Synthesis and fabrication of n-type phthalocyanine nanorods by chemical vapor deposition for organic photovoltaic cells
| Project/Area Number |
25390115
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
General applied physics
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| Research Institution | Kobe University |
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Principal Investigator |
Yasuko Koshiba 神戸大学, 工学(系)研究科(研究院), 助手 (70243326)
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| Co-Investigator(Kenkyū-buntansha) |
ISHIDA KENJI 神戸大学, 大学院工学研究科, 教授 (20303860)
UEDA YASUKIYO 神戸大学, 大学院工学研究科, 教授 (40116190)
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| Project Period (FY) |
2013-04-01 – 2016-03-31
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| Project Status |
Completed (Fiscal Year 2015)
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| Budget Amount *help |
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2015: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2014: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2013: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
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| Keywords | n型有機半導体 / ナノロッド / エネルギー変換 / 化学気相成長法 / 有機薄膜太陽電池 |
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| Outline of Final Research Achievements |
The thermal behavior of 1,2,4,5-tetracyanobenzene (TCNB) was measured under vacuum to atmospheric pressure conditions. We investigated the synthesis of 2,3,9,10,16,17,23,24-octacyanophthalocyanine (MPc(CN)8) molecules and the growth of MPc(CN)8-M nanorods on ultrathin metal (Cu, Fe, Ni : 6nm) films in vacuum by chemical vapor deposition (CVD). MPc(CN)8 molecules were synthesized and MPc(CN)8-M nanorods were formed on all substrates. Among them, CuPc(CN)8 molecules were synthesized in high yield, and CuPc(CN)8-Cu nanorods were deposited uniformly and in high density. These results can be explained by the stability of the MPc(CN)8-M complex, the oxide formation on the metal thin films, and the diffusion of metal atoms during the reaction.
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Report
(4 results)
Research Products
(19 results)
