishihara, Naoya Fukui, Hiroyuki Nasu, Tadanori Hashimoto
  • Journal Title: Fuel Volume: 134 Pages: 611-617
  • DOI: 10.1016/j.fuel.2014.06.004
  • NAID: 130004669641
  • Peer Reviewed
• [Journal Article] Catalytic Cracking of VGO by Hierarchical Y Zeolite Containing Mesoporous Silica-Alumina Catalysts Using Curie Point Pyrolyzer (2014)
  • Author(s): Ishihara, A.; Kimura, K.; Hashimoto, T.; Nasu, H.
  • Journal Title: J. Jpn. Petrol. Inst. Volume: 57 Pages: 34-45
  • NAID: 130003392364
  • Peer Reviewed
• [Journal Article] Hydrocracking of 1-methylnaphthalene/decahydronaphthalene mixture (2013)
  • Author(s): Atsushi Ishihara, Tomohiro Itoh, Hiroyuki Nasu, Tadanori Hashimoto, Takao Doi
  • Journal Title: Fuel Processing Technology Volume: 116 Pages: 222-227
  • DOI: 10.1016/j.fuproc.2013.07.001
  • Peer Reviewed
• [Presentation] Selective dehydrocyclization of n-heptane using zeolite-alumina composite supported NiMo catalysts (2015)
  • Author(s): Atsushi Ishihara, Akihiro Itoh, Hiroyuki Nasu, Tadanori Hashimoto
  • Organizer: Pacifichem 2015
  • Place of Presentation: Hawaii, Honolulu, USA
  • Year and Date: 2015-12-15
  • Int'l Joint Research
• [Presentation] Estimation of catalytic cracking reaction of model compounds using zeolite-containing hierarchical silica and silica-alumina catalysts by Curie point pyrolyzer (2015)
  • Author(s): Atsushi Ishihara, Masashi Ninomiya, Hiroyuki Nasu, Tadanori Hashimoto
  • Organizer: Pacifichem 2015
  • Place of Presentation: Hawaii, Honolulu, USA
  • Year and Date: 2015-12-15
  • Int'l Joint Research
• [Presentation] Selective dehydrocyclization- cracking of soybean oil using zeolite-alumina composite supported PtNiMo catalysts (2015)
  • Author(s): Atsushi Ishihara, Takumi Ogiyama, Tadanori Hashimoto, Hiroyuki Nasu
  • Organizer: Pacifichem 2015
  • Place of Presentation: Hawaii, Honolulu, USA
  • Year and Date: 2015-12-15
  • Int'l Joint Research
• [Presentation] Catalytic cracking of heavy oil by hierarchical Y zeolite containing mesoporous silica-aluminas using Curie point pyrolyzer (2015)
  • Author(s): Thanita Sonthisawate, Takehiro Nakanishi, Tadanori Hashimoto, Hiroyuki Nasu, Atsushi Ishihara
  • Organizer: The 5th International Symposium for Sustainability by Engineering at MIU (IS2 EMU 2015)
  • Place of Presentation: 三重大学 （三重県・津市）
  • Year and Date: 2015-09-29
  • Int'l Joint Research
• [Presentation] Hydrocracking of Atmospheric Residue by Zeolite-Alumina Containing Composite-Supported NiMo Catalysts Using Curie Point Pyrolyzer (2015)
  • Author(s): Syunya Ishida, Hiroyuki Nasu, Tadanori Hashimoto, Atsushi Ishihara
  • Organizer: The 5th International Symposium for Sustainability by Engineering at MIU (IS2 EMU 2015)
  • Place of Presentation: 三重大学 （三重県・津市）
  • Year and Date: 2015-09-29
  • Int'l Joint Research
• [Presentation] Selective Dehydrocyclization of n-Heptane Using the Zeolite-Alumina Composite-Supported NiMo Catalysts (2015)
  • Author(s): Akihiro Itoh, Tadanori Hashimoto, Hiroyuki Nasu, Atsushi Ishihara
  • Organizer: The 5th International Symposium for Sustainability by Engineering at MIU (IS2 EMU 2015)
  • Place of Presentation: 三重大学 （三重県・津市）
  • Year and Date: 2015-09-29
  • Int'l Joint Research
• [Presentation] Selective Dehydrocyclization-Cracking of Soybean Oil Using Zeolite-Alumina Composite Supported PtNiMo Catalysts (2015)
  • Author(s): Takumi Ogiyama, Hiroyuki Nasu, Tadanori Hashimoto, Atsushi Ishihara
  • Organizer: The 5th International Symposium for Sustainability by Engineering at MIU (IS2 EMU 2015)
  • Place of Presentation: 三重大学 （三重県・津市）
  • Year and Date: 2015-09-29
  • Int'l Joint Research
• [Presentation] Analysis of Catalytic Cracking of C12-C32 Hydrocarbons by Hierarchical Zeolite-Containing Silica-Aluminas Using Curie Point Pyrolyzer (2015)
  • Author(s): Masashi Ninomiya , Hiroyuki Nasu, Tadanori Hashimoto, Atsushi Ishihara
  • Organizer: The 5th International Symposium for Sustainability by Engineering at MIU (IS2 EMU 2015)
  • Place of Presentation: 三重大学 （三重県・津市）
  • Year and Date: 2015-09-29
  • Int'l Joint Research
• [Presentation] Preparation of Novel Carbon-Oxide Composite Supported Cobalt Catalysts and their Reactivity for Fischer-Tropsch Synthesis in the Presence of Solvent (2015)
  • Author(s): Yusuke Maejima, Hiroyuki Nasu, Tadanori Hashimoto, Atsushi Ishihara
  • Organizer: The 5th International Symposium for Sustainability by Engineering at MIU (IS2 EMU 2015), September 29th 2015
  • Place of Presentation: 三重大学 （三重県・津市）
  • Year and Date: 2015-09-29
  • Int'l Joint Research
• [Presentation] Preparation and Photocatalytic Activity of TiO2-Bi2O3 (2015)
  • Author(s): Syunki Okada, Tadanori Hashimoto, Hiroyuki Nasu, Atsushi Ishihara
  • Organizer: The 5th International Symposium for Sustainability by Engineering at MIU (IS2 EMU 2015)
  • Place of Presentation: 三重大学 （三重県・津市）
  • Year and Date: 2015-09-29
  • Int'l Joint Research
• [Presentation] Preparation of Novel Carbon-Oxide Composite Supported Cobalt Catalysts and Their Reactivity for Fischer-Tropsch Synthesis in the Presence of Solvent (2015)
  • Author(s): Atsushi Ishihara, Yusuke Maejima, Hiroyuki Nasu, Tadanori Hashimoto
  • Organizer: The 13th China-Japan Coal and C1 Chemistry Symposium
  • Place of Presentation: Dhunghang, China
  • Year and Date: 2015-08-31
  • Int'l Joint Research
• [Presentation] Elucidation of Catalytic Cracking of Soybean Oil by Zeolite-Mesoporous Oxides Composites Using Curie Point Pyrolyzer (2015)
  • Author(s): Atsushi Ishihara, Thanita Sonthisawate, Hiroyuki Nasu and Tadanori Hashimoto
  • Organizer: The 13th China-Japan Coal and C1 Chemistry Symposium
  • Place of Presentation: Dhunghang, China
  • Year and Date: 2015-08-31
  • Int'l Joint Research
• [Presentation] Catalytic Cracking of Soybean Oil by Different Hierarchical Zeolite Containing Mesoporous SiO2-Al2O3 Using a Curie Point Pyrolyzer (2015)
  • Author(s): Atsushi Ishihara, Daisuke Kawaraya, Thanita Sonthisawate, Hiroyuki Nasu, Tadanori Hashimoto
  • Organizer: ACS, National Meeting, Div. Energy Fuels, Boston 2015
  • Place of Presentation: Boston (USA)
  • Year and Date: 2015-08-16
  • Int'l Joint Research
• [Presentation] Catalytic Cracking of Heavy Oils by Hierarchical Zeolite Containing Mesoporous Silica-Aluminas with Large Mesopore Using Curie Point Pyrolyzer (2015)
  • Author(s): Atsushi Ishihara, Takehiro Nakanishi, Thanita Sonthisawate, Tadanori Hashimoto, Hiroyuki Nasu
  • Organizer: ACS, National Meeting, Div. Energy Fuels, Boston 2015
  • Place of Presentation: Boston (USA)
  • Year and Date: 2015-08-16
  • Int'l Joint Research
• [Presentation] Preparation and Photocatalytic Activity of Porous Bi2O3 (2015)
  • Author(s): Atsushi Ishihara, Tadanori Hashimoto, Honami Ohta, Hiroyuki Nasu
  • Organizer: ACS, National Meeting, Div. Energy Fuels, Boston 2015
  • Place of Presentation: Boston (USA)
  • Year and Date: 2015-08-16
  • Int'l Joint Research
• [Presentation] Catalytic cracking of soybean oil by three-layered hierarchical zeolite containing mesoporous SiO2-Al2O3 using a Curie point pyrolyzer (2015)
  • Author(s): Atsushi Ishihara, Daisuke Kawaraya, Thanita Sonthisawate, Tadanori Hashimoto, Hiroyuki Nasu
  • Organizer: ZMPC2015
  • Place of Presentation: 札幌コンベンションセンター （北海道・札幌市）
  • Year and Date: 2015-06-28
  • Int'l Joint Research
• [Presentation] Preparation of SiO2 and SiO2-Al2O3 catalysts by gel skeletal reinforcement and analysis of catalytic cracking reaction of n-dodecane (2015)
  • Author(s): Atsushi Ishihara, Hiroaki Oono, Tadanori Hashimoto, Hiroyuki Nasu
  • Organizer: ZMPC2015
  • Place of Presentation: 札幌コンベンションセンター （北海道・札幌市）
  • Year and Date: 2015-06-28
  • Int'l Joint Research
• [Presentation] ゼオライト-アルミナ複合担体担持NiMo触媒を用いたヘプタンの選択的環化脱水素反応 (2015)
  • Author(s): 石原 篤・伊藤晃寛・橋本忠範・那須弘行
  • Organizer: 第95回日本化学会春季年会
  • Place of Presentation: 千葉、日大船橋キャンパス
  • Year and Date: 2015-03-27
• [Presentation] ゼオライト-アルミナ複合担体担持遷移金属硫化物触媒による油脂の選択的環化脱水素化分解反応 (2015)
  • Author(s): 石原 篤・荻山拓巳・橋本忠範・那須弘行
  • Organizer: 第115回触媒討論会
  • Place of Presentation: 東京、成蹊大学
  • Year and Date: 2015-03-23
• [Presentation] 「最近の石油精製関連触媒の研究から」水素化脱硫触媒および接触分解触媒 (2014)
  • Author(s): 石原 篤
  • Organizer: 化学工学会 「賛助会員の会」
  • Place of Presentation: 東ソー四日市事業所
  • Year and Date: 2014-12-12
  • Invited
• [Presentation] ゲル骨格補強法を用いた新しいメソ多孔性物質の調製とそれらをマトリックスとして用いた油脂の接触分解特性 (2014)
  • Author(s): 石原 篤・瓦谷大祐・Thanita Sonthisawate・橋本忠範・那須弘行
  • Organizer: 平成26年度化学工学会流動床シンポジウム
  • Place of Presentation: 岡山理科大学
  • Year and Date: 2014-12-11
• [Presentation] キュリー・ポイント・パイロライザー法を用いた階層構造を持つゼオライト含有シリカーアルミナ触媒による接触分解反応の解析 (2014)
  • Author(s): 二宮 将・橋本忠範・那須弘行・石原 篤
  • Organizer: 2014年度石油学会・日本エネルギー学会関西支部合同発表会
  • Place of Presentation: 京都大学桂
  • Year and Date: 2014-12-05
• [Presentation] キュリー・ポイント・パイロライザー法を用いたゼオライト含有ミクロ-メソ多孔性複合体による重質油接触分解の解析 (2014)
  • Author(s): 石原 篤，中西健博，橋本忠範，那須弘行
  • Organizer: 第51回石炭科学会議
  • Place of Presentation: 東北大学
  • Year and Date: 2014-10-23
• [Presentation] Catalytic cracking of soybean oil by zeolite containing microporous and mesoporous composites using a Curie point pyrolyzer (2014)
  • Author(s): Thanita Sonthisawate, 橋本忠範, 那須弘行,石原 篤
  • Organizer: 石油学会旭川大会
  • Place of Presentation: 旭川、グランドホテル
  • Year and Date: 2014-10-17
• [Presentation] キュリー・ポイント・パイロライザーを用いたゼオライト-アルミナ複合担体担持NiMo触媒による常圧残油の水素化分解 (2014)
  • Author(s): 石田峻也・橋本忠範・那須弘行・石原 篤
  • Organizer: 石油学会旭川大会
  • Place of Presentation: 旭川、グランドホテル
  • Year and Date: 2014-10-16
• [Presentation] ゼオライト-アルミナ複合担体担持NiMo触媒による1-メチルナフタレンの水素化分解 (2014)
  • Author(s): 天野将佳・橋本忠範・那須弘行・石原 篤
  • Organizer: 石油学会旭川大会
  • Place of Presentation: 旭川、グランドホテル
  • Year and Date: 2014-10-16
• [Presentation] キュリー・ポイント・パイロライザー法を用いた三層の階層構造を有するゼオライト含有触媒による大豆油の接触分解 (2014)
  • Author(s): 石原 篤・瓦谷大祐・Thanita Sonthisawate・橋本忠範・那須弘行
  • Organizer: 石油学会旭川大会
  • Place of Presentation: 旭川、グランドホテル
  • Year and Date: 2014-10-16
• [Presentation] ヘキサメチルジシロキサンを用いた大きなメソ細孔を有するゲル骨格補強法シリカの調製と接触分解反応特性 (2014)
  • Author(s): 石原 篤・大野裕章・橋本忠範・那須弘之
  • Organizer: 第114回触媒討論会
  • Place of Presentation: 広島大学
  • Year and Date: 2014-09-27
• [Presentation] Effect of supports on hydrocracking of aromatic hydrocarbon using NiMo supported zeolite-alumina and silica-alumina composite catalysts (2014)
  • Author(s): Masayoshi AMANO, Tadanori HASHIMOTO, Hiroyuki NASU, Atsushi ISHIHARA
  • Organizer: 2014年度三重大学工学研究科国際シンポジウム
  • Place of Presentation: 三重大学
  • Year and Date: 2014-09-17
• [Presentation] Catalytic cracking of soybean oil by different hierarchical zeolite containing mesoporous SiO2-Al2O3 using a curie point pyrolyzer (2014)
  • Author(s): Daisuke Kawaraya, Tadanori Hashimoto, Hiroyuki Nasu, Atsushi Ishihara
  • Organizer: 2014年度三重大学工学研究科国際シンポジウム
  • Place of Presentation: 三重大学
  • Year and Date: 2014-09-17
• [Presentation] Preparation and Photocatalytic Activity of Porous Bi2O3 (2014)
  • Author(s): Honami Ohta, Tadanori Hashimoto, Hiroyuki Nasu, Atsushi Ishihara
  • Organizer: 2014年度三重大学工学研究科国際シンポジウム
  • Place of Presentation: 三重大学
  • Year and Date: 2014-09-17
• [Presentation] Preparation of SiO2 and SiO2-Al2O3 catalysts by gel skeletal reinforcement and analysis of catalytic cracking reaction of n-dodecane (2014)
  • Author(s): Hiroaki Ono, Tadanori Hashimoto, Hiroyuki Nasu, Atsushi Ishihara
  • Organizer: 2014年度三重大学工学研究科国際シンポジウム
  • Place of Presentation: 三重大学
  • Year and Date: 2014-09-17
• [Presentation] Catalytic cracking of heavy oil by hierarchical zeolite containing mesoporous silica-aluminas using Curie point pyrolyzer (2014)
  • Author(s): Takehiro Nakanishi・Tadanori Hashimoto・Hiroyuki Nasu・Atsushi Ishihara
  • Organizer: 2014年度三重大学工学研究科国際シンポジウム
  • Place of Presentation: 三重大学
  • Year and Date: 2014-09-17
• [Presentation] Analysis of adsorptive desulfurization reaction characteristics and preparation of Ni / ZnO-supported composite absorbents (2014)
  • Author(s): Daisuke Yamamoto・Tadanori Hashimoto・Hiroyuki Nasu・Atsushi Ishihara
  • Organizer: 2014年度三重大学工学研究科国際シンポジウム
  • Place of Presentation: 三重大学
  • Year and Date: 2014-09-17
• [Presentation] HYDROCRACKING OF 1-METHYLNAPHTHALENE CATALYZED BY ZEOLITE-ALUMINA COMPOSITE SUPPORTED NiMo CATALYSTS (2014)
  • Author(s): Atsushi ISHIHARA, Masayoshi AMANO, Tadanori HASHIMOTO, Hiroyuki NASU
  • Organizer: ACS National Meeting
  • Place of Presentation: San Francisco, Convention Center
  • Year and Date: 2014-08-14
• [Presentation] CATALYTIC CRACKING OF VACUUM GAS OIL BY HIERARCHICAL ZEOLITE CONTAINING SILICA-ALUMINAS USING CURIE POINT PYROLYZER (2014)
  • Author(s): Atsushi Ishihara, Kentaro Kimura, Tadanori Hashimoto and Hiroyuki Nasu
  • Organizer: ACS National Meeting
  • Place of Presentation: San Francisco, Convention Center
  • Year and Date: 2014-08-12
• [Presentation] 尿素を用いて調製した多孔性Bi2O3の光触媒活性 (2014)
  • Author(s): 石原 篤，太田帆奈美，橋本忠範，那須弘行
  • Organizer: 第23回日本エネルギー学会大会
  • Place of Presentation: 九州大学箱崎
  • Year and Date: 2014-07-19
• [Presentation] Preparation of SiO2-TiO2 and SiO2-ZrO2 catalysts by gel skeletal reinforcement and elucidation of their catalytic cracking properties as matrices (2014)
  • Author(s): Atsushi Ishihara, Daichi Sekii, Hiroyuki Nasu, Tadanori Hashimoto
  • Organizer: TOCAT7
  • Place of Presentation: Kyoto Teｒｒsa
  • Year and Date: 2014-06-02
• [Presentation] Catalytic cracking of vacuum gas oil by zeolite-kaolin composite catalysts using Curie point pyrolyzer (2014)
  • Author(s): Atsushi Ishihara, Kentaro Kimura, Hiroyuki Nasu, Tadanori Hashimoto
  • Organizer: TOCAT7
  • Place of Presentation: Kyoto Teｒｒsa
  • Year and Date: 2014-06-02
• [Presentation] キュリー・ポイント・パイロライザーを用いたゼオライト含有ミクロ-メソ多孔性複合体による重質炭素資源の接触分解反応 (2014)
  • Author(s): 中西健博・橋本忠範・那須弘行・石原 篤
  • Organizer: 石油学会 第57回年会
  • Place of Presentation: 船堀タワーホール
  • Year and Date: 2014-05-28
• [Presentation] ゲル骨格補強法を用いた大きなメソ細孔を有するシリカ及びシリカ-アルミナの調製とn-ドデカンの接触分解反応評価 (2014)
  • Author(s): 大野裕章・橋本忠範・那須弘行・石原 篤
  • Organizer: 石油学会 第57回年会
  • Place of Presentation: 船堀タワーホール
  • Year and Date: 2014-05-28
• [Presentation] 尿素を用いた多孔性Bi2O3の作製とその光触媒活性の評価 (2014)
  • Author(s): 太田帆奈美・橋本忠範・那須弘行・石原 篤
  • Organizer: 石油学会 第57回年会
  • Place of Presentation: 船堀タワーホール
  • Year and Date: 2014-05-28
• [Presentation] キュリー・ポイント・パイロライザー法を用いたゼオライト-アルミナ複合担体担持NiMo触媒による常圧残油の水素化分解 (2014)
  • Author(s): 石田峻也・橋本忠範・那須弘行・石原 篤
  • Organizer: 石油学会 第57回年会JPIJSポスターセッション
  • Place of Presentation: 船堀タワーホール
  • Year and Date: 2014-05-28
• [Presentation] キュリー・ポイント・パイロライザー法を用いた階層構造を持つゼオライト含有シリカ-アルミナ触媒による接触分解反応の解析 (2014)
  • Author(s): 二宮 将・橋本忠範・那須弘行・石原 篤
  • Organizer: 石油学会 第57回年会JPIJSポスターセッション
  • Place of Presentation: 船堀タワーホール
  • Year and Date: 2014-05-28
• [Presentation] 階層構造を持つゼオライト含有シリカ-アルミナの調製とキュリー・ポイント・パイロライザー法による重質炭素資源の接触分解の解析 (2014)
  • Author(s): 石原 篤
  • Organizer: 日本学術振興会 第148委員会研究会
  • Place of Presentation: 東京、神田エッサムホール
  • Year and Date: 2014-05-15
  • Invited
• [Presentation] キュリー・ポイント・パイロライザー法による減圧軽油の接触分解反応評価 (2014)
  • Author(s): 石原 篤・木村健太郎・橋本忠範・那須弘行
  • Organizer: 第113回触媒討論会
  • Place of Presentation: 豊橋ロシワールホテル
• [Presentation] PREPARATION OF SiO2 AND SiO2-Al2O3 CATALYSTS BY GEL SKELETAL REINFORCEMENT AND ELUCIDATION OF THEIR CATALYTIC CRACKING PROPERTIES AS MATRICES (2014)
  • Author(s): Atsushi Ishihara, Hiroaki Oono, Tadanori Hashimoto and Hiroyuki Nasu
  • Organizer: アメリカ化学会ナショナルミーティング
  • Place of Presentation: Dallas Convension Center
• [Presentation] CATALYTIC CRACKING CHARACTERISTICS OF CATALYSTS USING VARIOUS OXIDES WITH DIFFERENT PORE DIAMETER AS MATRICES (2014)
  • Author(s): Atsushi Ishihara, Kosuke Tatebe, Hiroyuki Nasu and Tadanori Hashimoto
  • Organizer: アメリカ化学会ナショナルミーティング
  • Place of Presentation: Dallas Convension Center
• [Presentation] ミクロ-メソ-メソの三層構造をもつゼオライト含有シリカ-アルミナによる油脂の接触分解 (2014)
  • Author(s): 石原 篤・瓦谷大祐・橋本忠範・那須弘行
  • Organizer: 日本化学会第94回春季年会
  • Place of Presentation: 名古屋大学
• [Presentation] キュリー・ポイント・パイロライザーを用いた階層構造をもつゼオライト含有シリカ-アルミナによる大豆油の接触分解 (2013)
  • Author(s): 石原 篤，瓦谷大祐，橋本忠範，那須弘之
  • Organizer: 化学工学会反応工学部会 流動床シンポジウム
  • Place of Presentation: 桐生
• [Presentation] 階層構造を持つゼオライト含有メソ多孔性シリカ－アルミナの調製とその接触分解特性の解析 (2013)
  • Author(s): 石原 篤
  • Organizer: 中部化学連合学協会研究発表会
  • Place of Presentation: 静岡大学
  • Invited
• [Remarks] 石原 篤
  • URL: http://www.inorg.chem.mie-u.ac.jp/page1/page1.html