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Synthesis of visible-light-driven photocatalysts with self-organized composite nanostructures grown in gas phase

Research Project

Project/Area Number 25390034
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Nanomaterials engineering
Research InstitutionAnan National College of Technology

Principal Investigator

Yoshida Takehito  阿南工業高等専門学校, その他部局等, 教授 (20370033)

Co-Investigator(Kenkyū-buntansha) UMEZU IKUROU  甲南大学, 理工学部, 教授 (30203582)
Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2015: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2014: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2013: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Keywordsパルスレーザーアブレーション法 / 気相成長 / 非熱平衡 / ナノ結晶 / 複合ナノ構造 / 自己組織化 / 光触媒 / 電荷分離
Outline of Final Research Achievements

Pulsed laser ablation (PLA) in vapor-phase is a candidate process to synthesize nanocrystallites with controlling not only their crystal structures but also agglomeration structures. In this study, we prepared TiO2 nanocrystallites agglomerated in self-organized web-structures by the PLA in O2 background gas. Paying attention to influence of the self-organized agglomeration structures on photocatalytic activities (PCA). Si substrates on which the TiO2 nanocrystallites deposited, in methylene blue aqueous solution, were irradiated by an UV excitation light. It was confirmed that the web-like structures were about 3-4 times higher than the cauliflower structures. We can conclude the web structures had high porous relating larger specific surface area, in comparison with the cauliflower structures.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (22 results)

All 2016 2015 2014 2013 Other

All Journal Article (6 results) (of which Peer Reviewed: 6 results,  Acknowledgement Compliant: 2 results) Presentation (14 results) (of which Int'l Joint Research: 4 results,  Invited: 3 results) Remarks (2 results)

  • [Journal Article] Pulsed-laser-deposited TiO2 nanocrystalline films supporting Au nanoparticles for visible-light-operating plasmonic photocatalysts2016

    • Author(s)
      T. Yoshida, T. Watanabe, F. Kikuchi, T. Tabuchi, I. Umezu, and M. Haraguchi
    • Journal Title

      Applied Physics A

      Volume: 122 Issue: 5 Pages: 1-5

    • DOI

      10.1007/s00339-016-0035-6

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Hierarchical Structure of TiO<sub>2</sub> Nano-aggregates Prepared by Pulsed Laser Ablation in Background Gas2015

    • Author(s)
      梅津郁朗,吉田岳人
    • Journal Title

      IEEJ Transactions on Electronics, Information and Systems

      Volume: 135 Issue: 9 Pages: 1055-1059

    • DOI

      10.1541/ieejeiss.135.1055

    • NAID

      130005096941

    • ISSN
      0385-4221, 1348-8155
    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Structural properties of TiO2 nanocrystallites condensed in vapor-phase for photocatalyst applications2014

    • Author(s)
      Takehito Yoshida, Nobuyasu Yagi, Riki Nakagou, Akira Sugimura, kurou Umezu
    • Journal Title

      Appl. Phys. A

      Volume: 117 Issue: 1 Pages: 223-227

    • DOI

      10.1007/s00339-014-8378-3

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Structural properties of TiO2 nanocrystallites condensed in vapor-phase for photocatalyst applications2014

    • Author(s)
      T. Yoshida, N. Yagi, R. Nakagou, M. Kondou, A. Sugimura and I. Umezu
    • Journal Title

      Appl. Phys. A

      Volume: 115 Pages: 1-5

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Non-equilibrium growth processes of porous TiO2 nanocrystal-films during pulsed laser ablation2013

    • Author(s)
      I. Umezu, N. Yagi, A. Sugimura and T. Yoshida
    • Journal Title

      Proc. of MRS 2012 fall meeting

      Volume: MRSF12-1497

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Formation of hierarchical structured TiO2 nanoparticle aggregates by pulsed laser ablation in background gas2013

    • Author(s)
      I. Umezu, A. Sugimura and T. Yoshida
    • Journal Title

      Proc. of Conference on Lasers and Electro-Optics Pacific Rim (CLEO-PR)

      Volume: 1

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] Nanostructured TiO2 by pulsed laser ablation for application to visible-light-operating plasmonic photocatalysts2016

    • Author(s)
      T. Yoshida, I. Umezu, and M. Haraguchi
    • Organizer
      Energy Materials Nanotechnology (EMN) TiO2 Meeting
    • Place of Presentation
      Hawaii, USA
    • Year and Date
      2016-03-27
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] ダブルパルスレーザーアブレーションによるTiO2とNiのプルーム衝突過程2016

    • Author(s)
      片山慶太,浜岡克佳,青木珠緒,福岡寛,吉田岳人,杉村 陽,梅津郁朗
    • Organizer
      第63回応用物理学会秋季学術講演会
    • Place of Presentation
      東京工業大学,東京都
    • Year and Date
      2016-03-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] TiO2 PLD nanocrystalline films supporting Au nanoparticles for application to visible-light-operating plasmonic photocatalysts2015

    • Author(s)
      T. Watanabe, F. Kikuchi, T. Tabuchi, T. Yoshida, I. Umezu, and M. Haraguchi
    • Organizer
      13th International Conference on Laser Ablation (COLA 2015)
    • Place of Presentation
      Cairns, Australia
    • Year and Date
      2015-08-31
    • Related Report
      2015 Annual Research Report 2014 Research-status Report
    • Int'l Joint Research
  • [Presentation] 金ナノ粒子担持型光触媒の作製技術の確立と特性評価2015

    • Author(s)
      菊地 史人,渡辺 てい,田渕 武尊,吉田 岳人,梅津 郁朗,原口 雅宜
    • Organizer
      応用物理学会中国四国支部・若手半導体研究会
    • Place of Presentation
      徳島大学,徳島県
    • Year and Date
      2015-08-06
    • Related Report
      2015 Annual Research Report
  • [Presentation] TiO2-based nanostructures synthesized by vapor-phase pulsed laser ablation for photocatalytic applications2015

    • Author(s)
      T. Yoshida and I. Umezu
    • Organizer
      Energy Materials Nanotechnology (EMN) Meeting
    • Place of Presentation
      Cancun, Mexico
    • Year and Date
      2015-06-08 – 2015-06-11
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] T. Yoshida and I. Umezu, "TiO2-based nanostructures synthesized by vapor-phase pulsed laser ablation for photocatalytic applications2015

    • Author(s)
      T. Yoshida and I. Umezu,
    • Organizer
      Energy Materials Nanotechnology (EMN) Cancum Meeting
    • Place of Presentation
      Cancun, Mexico
    • Year and Date
      2015-06-08
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Photocatalytic activities of TiO2 nanocrystallites agglomerated in self-organized web-structures by gas-phase pulsed laser ablation2015

    • Author(s)
      T. Yoshida, K. Wakamiya, T. Watanabe, T. Aoki, A. Sugimura, and I. Umezu
    • Organizer
      7th International Congress on Laser Advanced Materials Processing
    • Place of Presentation
      Kokura, Hukuoka
    • Year and Date
      2015-05-26 – 2015-05-29
    • Related Report
      2014 Research-status Report
  • [Presentation] Photocatalytic activities of TiO2 nanocrystallites agglomerated in self-organized web-structures by gas-phase pulsed laser ablation2015

    • Author(s)
      T. Yoshida, K. Wakamiya, T. Watanabe, T. Aoki, A. Sugimura, and I. Umezu
    • Organizer
      7th International Congress on Laser Advanced Materials Processing
    • Place of Presentation
      Kokura, Japan
    • Year and Date
      2015-05-26
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] TiO2 nanocrystallites agglomerated in self-organized web-structures synthesized in gas-phase pulsed laser ablation2014

    • Author(s)
      T. Yoshida, K. Wakamiya, A. Sugimura and I. Umezu
    • Organizer
      9th International Conference on Photo-Excited Processes and Applications
    • Place of Presentation
      Matsue, Shimane
    • Year and Date
      2014-09-30 – 2014-10-03
    • Related Report
      2014 Research-status Report
  • [Presentation] パルスレーザーアブレーションで作製したTiO2ナノ結晶凝集体の表面構造と光触媒機能の相関2014

    • Author(s)
      若宮 千司, 梅津 郁朗, 杉村 陽, 吉田 岳人
    • Organizer
      第75回応用物理学会秋季学術講演会
    • Place of Presentation
      札幌市,北海道大学
    • Year and Date
      2014-09-17 – 2014-09-20
    • Related Report
      2014 Research-status Report
  • [Presentation] Formation of hierarchical structured TiO2 nanoparticle aggregates by pulsed laser ablation in background gas2013

    • Author(s)
      I. Umezu, A. Sugimura and T. Yoshida
    • Organizer
      Conference on Lasers and Electro-Optics Pacific Rim (CLEO-PR)
    • Place of Presentation
      Kyoto, JAPAN
    • Related Report
      2013 Research-status Report
  • [Presentation] Relationship of photoctalytic activity to crystal structure of TiO2 nanoparticles synthesized by reactive pulsed laser ablation2013

    • Author(s)
      T. Yoshida, A. Sugimura and I. Umezu
    • Organizer
      12th International Conference on Laser Ablation (COLA 2013)
    • Place of Presentation
      Ischia, Italy
    • Related Report
      2013 Research-status Report
  • [Presentation] Formation of pattern structured TiO2 nano-aggregates by pulsed laser ablation in background gas2013

    • Author(s)
      I. Umezu, A. Sugimura and T. Yoshida
    • Organizer
      12th International Conference on Laser Ablation (COLA 2013)
    • Place of Presentation
      Ischia, Italy
    • Related Report
      2013 Research-status Report
  • [Presentation] パルスレーザーアブレーション法により自己組織的に網目構造凝集したTiO2ナノ結晶の光吸収特性2013

    • Author(s)
      若宮 千司, 梅津 郁朗, 杉村 陽, 吉田 岳人
    • Organizer
      第74回応用物理学会秋季学術講演会
    • Place of Presentation
      京都,日本
    • Related Report
      2013 Research-status Report
  • [Remarks] 阿南高専HP 教育・研究 研究者総覧 化学コース 吉田岳人

    • URL

      http://www01.anan-nct.ac.jp/souran/wp-content/uploads/2015/04/takehito.pdf

    • Related Report
      2014 Research-status Report
  • [Remarks] Google Citation, Takehito Yoshida

    • URL

      http://scholar.google.co.jp/citations?user=uBhrhz0AAAAJ&hl=en

    • Related Report
      2014 Research-status Report

URL: 

Published: 2014-07-25   Modified: 2019-07-29  

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