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Development of photocatalysts for photo-SCR of NH3 at high NOx flow rate

Research Project

Project/Area Number 25289287
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Catalyst/Resource chemical process
Research InstitutionKyoto University

Principal Investigator

Tanaka Tsunehiro  京都大学, 工学(系)研究科(研究院), 教授 (70201621)

Co-Investigator(Kenkyū-buntansha) TERAMURA Kentaro  京都大学, 大学院工学研究科, 准教授 (80401131)
Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥17,680,000 (Direct Cost: ¥13,600,000、Indirect Cost: ¥4,080,000)
Fiscal Year 2015: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2014: ¥5,980,000 (Direct Cost: ¥4,600,000、Indirect Cost: ¥1,380,000)
Fiscal Year 2013: ¥7,930,000 (Direct Cost: ¥6,100,000、Indirect Cost: ¥1,830,000)
Keywords光アンモニア脱硝 / TiO2 / N3色素 / NOx / NH3 / 可視光応答 / NH3-SCR / 色素増感 / 可視光応答化 / N3 dye
Outline of Final Research Achievements

NOx, which is present in the exhaust gas of stationary emission sources, is removed by selective catalytic reduction with NH3 (NH3-SCR) over vanadium oxide-based catalysts according to the following equation: (4NO + 4NH3 + O2 → 4N2 + 6H2O). We have reported the photo-assisted selective catalytic reduction (photo-SCR) of NO with NH3 in the presence of O2 over TiO2 photocatalysts under UV-light irradiation. It was espected that various dye-modified photocatalyst work efficiently as a visible-light response photocatalyst in the gas phase. we investigated photo-SCR under visible-light irradiation using TiO2 photocatalysts modified with N3-dye to improve the activity of this photocatalytic system.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • Research Products

    (13 results)

All 2015 2014 2013 Other

All Journal Article (4 results) (of which Peer Reviewed: 4 results,  Acknowledgement Compliant: 1 results) Presentation (9 results) (of which Invited: 2 results)

  • [Journal Article] Effects of SO2 on the Performance of Selective Catalytic Reduction of NO with NH3 over a TiO2 Photocatalyst2015

    • Author(s)
      Akira Yamamoto, Kentaro Teramura, Saburo Hosokawa, Tsunehiro Tanaka
    • Journal Title

      Science and Technology of Advanced Materials

      Volume: 16 Issue: 2 Pages: 1-9

    • DOI

      10.1088/1468-6996/16/2/024901

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Visible-Light-Assisted Selective Catalytic Reduction of NO with NH3 over Dye-Modified TiO2 Photocatalysts2015

    • Author(s)
      Akira Yamamoto, Yuto Mizuno, Kentaro Teramura,Saburo Hosokawa, Tetsuya Shishido, Tsunehiro Tanaka
    • Journal Title

      ChemCatChem

      Volume: 7 Issue: 12 Pages: 1818-1825

    • DOI

      10.1002/cctc.201500207

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Visible-light-assisted selective catalytic reduction of NO with NH3 on porphyrin derivative-modified TiO2 photocatalysts2015

    • Author(s)
      A. Yamamoto, Y. Mizuno, K. Teramura, S. Hosokawa, T. Shishido, T. Tanaka
    • Journal Title

      Catal. Sci. Technol.

      Volume: 5 Issue: 1 Pages: 556-561

    • DOI

      10.1039/c4cy00598h

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Effects of reaction temperature on the photocatalytic activity of photo-SCR of NO with NH3 over a TiO2 photocatalyst2013

    • Author(s)
      Akira Yamamoto, Yuto Mizuno, Kentaro Teramura, Tetsuya Shishido, Tunehiro Tanaka
    • Journal Title

      Catalysis Science & Technology

      Volume: 3 Issue: 7 Pages: 1771-1775

    • DOI

      10.1039/c3cy00022b

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Presentation] 色素修飾TiO2触媒上での可視光アンモニア脱硝2015

    • Author(s)
      山本旭、寺村謙太郎、細川三郎、田中庸裕
    • Organizer
      第115回触媒討論会
    • Place of Presentation
      成蹊大学
    • Year and Date
      2015-03-23 – 2015-03-24
    • Related Report
      2014 Annual Research Report
  • [Presentation] 色素増感型光触媒を用いた可視光照射下でのアンモニア脱硝2014

    • Author(s)
      山本旭、寺村謙太郎、細川三郎、田中庸裕
    • Organizer
      第33回 固体・表面光化学討論会
    • Place of Presentation
      京都大学 楽友会館
    • Year and Date
      2014-12-16 – 2014-12-17
    • Related Report
      2014 Annual Research Report
  • [Presentation] ポルフィリン修飾TiO2を用いた可視光アンモニア脱硝の高活性化2014

    • Author(s)
      水野由克,山本旭,寺村謙太郎,細川三郎,田中庸裕
    • Organizer
      第7回触媒表面化学研究発表会
    • Place of Presentation
      関西大学
    • Year and Date
      2014-10-31
    • Related Report
      2014 Annual Research Report
  • [Presentation] 可視光応答型ポルフィリン修飾TiO2を用いたアンモニア脱硝2014

    • Author(s)
      水野由克、山本旭、寺村謙太郎、細川三郎、田中庸裕
    • Organizer
      第114回触媒討論会
    • Place of Presentation
      広島大学 東広島キャンパス
    • Year and Date
      2014-09-25 – 2014-09-27
    • Related Report
      2014 Annual Research Report
  • [Presentation] 色素修飾TiO2上でのアンモニア脱硝における色素の役割2014

    • Author(s)
      山本旭、寺村謙太郎、細川三郎、田中庸裕
    • Organizer
      第33回光がかかわる触媒化学シンポジウム
    • Place of Presentation
      東京理科大学 葛飾キャンパス
    • Year and Date
      2014-07-18
    • Related Report
      2014 Annual Research Report
  • [Presentation] Heat-Promoted Selective Catalytic Reduction of NO with NH3 over a TiO2 photocatalyst2013

    • Author(s)
      A. Yamamoto, Y. Mizuno, K. Teramura, T. Shishido, T. Tanaka
    • Organizer
      The 6th Asia-PAcific Congress on Catalysis
    • Place of Presentation
      Taipei, Taiwan
    • Related Report
      2013 Annual Research Report
  • [Presentation] 光触媒を用いたアンモニア脱硝の高活性化

    • Author(s)
      山本旭、寺村謙太郎、宍戸哲也、田中庸裕
    • Organizer
      第32回光がかかわる触媒化学シンポジウム
    • Place of Presentation
      東京工業大学大岡山キャンパス 蔵前ホール
    • Related Report
      2013 Annual Research Report
  • [Presentation] 固体表面上での分子の光活性化

    • Author(s)
      寺村謙太郎
    • Organizer
      第248回応用セラミックス研究所講演会 (第18回先端無機材料講演会)
    • Place of Presentation
      東京工業大学応用セラミックス研究所・R3棟6階大ゼミ室
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 固体表面での分子の光活性化

    • Author(s)
      寺村謙太郎
    • Organizer
      平成25年度第1回キャタリストクラブ例会
    • Place of Presentation
      大阪大学中之島センター7階702号室(大阪市)
    • Related Report
      2013 Annual Research Report
    • Invited

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Published: 2013-05-21   Modified: 2019-07-29  

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