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Fabrication of all-solid-state thin-film batteries and in-situ electrochemical characterization

Research Project

Project/Area Number 25390072
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Thin film/Surface and interfacial physical properties
Research InstitutionTohoku University

Principal Investigator

SHIRAKI Susumu  東北大学, 原子分子材料科学高等研究機構, 准教授 (80342799)

Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2015: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2014: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2013: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywords表面界面 / 薄膜 / リチウム電池 / イオン伝導 / 表面・界面 / リチウムイオン2次電池 / エピタキシャル薄膜 / パルスレーザー堆積法
Outline of Final Research Achievements

All-solid-state Li batteries are expected to become the next generation batteries owing to their improved safety, larger capacity, and higher output relative to present batteries based on liquid electrolytes. One of the major drawbacks for the practical use of all-solid-state batteries is their large interface resistance at the solid electrolyte and electrode interface. In this study, we fabricated all-solid-state thin film batteries by stacking cathode, solid-electrolyte, and anode thin films. We obtained a remarkably low interface resistance when the electrolyte films were deposited in an off-axis sputtering configuration. The key to obtaining a low interface resistance with low activation energy is to reduce sputtering damage by using an off-axis sputtering configuration. The low interface resistance obtained implies that the negative space-charge layer effect is negligible in the solid-electrolyte/electrode interface.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (40 results)

All 2016 2015 2014 2013 Other

All Journal Article (16 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 13 results,  Acknowledgement Compliant: 7 results,  Open Access: 1 results) Presentation (15 results) (of which Int'l Joint Research: 2 results) Book (4 results) Remarks (4 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Orientation control of LiCoO2 epitaxial thin films on metal substrates2016

    • Author(s)
      Susumu Shiraki, Yoshitaka Takagi, Ryota Shimizu, Tohru Suzuki, Masakazu Haruta, Yukio Sato, Yuichi Ikuhara and Taro Hitosugi
    • Journal Title

      Thin Solid Films

      Volume: 600 Pages: 175-178

    • DOI

      10.1016/j.tsf.2016.01.032

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Preparation and in-situ characterization of well-defined solid electrolyte/electrode interfaces in thin-film lithium batteries2016

    • Author(s)
      Masakazu Haruta, Susumu Shiraki, Takeo Ohsawa, Tohru Suzuki, Akichika Kumatani, Yoshitaka Takagi, Ryota Shimizu, and Taro Hitosugi
    • Journal Title

      Solid State Ionics

      Volume: 285 Pages: 118-121

    • DOI

      10.1016/j.ssi.2015.06.007

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Li-ion diffusion in Li4Ti5O12 and LiTi2O4 battery materials detected by muon-spin spectroscopy2015

    • Author(s)
      Jun Sugiyama, Hiroshi Nozaki, Izumi Umegaki, Kazuhiko Mukai, Kazutoshi Miwa, Susumu Shiraki, Taro Hitosugi, , Andreas Suter, Thomas Prokscha, Zaher Salman, James S. Lord, and Martin Mansson
    • Journal Title

      PHYSICAL REVIEW B

      Volume: 92 Issue: 1 Pages: 014417-014417

    • DOI

      10.1103/physrevb.92.014417

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Negligible “negative space-charge layer effects” at oxide-electrolyte/electrode interfaces of thin-film batteries2015

    • Author(s)
      Masakazu Haruta, Susumu Shiraki, Tohru Suzuki, Akichika Kumatani, Takeo Ohsawa, Yoshitaka Takagi, Ryota Shimizu, and Taro Hitosugi
    • Journal Title

      Nano Letters

      Volume: 15 Issue: 3 Pages: 1498-1502

    • DOI

      10.1021/nl5035896

    • Related Report
      2015 Annual Research Report 2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] 極めて低い電解質/電極界面抵抗を有する全固体リチウム電池の作製 -液体電解質系リチウムイオン電池を凌駕する高速充放電に向けて-2015

    • Author(s)
      春田正和、白木将、一杉太郎
    • Journal Title

      自動車技術

      Volume: 69 Pages: 120-121

    • Related Report
      2015 Annual Research Report
    • Acknowledgement Compliant
  • [Journal Article] 全固体リチウム電池の酸化物電解質/電極界面におけるイオン伝導特性2015

    • Author(s)
      春田正和、白木将、一杉太郎
    • Journal Title

      エネルギーデバイス

      Volume: 2 Pages: 42-45

    • Related Report
      2015 Annual Research Report
    • Acknowledgement Compliant
  • [Journal Article] 応用物理学的アプローチを活用した全固体Li電池研究:電極/電解質界面抵抗の低減に向けた界面研究2015

    • Author(s)
      白木将、春田正和、河底秀幸、一杉太郎
    • Journal Title

      応用物理学会分科会誌M&BE

      Volume: 26 Pages: 212-217

    • Related Report
      2015 Annual Research Report
    • Acknowledgement Compliant
  • [Journal Article] Fabrication of all-solid-state battery using epitaxial LiCoO2 thin films2014

    • Author(s)
      S. Shiraki, H. Oki, Y. Takagi, T. Suzuki, A. Kumatani, R. Shimizu, Masakazu Haruta, T. Ohsawa, Y. Sato, Y. Ikuhara, and T. Hitosugi
    • Journal Title

      Journal of Power Sources

      Volume: 267 Pages: 881-887

    • DOI

      10.1016/j.jpowsour.2014.05.133

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Epitaxial growth of Li4Ti5O12 thin films using RF magnetron sputtering2014

    • Author(s)
      A. Kumatani, S. Shiraki, Y. Takagi, T. Suzuki, T. Ohsawa, X. Gao, Y. Ikuhara, T. Hitosugi
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 53 Issue: 5 Pages: 123103-123103

    • DOI

      10.7567/jjap.53.058001

    • NAID

      210000143760

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Bottom-Up Graphene-Nanoribbon Fabrication Reveals Chiral Edges and Enantioselectivity2014

    • Author(s)
      Han, P.; Akagi, K.; Canova, F. F.; Mutoh, H.; Shiraki, S.; Iwaya, K.; Weiss,P. S.; Asao, N.; Hitosugi, T.
    • Journal Title

      ACS Nano

      Volume: 8 Issue: 9 Pages: 9181-9187

    • DOI

      10.1021/nn5028642

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Epitaxial thin film growth of LiH using a liquid-Li atomic template2014

    • Author(s)
      H. Oguchi, T. Ikeshoji, T. Ohsawa, S. Shiraki, H. Kuwano, S.Orimo, T. Hitosugi
    • Journal Title

      Applied Physics Letters

      Volume: 105 Issue: 21

    • DOI

      10.1063/1.4902446

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Atomic-scale investigations of perovskite oxide heteroepitaxy2014

    • Author(s)
      T. Ohsawa, R. Shimizu, K. Iwaya, S. Shiraki, and T. Hitosugi
    • Journal Title

      J. Ceram. Soc. Jpn.

      Volume: 122 Pages: 456-459

    • NAID

      130004480270

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Epitaxial growth process of La_<0.7>Ca_<0.3>MnO_3 Thin Films on SrTiO_3(001) : Thickness-Dependent Inhomogeneity Caused by Excess Ti Atoms2014

    • Author(s)
      Ryota Shimizu, et al.
    • Journal Title

      Crystal Growth & Design

      Volume: 14 Issue: 4 Pages: 1555-1560

    • DOI

      10.1021/cg4013119

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Antiphase inversion domains in lithium cobaltite thin films deposited on single-crystal sapphire substrates2013

    • Author(s)
      S. Zheng, C. A. Fisher, T. Hitosugi, A. Kumatani, S. Shiraki, Y. H. Ikuhara, A. Kuwabara, H. Moriwake, H. Oki, and Y. Ikuhara
    • Journal Title

      Acta Materialia

      Volume: 61 Pages: 7671-7678

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Capability of Insulator Study by Photoemission Electron Microscopy at SPring-82013

    • Author(s)
      T. Ohkochi, M. Kotsugi, K. Yamada, K. Kawano, K. Horiba, F. Kitajima, M. Oura, S. Shiraki, T. Hitosugi, M. Oshima, T. Ono, T. Kinoshita, T. Muro, and Y. Watanabe
    • Journal Title

      Journal of Synchrotron Radiation

      Volume: 20 Pages: 620-625

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Effects of atomic collisions on the stoichiometry of thin films prepared by pulsed laser deposition2013

    • Author(s)
      D. Packwood, S. Shiraki, T. Hitosugi
    • Journal Title

      Phys. Rev. Lett.

      Volume: 11

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] PLDで成膜したLi3PO4固体電解質/LiCoO2電極界面のイオン伝導2016

    • Author(s)
      白木 将、鈴木 竜、河底 秀幸、清水 亮太、白澤 徹郎、一杉 太郎
    • Organizer
      電気化学会第83回大会
    • Place of Presentation
      大阪大学(大阪府・吹田市)
    • Year and Date
      2016-03-29
    • Related Report
      2015 Annual Research Report
  • [Presentation] PLDで成膜したLi3PO4固体電解質/LiCoO2電極界面のイオン伝導2016

    • Author(s)
      白木 将、鈴木 竜、河底 秀幸、清水 亮太、白澤 徹郎、一杉 太郎
    • Organizer
      第63回応用物理学会春季学術講演会
    • Place of Presentation
      東京工業大学(東京都・目黒区)
    • Year and Date
      2016-03-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] Fabrication and Electrochemical Characterization of All-Solid-State Thin Film Lithium-Ion Batteries2016

    • Author(s)
      Susumu Shiraki, Hideyuki Kawasoko, Toru Suzuki, Ryota Shimizu and Taro Hitosugi
    • Organizer
      The AIMR International Symposium 2016
    • Place of Presentation
      仙台国際センター(宮城県・仙台市)
    • Year and Date
      2016-02-22
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 全固体薄膜電池における電極/電解質界面におけるイオン伝導特性2015

    • Author(s)
      白木将、春田正和, 河底秀幸, 鈴木竜, 清水亮太, 一杉太郎
    • Organizer
      表面界面スペクトロスコピー2015
    • Place of Presentation
      国立女性教育会館(埼玉県・比企郡)
    • Year and Date
      2015-11-27
    • Related Report
      2015 Annual Research Report
  • [Presentation] 全固体リチウムイオン電池の酸化物電解質/電極界面におけるイオン伝導特性2015

    • Author(s)
      白木将,春田正和,鈴木竜,清水亮太,河底秀幸,一杉太郎
    • Organizer
      第56回電池討論会
    • Place of Presentation
      愛知県産業労働センターウインクあいち(愛知県・名古屋市)
    • Year and Date
      2015-11-11
    • Related Report
      2015 Annual Research Report
  • [Presentation] Ion conductivity at solid-electrolyte/electrode interface in all-solid-state batteries2015

    • Author(s)
      Susumu Shiraki, Masakazu Haruta, Tohru Suzuki, Ryota Shimizu, Hideyuki Kawasoko and Taro Hitosugi
    • Organizer
      10th International Symposium on Atomic Level Characterizations for New Materials and Devices (ALC15)
    • Place of Presentation
      くにびきメッセ(島根県・島根市)
    • Year and Date
      2015-10-25
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] PLDで成膜したLi3PO4固体電解質とLiCoO2電極界面のイオン伝導特性2015

    • Author(s)
      白木 将, 鈴木 竜, 河底 秀幸, 清水 亮太, 一杉 太郎
    • Organizer
      第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋国際会議場(愛知県・名古屋市)
    • Year and Date
      2015-09-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] 全固体リチウムイオン電池の酸化物電解質/電極界面におけるイオン伝導特性2015

    • Author(s)
      白木将,春田正和,鈴木竜,清水亮太,河底秀幸,一杉太郎
    • Organizer
      九州表面・真空研究会2015
    • Place of Presentation
      九州工業大学(福岡県・北九州市)
    • Year and Date
      2015-06-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] 全固体リチウム電池の酸化物電解質/電極界面におけるイオン伝導特性2015

    • Author(s)
      白木将、春田正和,鈴木竜,高木由貴,清水亮太,一杉太郎
    • Organizer
      第62回応用物理学会春季学術講演会
    • Place of Presentation
      東海大学(神奈川)
    • Year and Date
      2015-03-11 – 2015-03-14
    • Related Report
      2014 Research-status Report
  • [Presentation] 全固体リチウム電池の酸化物電解質/電極界面におけるイオン伝導特性2015

    • Author(s)
      白木将、春田正和,一杉太郎
    • Organizer
      学術振興会マイクロビームアナリシス第141委員会第159回研究会
    • Place of Presentation
      成蹊大学(東京)
    • Year and Date
      2015-02-19 – 2015-02-20
    • Related Report
      2014 Research-status Report
  • [Presentation] LiCoO2エピタキシャル薄膜の配向制御と電気化学評価2014

    • Author(s)
      白木将,高木由貴,春田正和,清水亮太,鈴木竜,佐藤幸生,幾原雄一,一杉太郎
    • Organizer
      2014年電気化学秋季大会・第57回化学センサ研究発表会
    • Place of Presentation
      北海道大学(北海道)
    • Year and Date
      2014-09-27 – 2014-09-28
    • Related Report
      2014 Research-status Report
  • [Presentation] 金属単結晶基板上に成膜したLiCoO2エピタキシャル薄膜の配向制御2014

    • Author(s)
      白木将,高木由貴,春田正和,清水亮太,鈴木竜,佐藤幸生,幾原雄一,一杉太郎
    • Organizer
      第75回応用物理学会秋季学術講演会
    • Place of Presentation
      北海道大学(北海道)
    • Year and Date
      2014-09-17 – 2014-09-20
    • Related Report
      2014 Research-status Report
  • [Presentation] 金属単結晶基板上に成膜したLiCoO2薄膜の構造と電気化学評価2014

    • Author(s)
      白木将,高木由貴,春田正和,清水亮太,鈴木竜,佐藤幸生,幾原雄一,一杉太郎
    • Organizer
      九州表面・真空研究会2014
    • Place of Presentation
      福岡教育大学(福岡)
    • Year and Date
      2014-06-07
    • Related Report
      2014 Research-status Report
  • [Presentation] Fabrication of all-solid-state battery using epitaxial LiCoO2 thin films2013

    • Author(s)
      Susumu SHIRAKI, Yoshitaka Takagi, Hideki Oki, Akichika Kumatani, Ryota Shimizu, Toru Suzuki, Masakazu Haruta, Takeo Ohsawa, Yukio Sato, Yuichi Ikuhara and Taro Hitosugi
    • Organizer
      9th international symposium on atomic level characterizations for new materials and evices '13
    • Place of Presentation
      Hawaii, USA
    • Related Report
      2013 Research-status Report
  • [Presentation] 金属単結晶基板上に成膜したLiCoO2エピタキシャル薄膜の構造評価2013

    • Author(s)
      白木将、高木由貴、熊谷明哉、清水亮太、鈴木竜、春田正和、大澤健男、佐藤 幸生、幾原雄一、一杉太郎
    • Organizer
      第74回応用物理学会秋季学術講演会
    • Place of Presentation
      同志社大学(京都府)
    • Related Report
      2013 Research-status Report
  • [Book] LiBの高容量・高耐久化のための電極-電解液(質)の界面制御技術と解析・評価法2015

    • Author(s)
      白木将、春田正和、一杉太郎
    • Total Pages
      350
    • Publisher
      技術情報協会
    • Related Report
      2015 Annual Research Report
  • [Book] LiBの高容量・高耐久化のための電極-電解液(質)の界面制御技術と解析・評価法2015

    • Author(s)
      白木将ほか
    • Total Pages
      350
    • Publisher
      技術情報協会出版
    • Related Report
      2014 Research-status Report
  • [Book] マイクロビームアナリシス・ハンドブック2014

    • Author(s)
      白木将ほか
    • Total Pages
      736
    • Publisher
      オーム社
    • Related Report
      2014 Research-status Report
  • [Book] 問題と解説で学ぶ表面科学2013

    • Author(s)
      白木将ほか
    • Total Pages
      208
    • Publisher
      共立出版
    • Related Report
      2013 Research-status Report
  • [Remarks] 全固体電池において、極めて低い電極/電解質界面抵抗を実現

    • URL

      http://www.wpi-aimr.tohoku.ac.jp/jp/news/press/2015/20150303_000542.html

    • Related Report
      2015 Annual Research Report 2014 Research-status Report
  • [Remarks] 全固体リチウム電池: 高品質の界面を実現する

    • URL

      http://research.wpi-aimr.tohoku.ac.jp/jpn/research/924

    • Related Report
      2015 Annual Research Report
  • [Remarks] ジグザク型グラフェンナノリボンの作製に成功

    • URL

      http://www.wpi-aimr.tohoku.ac.jp/jp/news//2014/20140910_000494.html

    • Related Report
      2014 Research-status Report
  • [Remarks] 高品質リチウムイオン電池開発に新指針

    • URL

      http://www.wpi-aimr.tohoku.ac.jp/jp/news/press/2013/20130711_000395.html

    • Related Report
      2013 Research-status Report
  • [Patent(Industrial Property Rights)] 記憶セル及び記憶回路2015

    • Inventor(s)
      一杉太郎, 白木将, 鈴木竜
    • Industrial Property Rights Holder
      一杉太郎, 白木将, 鈴木竜
    • Industrial Property Rights Type
      特許
    • Filing Date
      2015-05-18
    • Related Report
      2015 Annual Research Report

URL: 

Published: 2014-07-25   Modified: 2019-07-29  

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