Development of visivle-light responsive organic-inorganic hybrid catalysts for selective reduction
| Project/Area Number |
25289289
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Partial Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Catalyst/Resource chemical process
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| Research Institution | Osaka University |
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Principal Investigator |
Mori Kohsuke 大阪大学, 工学(系)研究科(研究院), 准教授 (90423087)
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| Project Period (FY) |
2013-04-01 – 2016-03-31
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| Project Status |
Completed (Fiscal Year 2015)
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| Budget Amount *help |
¥16,120,000 (Direct Cost: ¥12,400,000、Indirect Cost: ¥3,720,000)
Fiscal Year 2015: ¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2014: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2013: ¥8,060,000 (Direct Cost: ¥6,200,000、Indirect Cost: ¥1,860,000)
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| Keywords | 光触媒 / 金属錯体 / 還元反応 / ハイブリッド / 講難度還元反応 / 有機－無機ハイブリッド / 水素 / 二酸化炭素 / 太陽エネルギー / 高難度還元反応 / 有機無機ハイブリッド / 水素エネルギー |
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| Outline of Final Research Achievements |
In this study, hybrid photocatalysts that enable efficient Sun-light absorption, hormation of hot electrons with high reduction energy, and reduction reaction has been developed. Target reacions are selective photochemical molecular transformations including H2 evolution from water and CO2 reduction to CO. In comparison with inherent properties of complexes in solution, such hybrid materials exhibit unexpected physicochemical properties that are induced by not only both steric- and electrostatic effect within the restricted void spaces, but also the nature of the surface functional groups on the host materials.
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Report
(4 results)
Research Products
(80 results)
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[Journal Article] Enhanced activity and selectivity in the one-pot hydroxylation of phenol by Pd/SiO2@Fe-containing mesoporous silica core-shell catalyst2014
Author(s)
Ikurumi, S., Okada, S., Nakatsuka, K., Kamegawa, T., Mori, K., Yamashita, H.
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Journal Title
Journal of Physical Chemistry C
Volume: 118
Issue: 1
Pages: 575-581
DOI
Related Report
Peer Reviewed / Open Access
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[Journal Article] Activity, recyclability, and stability of lipases immobilized on oil-filled spherical silica nanoparticles with different silica shell structures2013
Author(s)
Kuwahara, Y., Yamanishi, T., Kamegawa, T., Mori, K., Yamashita, H.
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Journal Title
ChemCatChem
Volume: 5
Issue: 8
Pages: 2527-2536
DOI
Related Report
Peer Reviewed
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[Journal Article] The synthesis of size- and color-controlled silver nanoparticles by using microwave heating and their enhanced catalytic activity by localized surface plasmon resonance2013
Author(s)
Fuku, K., Hayashi, R., Takakura, S., Kamegawa, T., Mori, K., Yamashita, H.
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Journal Title
Angewandte Chemie - International Edition
Volume: 52
Issue: 29
Pages: 7446-7450
DOI
Related Report
Peer Reviewed
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