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Development of new educational tool for scientific experiments based on chemiluminescence originating from bioluminescence

Research Project

Project/Area Number 25350269
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Science education
Research InstitutionKanagawa University

Principal Investigator

Matsumoto Masakatsu  神奈川大学, 付置研究所, 名誉教授 (10260986)

Co-Investigator(Kenkyū-buntansha) 渡辺 信子  神奈川大学, 理学部, 助教 (40291744)
佐野 裕之  神奈川大学, 付置研究所, 研究員 (50739357)
Co-Investigator(Renkei-kenkyūsha) IJUIN Hisako  神奈川大学, 付置研究所, プロジェクト研究員 (60398948)
Project Period (FY) 2013-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2015: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2014: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2013: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Keywords化学発光 / 理科教材 / ジオキセタン / 光るシャボン玉 / 光るあぶり出し / 科学教育 / 光/化学エネルギー相互変換 / 生物発光
Outline of Final Research Achievements

It is quite important for students to more like science that they have a good experience of magical and miraculous phenomena which appeal to the five senses, especially sight. Although classical chemiluminescence of luminol and peroxalate/ fluorescer system has been developed as a good educational tool for scientific experiments, we attempted to develop a new one using dioxetane-based chemiluminescence, since it possesses various distinctive features: dioxetanes are so-called “pre-charged” chemiluminescence substrates from which we can “on demand” observe light emission. Thus, we made a handbook for scientific experiments, in which we showed interconversion between light energy and chemical energy through experiments of dioxetane synthesis from a precursor compound using sunlight. Furthermore, the text shows unprecedented chemiluminescent performances such as drawing of luminous figures and letters and luminous soap bubbles.

Report

(5 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (12 results)

All 2017 2016 2015 2014 2013 Other

All Journal Article (6 results) (of which Peer Reviewed: 6 results,  Open Access: 3 results,  Acknowledgement Compliant: 5 results) Presentation (6 results) (of which Invited: 1 results)

  • [Journal Article] Hydrogen bonding network-assisted chemiluminescent thermal decomposition of 3-hydroxyphenyl-substituted dioxetanes in crystal2017

    • Author(s)
      N. Watanabe, H. Takatsuka, H. K. Ijuin, A. Wakatsuki and M. Matsumoto
    • Journal Title

      Tetrahedron Letters

      Volume: 57 Issue: 23 Pages: 2558-2562

    • DOI

      10.1016/j.tetlet.2016.05.004

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Synthesis of tricyclic dioxetanes that exhibit intramolecular charge-transfer-induced decomposition: relationship between structure and chemiluminescence efficiency2017

    • Author(s)
      N. Watanabe, Y. Mizuno, Y. Maeda, H. K. Ijuin and M. Matsumoto
    • Journal Title

      Heterocycles

      Volume: 95 Issue: 1 Pages: 487-506

    • DOI

      10.3987/com-16-s(s)40

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Solvent- and temperature-controlled inversion of π-facial selectivity in the 1,2-cycloaddition of singlet oxygen to hydroxyphenyl-substituted cyclohexadihydrofurans2017

    • Author(s)
      N. Watanabe, K. Hiragaki, K. Tsurumi, H. K. Ijuin, and M. Matsumoto
    • Journal Title

      Tetrahedron

      Volume: 73 Issue: 14 Pages: 1845-1853

    • DOI

      10.1016/j.tet.2017.02.038

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Hydrogen bonding network-assisted chemiluminescent thermal decomposition of 3-hydroxypheyl-subsituted dioxetanes in crysatal2016

    • Author(s)
      N. Watanabe, H. Takatsuka, H. K. Ijuin, A. Wakatsuki, M. Matsumoto
    • Journal Title

      Tetrahedron Letters

      Volume: 57

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Synthesis of bicyclic dioxetanes bearing a hydroxyphenanthrene or hydroxy[4]helicene moiety and their base-induced chemiluminescent decomposition2015

    • Author(s)
      Yohei Koyama, Nobuko Watanabe, Hisako K. Ijuin, and Masakatsu Matsumoto
    • Journal Title

      HETEROCYCLES

      Volume: 90 Issue: 1 Pages: 462-481

    • DOI

      10.3987/com-14-s(k)43

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Chemiexcitation efficiency for the charge-transfer-induced chemiluminescent decomposition of 3-hydroxyphenyl-substituted dioxetanes in an aqueous system2014

    • Author(s)
      N. Watanabe, A. Oguri, M. Horikoshi, H. Takatsuka, H. K. Ijuin, M. Matsumoto
    • Journal Title

      Tetrahedron Lett.

      Volume: 55 Issue: 9 Pages: 1644-1647

    • DOI

      10.1016/j.tetlet.2014.01.089

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] ベンゾアゾリルフェノール置換ジオキセタンの固体発光分解2016

    • Author(s)
      渡邉信子、若月愛結、大塚澪、伊集院久子、加部義夫、松本正勝
    • Organizer
      複素環化学討論会
    • Place of Presentation
      金沢歌劇場
    • Year and Date
      2016-09-26
    • Related Report
      2016 Annual Research Report
  • [Presentation] コハクオナジマイマイのライフサイクルにおける黄色蛍光物質の変遷2014

    • Author(s)
      伊集院久子・渡邉信子・浅見崇比呂・松本正勝
    • Organizer
      生物発光化学発光研究会第31回学術講演会
    • Place of Presentation
      信州大学繊維学部
    • Year and Date
      2014-11-01
    • Related Report
      2014 Research-status Report
  • [Presentation] ジオキセタン型化学発光と生物発光ー立体化学に視点から眺めるー2014

    • Author(s)
      松本正勝
    • Organizer
      生物発光化学発光研究会第31回学術講演会
    • Place of Presentation
      信州大学繊維学部
    • Year and Date
      2014-11-01
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] ω-位を官能基化したリンカーで修飾されたジオキセタン型化学発光化合物2013

    • Author(s)
      入江 花風・渡辺 信子・伊集院 久子・山口 和夫・松本 正勝
    • Organizer
      2013年光化学討論会
    • Place of Presentation
      愛媛大学 城北地区(愛媛県松山市)
    • Related Report
      2013 Research-status Report
  • [Presentation] 低分子化合物測定のための新規binary matrixの探索

    • Author(s)
      伊集院久子、大橋守、大脇福喜子、渡邉信子、松本正勝
    • Organizer
      第61回質量分析総合討論会
    • Place of Presentation
      つくば国際会議場エポカル(茨城県つくば市)
    • Related Report
      2013 Research-status Report
  • [Presentation] コハクオナジマイマイおよびその近縁種の黄色蛍光物質

    • Author(s)
      伊集院久子・重田紗季江・品田麻美・中島愛乃・渡邉信子・浅見崇比呂・松本正勝
    • Organizer
      生物発光化学発光研究会第30回学術講演会
    • Place of Presentation
      東京工業大学蔵前会館(東京都目黒区)
    • Related Report
      2013 Research-status Report

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Published: 2014-07-25   Modified: 2019-07-29  

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