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Chiral Surface Formation and Chiral Molecular Recognition by Micro-Magnetohydrodynamic Effect

Research Project

Project/Area Number 25390040
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Nano/Microsystems
Research InstitutionTohoku University

Principal Investigator

Mogi Iwao  東北大学, 金属材料研究所, 助教 (50210084)

Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2015: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2014: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2013: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywordsマイクロ渦流 / キラリティ / 磁気電気化学 / 磁気流体力学 / アミノ酸 / 電極界面 / キラル触媒
Outline of Final Research Achievements

In our previous studies, we reported that electrodeposition under magnetic fields (magneto-electrodeposition) is able to produce chiral surfaces on metal films. In this study, we have conducted the magneto-electrodeposition of copper metal under various conditions. As a result, we have found the mechanism of chiral surface formation and the chiral recognition of amino acids on such chiral surfaces. Furthermore, we have found that chiral surfaces can be formed by new methods of magneto-electrochemical etching and rotational magneto-electrodeposition.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (22 results)

All 2016 2015 2014 2013

All Journal Article (8 results) (of which Peer Reviewed: 7 results,  Acknowledgement Compliant: 3 results,  Open Access: 2 results) Presentation (14 results) (of which Int'l Joint Research: 3 results,  Invited: 2 results)

  • [Journal Article] Lifetime of Ionic Vacancy Created in Redox Electrode Reaction Measured by Cyclotron MHD Electrode2016

    • Author(s)
      A. Sugiyama, R. Morimoto, T. Osaka, I. Mogi, M. Asanuma, M. Miura, Y. Oshikiri, Y. Yamauchi
    • Journal Title

      Sci. Rep.

      Volume: 6 Issue: 1 Pages: 19795-19795

    • DOI

      10.1038/srep19795

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Chiral Surface Formation of Copper Films by Magnetoelectrochemical Etching2015

    • Author(s)
      I. Mogi, R. Aogaki, K. Watanabe
    • Journal Title

      Magnetohydrodynamics

      Volume: 51 (2) Pages: 361-368

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Tailoring of Surface Chirality by Micro-Vortices and Specific Adsorption in Magnetoelectrodeposition2015

    • Author(s)
      I. Mogi, R. Aogaki, K. Watanabe
    • Journal Title

      Bulletin of the Chemical Society of Japan

      Volume: 88 Issue: 10 Pages: 1479-1485

    • DOI

      10.1246/bcsj.20150208

    • NAID

      130005102822

    • ISSN
      0009-2673, 1348-0634
    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Chiral Catalytic Activities in Magnetoelectrochemical Etching2015

    • Author(s)
      R. Aogaki, R. Morimoto, M. Asanuma, I. Mogi, A. Sugiyama, M. Miura, Y. Oshikiri, Y. Yamauchi
    • Journal Title

      Magnetohydrodynamics

      Volume: 51 (2) Pages: 353-360

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Chirality Induced by Magnetoelectrolysis2014

    • Author(s)
      1)I. Mogi, R. Aogaki, R. Morimoto, K. Watanabe
    • Journal Title

      Acta Physica Polonica A

      Volume: 126 Issue: 1 Pages: 380-381

    • DOI

      10.12693/aphyspola.126.380

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Chiral Surface Formation by Magnetoelectrochemical Etching2014

    • Author(s)
      2)I. Mogi, R. Aogaki, K. Watanabe
    • Journal Title

      Proc. on 9th Int. PAMIR Conf. on Fundamental and Applied MHD, Thermo Acoustic and Space Technologies (Riga, Latvia, Jun. 16-20, 2014)

      Volume: 2 Pages: 154-158

    • Related Report
      2014 Research-status Report
    • Acknowledgement Compliant
  • [Journal Article] Surface chirality induced by rotational electrodeposition in magnetic fields2013

    • Author(s)
      Iwao Mogi, Ryoichi Morimoto, Ryoichi Aogaki, Kazuo Watanabe
    • Journal Title

      Scientific Reports

      Volume: 3

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Magnetoelectrodeposition for the Chiral Surface Formation of Cu Films2013

    • Author(s)
      I. Mogi, R. Aogaki, R. Morimoto, K. Watanabe
    • Journal Title

      ECS Transaction

      Volume: 45 (12) Issue: 12 Pages: 1-8

    • DOI

      10.1149/04512.0001ecst

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] Chiral surface formation by galvanostatic magnetoelectrodeposition2015

    • Author(s)
      茂木 巖
    • Organizer
      PACIFICHEM 2015
    • Place of Presentation
      ホノルル,ハワイ,米国
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Surface Chirality Tailored by Micro-MHD Effects and Specific Adsorption2015

    • Author(s)
      茂木 巖
    • Organizer
      6th Int. Conf. on Magneto-Science
    • Place of Presentation
      松本市,日本
    • Year and Date
      2015-10-27
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Chirality Induction by Galvanostatic Magnetoelectrodeposition2015

    • Author(s)
      茂木 巖
    • Organizer
      66th Annual Meeting of the International Society of Electrochemistry
    • Place of Presentation
      台北, 台湾
    • Year and Date
      2015-10-04
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] マイクロ電極における磁気電気化学キラリティ2015

    • Author(s)
      茂木 巖
    • Organizer
      第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋国際会議場
    • Year and Date
      2015-09-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] 磁気電気化学キラリティへのマイクロ電極の効果2015

    • Author(s)
      茂木 巖
    • Organizer
      2015年電気化学秋季大会
    • Place of Presentation
      埼玉工業大学
    • Year and Date
      2015-09-11
    • Related Report
      2015 Annual Research Report
  • [Presentation] 定電流磁気電析によるキラル界面形成と添加剤効果2014

    • Author(s)
      茂木 巖
    • Organizer
      第9回日本磁気科学会年会
    • Place of Presentation
      高山市民文化会館(岐阜県高山市)
    • Year and Date
      2014-11-13 – 2014-11-14
    • Related Report
      2014 Research-status Report
  • [Presentation] 定電流磁気電析による界面キラリティの制御2014

    • Author(s)
      茂木 巖
    • Organizer
      第75回応用物理学会秋季学術講演会
    • Place of Presentation
      北海道大学(札幌市)
    • Year and Date
      2014-09-17 – 2014-09-20
    • Related Report
      2014 Research-status Report
  • [Presentation] Chiral surface formation by Magnetoelectrolysis2014

    • Author(s)
      茂木 巖
    • Organizer
      第38回日本磁気学会学術講演会
    • Place of Presentation
      慶應義塾大学(横浜市)
    • Year and Date
      2014-09-02 – 2014-09-05
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] Control of Surface Chirality of Cu Films by Galvanostatic Magnetoelectrodeposition2014

    • Author(s)
      茂木 巖
    • Organizer
      6th Int. Workshop on Materials Analysis and Processing in Magnetic Fields
    • Place of Presentation
      サザンビーチホテル(沖縄県糸満市)
    • Year and Date
      2014-07-08 – 2014-07-11
    • Related Report
      2014 Research-status Report
  • [Presentation] Chiral Surface Formation by Magnetoelectrochemical Etching2014

    • Author(s)
      茂木 巖
    • Organizer
      9th Int. PAMIR Conf. on Fundamental and Applied MHD, Thermo Acoustic and Space Technologies
    • Place of Presentation
      リガ市(ラトビア)
    • Year and Date
      2014-06-15 – 2014-06-20
    • Related Report
      2014 Research-status Report
  • [Presentation] 磁気電解エッチングによるキラル界面の生成2014

    • Author(s)
      茂木 巖
    • Organizer
      第61回応用物理学会春季学術講演会
    • Place of Presentation
      青山学院大学
    • Related Report
      2013 Research-status Report
  • [Presentation] 磁気電解エッチングによる銅薄膜のキラル界面の生成2014

    • Author(s)
      茂木 巖
    • Organizer
      電気化学会第81回大会
    • Place of Presentation
      関西大学
    • Related Report
      2013 Research-status Report
  • [Presentation] Surface Chirality Induced by Rotational Magnetoelectrodeposition2013

    • Author(s)
      茂木 巖
    • Organizer
      5th Int. Conf. on Magneto-Science
    • Place of Presentation
      フランス,ボルドー
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] 回転磁気電析によるキラル界面の生成2013

    • Author(s)
      茂木 巖
    • Organizer
      2013年電気化学会秋季大会
    • Place of Presentation
      東京工業大学
    • Related Report
      2013 Research-status Report

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Published: 2014-07-25   Modified: 2019-07-29  

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