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Fabrication of bulk nanocrystalline Fe alloys with high strength and high tensile ductility by electrodeposition

Research Project

Project/Area Number 25390031
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Nanomaterials engineering
Research InstitutionOsaka Prefecture University

Principal Investigator

Yorinobu Takigawa  大阪府立大学, 工学(系)研究科(研究院), 准教授 (70382231)

Research Collaborator MATSUI Isao  
KAWAKATSU Tomo  
MORI Hiroki  
OGURA Yu  
Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2015: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2014: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2013: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Keywords電解析出法 / ナノ結晶材料 / バルク / 延性 / 結晶成長 / 粒界偏析 / バルクナノ結晶材料 / Fe基合金 / 配向 / Fe-Ni合金 / 高強度 / 高延性
Outline of Final Research Achievements

Bulk nanocrystalline Fe-Ni, Fe-Ni-C and Fe-Mn alloys were fabricated by an electrodeposition. Fe-Ni alloys exhibit high strength of 1.5GPa and large tensile ductility of 15%. The intrinsic ductility of these alloys was explored, taking into consideration the relationship between ductility and the orientation index or contents of grain boundary embrittlement element. An applying multiple regression analysis provides accurate predictions for the ductility. The analysis of this study points to the potency that the intrinsic ductility of nanocrystalline Fe–Ni alloys is higher than that of the present highest value of 24%.
Fe-Ni-C alloys with high hardness are also fabricated. The addition of propionic acid to the deposition bath could release the excess grain boundary defects of electrodeposited alloys in as-deposited states. Fe-Mn alloys without voids and cracks were also fabricated.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (32 results)

All 2016 2015 2014 Other

All Journal Article (5 results) (of which Peer Reviewed: 5 results,  Open Access: 1 results,  Acknowledgement Compliant: 3 results) Presentation (26 results) (of which Int'l Joint Research: 3 results,  Invited: 6 results) Remarks (1 results)

  • [Journal Article] Reduction in sulfur content of electrodeposited bulk nanocrystalline Fe-Ni alloys using manganese chloride2016

    • Author(s)
      Hiroki Mori, Isao Matsui, Yorinobu Takigawa, Tokuteru Uesugi, Kenji Higashi
    • Journal Title

      Materials Letters

      Volume: 175 Pages: 86-88

    • DOI

      10.1016/j.matlet.2016.03.146

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Mechanical behavior of electrodeposited bulk nanocrystalline Fe-Ni alloys2015

    • Author(s)
      I. Matsui, H. Mori, T. Kawakatsu, Y. Takigawa, T. Uesugi, K. Higashi
    • Journal Title

      Materials Research

      Volume: 18 Issue: suppl 1 Pages: 95-100

    • DOI

      10.1590/1516-1439.329014

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Enhancement in mechanical properties of bulk nanocrystalline Fe-Ni alloys electrodeposited using propionic acid2014

    • Author(s)
      I. Matsui, H. Mori, T. Kawakatsu, Y. Takigawa, T. Uesugi and K. Higashi
    • Journal Title

      Materials Science and Engineering A

      Volume: 607 Pages: 505-510

    • DOI

      10.1016/j.msea.2014.04.042

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Strategy for Electrodeposition of Highly Ductile Bulk Nanocrystalline Metals with a Face-Centered Cubic Structure2014

    • Author(s)
      I. Matsui, Y. Takigawa, D. Yokoe, T. Kato, T. Uesugi, and K. Higashi
    • Journal Title

      MATERIALS TRANSACTIONS

      Volume: 55 Issue: 12 Pages: 1859-1866

    • DOI

      10.2320/matertrans.M2014268

    • NAID

      130004700350

    • ISSN
      1345-9678, 1347-5320
    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Fabrication of bulk nanocrystalline Fe-Ni alloys with high strength and high ductility by an electrodeposition2014

    • Author(s)
      I. Matsui, T. Kawakatsu, Y. Takigawa, T. Uesugi, K. Higashi
    • Journal Title

      Materials Letters

      Volume: 116 Pages: 71-74

    • DOI

      10.1016/j.matlet.2013.10.108

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] 電解析出法による高強度・高延性バルクナノ結晶材料の作製2016

    • Author(s)
      瀧川順庸, 松井功, 上杉徳照, 東健司
    • Organizer
      日本金属学会 2016年春期大会
    • Place of Presentation
      東京理科大学葛飾キャンパス(東京都葛飾区)
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] S量低減と成長モード制御による高強度・高延性電析バルクナノ結晶Fe-Ni合金の創製2016

    • Author(s)
      瀧川順庸, 森宏樹, 松井功, 上杉徳照, 東健司
    • Organizer
      表面技術協会 第133回講演大会
    • Place of Presentation
      早稲田大学(東京都新宿区)
    • Year and Date
      2016-03-23
    • Related Report
      2015 Annual Research Report
  • [Presentation] Improvement in plastic elongation at room temperature of electrodeposited bulk nanocrystalline Fe-Ni alloys by reducing sulfur content2015

    • Author(s)
      H. Mori, I. Matsui, Y. Takigawa, T. Uesugi and K. Higashi
    • Organizer
      Twenty-Fourth International Symposium on Processing and Fabrication of Advanced Materials (PFAM XXIV)
    • Place of Presentation
      関西大学(大阪府吹田市)
    • Year and Date
      2015-12-19
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Fabrication of Bulk Nanocrystalline Alloys with Tensile Ductility by Electrodeposition2015

    • Author(s)
      Y. Takigawa, I. Matusi, T.Uesugi and K. Higashi
    • Organizer
      Twenty-Fourth International Symposium on Processing and Fabrication of Advanced Materials (PFAM XXIV)
    • Place of Presentation
      関西大学(大阪府吹田市)
    • Year and Date
      2015-12-18
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 電解析出法による高強度・高延性バルクナノ結晶材料の創製2015

    • Author(s)
      瀧川順庸
    • Organizer
      日本金属学会・日本鉄鋼協会関西支部 平成27年度材料化学研究会・鉄鋼プロセス研究会合同研究会
    • Place of Presentation
      大阪府立大学iサイトなんば(大阪府大阪市)
    • Year and Date
      2015-12-07
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] S量低減と成長モード制御による高延性電析バルクナノ結晶Fe-Ni合金の作製2015

    • Author(s)
      森宏樹, 松井功, 瀧川順庸, 上杉徳照, 東健司
    • Organizer
      日本金属学会・日本鉄鋼協会関西支部 平成27年度材料化学研究会・鉄鋼プロセス研究会合同研究会
    • Place of Presentation
      大阪府立大学iサイトなんば(大阪府大阪市)
    • Year and Date
      2015-12-07
    • Related Report
      2015 Annual Research Report
  • [Presentation] 電解析出法を用いたナノ結晶Fe-Mn合金の創製2015

    • Author(s)
      小倉悠, 森宏樹, 上杉徳照, 瀧川順庸, 東健司
    • Organizer
      日本金属学会・日本鉄鋼協会関西支部 平成27年度材料化学研究会・鉄鋼プロセス研究会合同研究会
    • Place of Presentation
      大阪府立大学iサイトなんば(大阪府大阪市)
    • Year and Date
      2015-12-07
    • Related Report
      2015 Annual Research Report
  • [Presentation] 電析バルクナノ結晶Fe-Ni合金の高延性化2015

    • Author(s)
      森宏樹, 松井功, 瀧川順庸, 上杉徳照, 東 健司
    • Organizer
      表面技術協会 第17回関西表面技術フォーラム
    • Place of Presentation
      甲南大学(兵庫県神戸市)
    • Year and Date
      2015-11-26
    • Related Report
      2015 Annual Research Report
  • [Presentation] 電解析出法によるバルクナノ結晶Fe-Mn合金の創製2015

    • Author(s)
      小倉悠, 森宏樹, 瀧川順庸, 上杉徳照, 東健司
    • Organizer
      日本材料学会 若手学生研究発表会
    • Place of Presentation
      京都テルサ(京都府京都市)
    • Year and Date
      2015-10-14
    • Related Report
      2015 Annual Research Report
  • [Presentation] Fabrication of Bulk Nanocrystalline Metals and Alloys with Tensile Ductility by Electrodeposition2015

    • Author(s)
      Yorinobu Takigawa, Isao Matusi, Tokuteru Uesugi, Kenji Higashi
    • Organizer
      12th International Conference on Superplasticity in Advanced Materials (ICSAM)
    • Place of Presentation
      東京大学(東京都文京区)
    • Year and Date
      2015-09-09
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 電析バルクナノ結晶Fe-Ni合金の機械的特性改善2015

    • Author(s)
      森宏樹, 松井功, 瀧川順庸, 上杉徳照, 東健司
    • Organizer
      日本金属学会2015年春期(第156回)講演大会
    • Place of Presentation
      東京大学駒場キャンパス
    • Year and Date
      2015-03-18 – 2015-03-20
    • Related Report
      2014 Research-status Report
  • [Presentation] Effect of low temperature thermal treatment on mechanical properties of electrodeposited bulk nanocrystalline Fe-Ni alloys2015

    • Author(s)
      I. Matsui, H. Mori, Y. Takigawa, T. Uesugi and K. Higashi
    • Organizer
      TMS2015
    • Place of Presentation
      Orlando, USA
    • Year and Date
      2015-03-15 – 2015-03-19
    • Related Report
      2014 Research-status Report
  • [Presentation] プロピオン酸添加による電析バルクナノ結晶Fe-Ni合金の強度向上2014

    • Author(s)
      森宏樹, 川勝智, 松井功, 瀧川順庸, 上杉徳照, 東健司
    • Organizer
      日本鉄鋼協会・日本金属学会関西支部 平成26年度関西支部鉄鋼プロセス研究会・材料化学研究会 第3回合同研究会
    • Place of Presentation
      京都大学
    • Year and Date
      2014-12-25
    • Related Report
      2014 Research-status Report
  • [Presentation] 電解析出法による高強度・高延性バルクナノ結晶メタルの作製2014

    • Author(s)
      松井功, 瀧川順庸, 横江大作, 加藤丈晴, 上杉徳照, 東健司
    • Organizer
      平成26年度表面技術若手研究者・技術者研究交流発表会
    • Place of Presentation
      名古屋市工業研究所
    • Year and Date
      2014-12-08
    • Related Report
      2014 Research-status Report
  • [Presentation] プロピオン酸添加による電析バルクナノ結晶Fe-Ni合金の粒界緩和強化2014

    • Author(s)
      森宏樹, 川勝智, 松井功, 瀧川順庸, 上杉徳照, 東健司
    • Organizer
      第16回関西表面技術フォーラム
    • Place of Presentation
      甲南大学 ポートアイランドキャンパス
    • Year and Date
      2014-11-27 – 2014-11-28
    • Related Report
      2014 Research-status Report
  • [Presentation] Fabrication of bulk nanocrystalline alloys by electrodeposition2014

    • Author(s)
      Y. Takigawa
    • Organizer
      2nd TKU-OPU international symposium
    • Place of Presentation
      Taipei, Taiwan
    • Year and Date
      2014-09-25 – 2014-09-27
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] カルボン酸添加による電析バルクナノ結晶Fe-Ni合金の強度向上2014

    • Author(s)
      森宏樹, 川勝智, 松井功, 瀧川順庸, 上杉徳照, 東健司
    • Organizer
      日本金属学会2014年秋期(第155回)講演大会
    • Place of Presentation
      名古屋大学
    • Year and Date
      2014-09-24 – 2014-09-26
    • Related Report
      2014 Research-status Report
  • [Presentation] カルボン酸添加浴を用いた高強度電析バルクナノ結晶Fe-Ni合金の作製2014

    • Author(s)
      森宏樹, 川勝智, 松井功, 瀧川順庸, 上杉徳照, 東健司
    • Organizer
      表面技術協会第130回講演大会
    • Place of Presentation
      京都大学
    • Year and Date
      2014-09-22 – 2014-09-23
    • Related Report
      2014 Research-status Report
  • [Presentation] 電解析出法による高延性バルクナノ結晶材料の創製2014

    • Author(s)
      瀧川順庸
    • Organizer
      電気鍍金研究会9月例会
    • Place of Presentation
      大阪鍍金会館
    • Year and Date
      2014-09-03
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] Mechanical behavior of electrodeposited bulk nanocrystalline Fe–Ni alloys2014

    • Author(s)
      I. Matsui, H. Mori, T. Kawakatsu, Y. Takigawa, T. Uesugi and K. Higashi
    • Organizer
      The 15th International Conference on Rapidly Quenched and Metastable Materials (RQ15)
    • Place of Presentation
      Shanghai, China
    • Year and Date
      2014-08-24 – 2014-08-28
    • Related Report
      2014 Research-status Report
  • [Presentation] 電解析出法によるバルクナノ結晶Fe-Ni合金の作製とその機械特性評価

    • Author(s)
      川勝智, 松井功, 瀧川順庸, 上杉徳照, 東健司
    • Organizer
      表面技術協会第128回講演大会
    • Place of Presentation
      福岡工業大学
    • Related Report
      2013 Research-status Report
  • [Presentation] 電析バルクナノ結晶Fe-Ni合金の引張強度と延性

    • Author(s)
      川勝智, 松井功, 瀧川順庸, 上杉徳照, 東健司
    • Organizer
      第15回関西表面技術フォーラム
    • Place of Presentation
      岡山大学
    • Related Report
      2013 Research-status Report
  • [Presentation] Fe-Ni電析浴におけるホウ酸代替物質の検討

    • Author(s)
      森宏樹, 川勝智, 松井功, 瀧川順庸, 上杉徳照, 東健司
    • Organizer
      第15回関西表面技術フォーラム
    • Place of Presentation
      岡山大学
    • Related Report
      2013 Research-status Report
  • [Presentation] Fabrication of bulk nanocrystalline materials with tensile ductility by electrodeposition

    • Author(s)
      Y. Takigawa, I. Matsui, T. Uesugi and K. Higashi
    • Organizer
      THERMEC'2013
    • Place of Presentation
      LasVegas, USA
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] 電解析出による高延性を示すバルクナノ結晶Fe-Ni合金の作製

    • Author(s)
      松井 功,川勝 智,瀧川順庸,上杉徳照,東 健司
    • Organizer
      表面技術協会第129回講演大会
    • Place of Presentation
      東京理科大学
    • Related Report
      2013 Research-status Report
  • [Presentation] 電析バルクナノ結晶Fe–Ni合金の作製とその機械的性質

    • Author(s)
      松井 功,川勝 智,瀧川順庸,上杉徳照,東 健司
    • Organizer
      日本金属学会2014年春期(第154回)講演大会
    • Place of Presentation
      東京工業大学
    • Related Report
      2013 Research-status Report
  • [Remarks] 大阪府立大学大学院工学研究科マテリアル工学分野マテリアル設計最適化研究グループ

    • URL

      http://www2.mtl.osakafu-u.ac.jp/

    • Related Report
      2014 Research-status Report

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Published: 2014-07-25   Modified: 2019-07-29  

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