Development of doping techniques in organic solar cells by flux-controlled deposition and synchrotron based analyses
| Project/Area Number |
25390063
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Crystal engineering
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| Research Institution | University of Tsukuba |
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Principal Investigator |
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| Project Period (FY) |
2013-04-01 – 2016-03-31
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| Project Status |
Completed (Fiscal Year 2015)
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| Budget Amount *help |
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2015: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2014: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2013: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
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| Keywords | 有機薄膜太陽電池 / ドーピング / バンドベンディング / 光電子分光 / 電子状態制御 / 不純物添加 / 結晶成長 / 電子状態 |
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| Outline of Final Research Achievements |
Doping techniques of SubPc/C60 heterostructure based solar cells were studied. We found Ca is a good dopant for C60 films; the electric conductivity was improved by three orders of magnitude by Ca doping with molar ratio of 0.2. The effective dopant for SubPc films, on the other hand, was MoO3. But the improvement of the electric conductivity was only one order of magnitude even though huge amount of MoO3 was added. To understand this phenomena, we studied electrical properties of both films by ultraviolet photoelectron spectroscopy. It was found that SubPc thin films showed highly dense tail states due to the disturbance of SubPc films. Thus, the improvement of the structural properties of the SubPc thin films is a key of high-quality impurity-doped solar cell.
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Report
(4 results)
Research Products
(23 results)
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[Journal Article] A new anodic buffer layer material for non-mixed planar heterojunction chloroboron subphthalocyanine organic photovoltaic achieving 96% internal quantum efficiency2015
Author(s)
Chi-Feng Lin, Shun-Wei Liu, Chih-Chien Lee, Takeaki Sakurai, Masato Kubota, Wei-Cheng Su, Jia-Cing Huang, Tien-Lung Chiu, Hsieh-Cheng Han, Li-Chyong Chen, Chin-Ti Chen, Jiun-Haw Lee
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Journal Title
Solar Energy Materials and Solar Cells
Volume: 137
Pages: 138-145
DOI
Related Report
Peer Reviewed / Int'l Joint Research
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