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Chelating resin immobilizing polymer ligand for high-throughput separation of critical metals

Research Project

Project/Area Number 25340092
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Environmental conscious materials and recycle
Research InstitutionUniversity of Toyama

Principal Investigator

Kagaya Shigehiro  富山大学, 大学院理工学研究部(工学), 教授 (50272894)

Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2015: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2014: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2013: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Keywords環境技術 / 環境材料 / 廃棄物再資源化 / 固相抽出 / キレート樹脂
Outline of Final Research Achievements

Chelating resins for selective and rapid separation of critical metals, such as noble metals, rare earth elements, and rare metals, were prepared. As functional groups, polymer ligands, such as N-acetylated (Ac-), phosphomethylated (PM-), and carboxymethylated (CM-) polyethyleneimines (PEI), were immobilized on porous polymer resins. The resins immobilizing Ac-PEI and PM-PEI were useful for adsorption of noble metals (especially Au(III)) and rare earth elements, respectively. The resin immobilizing CM-PEI had the most excellent ability from the viewpoints of both selectivity and rapidity.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (21 results)

All 2016 2015 2014 2013 Other

All Journal Article (3 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 3 results) Presentation (16 results) (of which Invited: 4 results) Book (2 results)

  • [Journal Article] Chelating resin immobilizing carboxymethylated polyethyleneimine for selective solid-phase extraction of trace elements: Effect of the molecular weight of polyethyleneimine and its carboxymethylation rate2016

    • Author(s)
      Shigehiro Kagaya, Takehiro Kajiwara, Makoto Gemmei-Ide, Waka Kamichatani, Yoshinori Inoue
    • Journal Title

      Talanta

      Volume: 147 Pages: 342-350

    • DOI

      10.1016/j.talanta.2015.09.071

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Chelating Materials Immobilizing Carboxymethylated Pentaethylenehexamine and Polyethyleneimine as Ligands2014

    • Author(s)
      Shigehiro Kagaya, Yoshinori Inoue
    • Journal Title

      Analytical Sciences

      Volume: 30 Issue: 1 Pages: 35-42

    • DOI

      10.2116/analsci.30.35

    • NAID

      130004442243

    • ISSN
      0910-6340, 1348-2246
    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Potential of Presep<sup>&reg;</sup> PolyChelate as a Chelating Resin: Comparative Study with Some Aminocarboxylic Acid-type Resins2013

    • Author(s)
      Shigehiro Kagaya, Yumi Saeki, Daiki Morishima, Riko Shirota, Takehiro Kajiwara, Toshifumi Kato, Makoto Gemmei-Ide
    • Journal Title

      Analytical Sciences

      Volume: 29 Issue: 11 Pages: 1107-1112

    • DOI

      10.2116/analsci.29.1107

    • NAID

      130004442172

    • ISSN
      0910-6340, 1348-2246
    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] 水中微量元素の高速分離濃縮技術2016

    • Author(s)
      加賀谷重浩
    • Organizer
      日本分析化学会第76回分析化学討論会
    • Place of Presentation
      岐阜
    • Year and Date
      2016-05-28
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 微量元素の固相抽出分離における選択性・迅速性の改善2016

    • Author(s)
      加賀谷重浩
    • Organizer
      プラズマ分光分析研究会第96回講演会
    • Place of Presentation
      富山
    • Year and Date
      2016-03-11
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 微量元素の高速固相抽出分離のためのキレート樹脂2015

    • Author(s)
      加賀谷重浩
    • Organizer
      中部化学関係学協会支部連合第46回中部化学関係学協会支部連合秋季大会
    • Place of Presentation
      津
    • Year and Date
      2015-11-07
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] カルボキシメチル化ポリエチレンイミン型キレート樹脂を用いた微量元素の高速固相抽出分離2015

    • Author(s)
      城田理子,加藤雄大,梶原健寛,上茶谷若,井上嘉則,源明誠,加賀谷重浩
    • Organizer
      日本分析化学会第64年会
    • Place of Presentation
      博多
    • Year and Date
      2015-09-09
    • Related Report
      2015 Annual Research Report
  • [Presentation] キレート樹脂含有ディスク型焼結多孔体を用いる微量元素の固相抽出分離2015

    • Author(s)
      城田理子,梶原健寛,井上嘉則,加藤敏文,齊藤満,源明誠,加賀谷重浩
    • Organizer
      日本分析化学会第64年会
    • Place of Presentation
      博多
    • Year and Date
      2015-09-09
    • Related Report
      2015 Annual Research Report
  • [Presentation] ポリエチレンイミン追加導入型樹脂:元素捕捉におよぼすカルボキシメチル化の効果2015

    • Author(s)
      加藤 雄大,城田理子,梶原 健寛,井上 嘉則,上茶谷若,源明 誠,加賀谷 重浩
    • Organizer
      日本分析化学会第75回分析化学討論会
    • Place of Presentation
      甲府
    • Year and Date
      2015-05-23
    • Related Report
      2015 Annual Research Report
  • [Presentation] 長鎖アミノカルボン酸型樹脂による微量元素の高速固相抽出分離2015

    • Author(s)
      城田理子,加賀谷重浩,源明誠,井上嘉則,上茶谷若,梶原健寛,齊藤満
    • Organizer
      日本分析化学会第75回分析化学討論会
    • Place of Presentation
      甲府
    • Year and Date
      2015-05-23
    • Related Report
      2015 Annual Research Report
  • [Presentation] カルボキシメチル化ポリエチレンイミン型キレート樹脂を用いた元素捕捉におよぼすポリエチレンイミン分子量の影響2014

    • Author(s)
      城田理子,加賀谷重浩,源明誠,井上嘉則,加藤敏文,梶原健寛,齊藤満
    • Organizer
      第45回中部化学関係学協会支部連合秋季大会
    • Place of Presentation
      春日井
    • Year and Date
      2014-11-30
    • Related Report
      2014 Research-status Report
  • [Presentation] ハイスループット処理が可能な長鎖アミノカルボン酸型樹脂2014

    • Author(s)
      城田理子,源明誠,加賀谷重浩
    • Organizer
      日本化学会近畿支部平成26年度北陸地区講演会及び研究発表会
    • Place of Presentation
      富山
    • Year and Date
      2014-11-21
    • Related Report
      2014 Research-status Report
  • [Presentation] キレート樹脂含有焼結多孔体を用いる環境試料中微量元素の固相抽出分離2014

    • Author(s)
      城田理子,加賀谷重浩,源明誠,井上嘉則,加藤敏文,梶原健寛,齊藤満
    • Organizer
      日本分析化学会第63年会
    • Place of Presentation
      広島
    • Year and Date
      2014-09-17
    • Related Report
      2014 Research-status Report
  • [Presentation] 長鎖アミノカルボン酸型樹脂の元素捕捉特性2014

    • Author(s)
      城田理子,加賀谷重浩,源明誠,井上嘉則,上茶谷若,梶原健寛,齊藤満
    • Organizer
      日本分析化学会第33回分析化学中部夏期セミナー
    • Place of Presentation
      富山
    • Year and Date
      2014-09-04 – 2014-09-05
    • Related Report
      2014 Research-status Report
  • [Presentation] 迅速な元素分離を可能にする固相抽出材の開発2014

    • Author(s)
      加賀谷重浩
    • Organizer
      日本分析化学会中部支部平成26年北陸地区講演会
    • Place of Presentation
      金沢
    • Year and Date
      2014-07-12
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] カルボキシメチル化ポリエチレンイミン型キレート樹脂による銅(II)の捕捉におよぼすポリエチレンイミン分子量の影響2014

    • Author(s)
      加賀谷重浩 ,城田理子,源明誠,井上嘉則,上茶谷 若,梶原 健寛,齊藤 満
    • Organizer
      日本分析化学会第73回分析化学討論会
    • Place of Presentation
      郡山
    • Year and Date
      2014-05-25
    • Related Report
      2014 Research-status Report
  • [Presentation] ポリエチレンイミン型樹脂へのポリエチレンイミン追加導入による元素捕捉容量の改善2014

    • Author(s)
      加賀谷重浩,加藤雄大,源明誠,井上嘉則,上茶谷若,梶原健寛,齋藤 満
    • Organizer
      日本分析化学会第73回分析化学討論会
    • Place of Presentation
      郡山
    • Year and Date
      2014-05-25
    • Related Report
      2014 Research-status Report
  • [Presentation] ホスホメチル化ポリエチレンイミン型キレート樹脂を用いる希土類元素の固相抽出分離

    • Author(s)
      池田涼, 加賀谷重浩, 井上嘉則, 加藤敏文, 齊藤満
    • Organizer
      日本分析化学会第73回分析化学討論会
    • Place of Presentation
      函館
    • Related Report
      2013 Research-status Report
  • [Presentation] ホスホメチル化ポリエチレンイミン型キレート樹脂を用いる固相抽出/ICP-AESによる希土類元素の定量

    • Author(s)
      池田涼, 加賀谷重浩, 井上嘉則, 加藤敏文, 齊藤満
    • Organizer
      日本分析化学会第62年会
    • Place of Presentation
      東大阪
    • Related Report
      2013 Research-status Report
  • [Book] 微量金属分析の前処理と測定ノウハウ(第1章第2節 ICP発光分光分析のための微量元素の分離濃縮技術)2015

    • Author(s)
      加賀谷重浩
    • Total Pages
      10
    • Publisher
      技術情報協会
    • Related Report
      2014 Research-status Report
  • [Book] Chelating resin, in "Encyclopedia of Polymeric Nanomaterials"2014

    • Author(s)
      Shigehiro Kagaya, Makoto Gemmei-Ide, Yoshinori Inoue
    • Total Pages
      10
    • Publisher
      SpringerReference.com
    • Related Report
      2013 Research-status Report

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Published: 2014-07-25   Modified: 2019-07-29  

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