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Development research of catalytic particle supporting by ion irradiation at solid-liquid interface

Research Project

Project/Area Number 25390141
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Quantum beam science
Research InstitutionInstitute of Physical and Chemical Research

Principal Investigator

Kobayashi Tomohiro  国立研究開発法人理化学研究所, 光量子工学研究領域, 専任研究員 (40282496)

Co-Investigator(Renkei-kenkyūsha) IKEDA Tokihiro  理化学研究所, 仁科加速器研究センター, 専任研究員 (80301745)
Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2015: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2014: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2013: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Keywordsイオン照射 / キャピラリー / 集束イオンビーム / 液体中照射 / ナノ粒子 / 触媒 / 放射線還元 / 金属微粒子 / イオンビーム / 触媒微粒子 / 触媒粒子
Outline of Final Research Achievements

We have developed the irradiation system by using a tapered glass capillary with thin lid at the tip. Through the capillary set at the end of the beamline, ion beam is ejected into liquid in container. Ions are accelerated with an electrostatic accelerator. The diameter of the ion beam is controlled with that of inner diameter of the capillary tip from several um to mm. The promising applications of material modification using this system will be nanoparticle synthesis. Ion irradiation can reduce metallic ions strongly by densely-formed reductive radicals. We have obtained Au, Ag, Ni, Pt, Cu single-metal nanoparticles and Pt-Cu bimetallic nanoparticles so far. The size, shape, composition of particles were observed by using electron microscope equipped with energy dispersive X-ray spectrometer.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (14 results)

All 2015 2014 Other

All Presentation (11 results) (of which Int'l Joint Research: 2 results) Remarks (2 results) Patent(Industrial Property Rights) (1 results)

  • [Presentation] Metallic particle formation by ion beam irradiation in liquid2015

    • Author(s)
      松林 洋太、小林 知洋、寺井 隆幸
    • Organizer
      第24回日本MRS年次大会
    • Place of Presentation
      横浜情報文化センター・横浜・神奈川
    • Year and Date
      2015-12-09
    • Related Report
      2015 Annual Research Report
  • [Presentation] Ion Irradiation System in Wet Environment by using Glass Capillary and Tandem Accelerator2015

    • Author(s)
      Tomohiro Kobayashi
    • Organizer
      The 19th International Conference on Surface Modification of Materials by Ion Beams (SMMIB-19)
    • Place of Presentation
      Chiang Mai, Thailand
    • Year and Date
      2015-11-24
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Metallic particle formation by ion beam irradiation in liquid2015

    • Author(s)
      Yota Matsubayashi, Tomohiro Kobayashi and Takayuki Terai
    • Organizer
      The 19th International Conference on Surface Modification of Materials by Ion Beams (SMMIB-19)
    • Place of Presentation
      Chiang Mai, Thailand
    • Year and Date
      2015-11-24
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 液体中イオンビーム照射による金属微粒子の生成2015

    • Author(s)
      松林 洋太、小林 知洋、寺井 隆幸
    • Organizer
      第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋国際会議場・名古屋・愛知
    • Year and Date
      2015-09-14
    • Related Report
      2015 Annual Research Report
  • [Presentation] 液体中イオンビーム照射による材料表面への白金微粒子担持2015

    • Author(s)
      松林洋太, 小林知洋, 寺井隆幸, 鈴木晶大
    • Organizer
      第62回応用物理学会春季学術講演会
    • Place of Presentation
      東海大学(神奈川県平塚市)
    • Year and Date
      2015-03-11 – 2015-03-14
    • Related Report
      2014 Research-status Report
  • [Presentation] Proton Irradiation in Liquid with Glass Capillaries and Metallic Particle Formation by Radiation Reduction2014

    • Author(s)
      T.Kobayashi, T. Yamaki, T. Hakoda, S. Yamamoto and Y. Yamazaki
    • Organizer
      第15回イオンビームによる表面・界面解析特別研究会
    • Place of Presentation
      筑波大学(茨城県つくば市)
    • Year and Date
      2014-12-05 – 2014-12-06
    • Related Report
      2014 Research-status Report
  • [Presentation] Catalytic Nanoparticle Formation by Ion Irradiation at Solid-Liquid Interface2014

    • Author(s)
      T.Kobayashi, T. Yamaki, T. Hakoda and Y. Yamazaki
    • Organizer
      19th International Conference on Ion Beam Modification of Materials (IBMM2014)
    • Place of Presentation
      University of Leuven, Leuven, Belgium
    • Year and Date
      2014-09-14 – 2014-09-19
    • Related Report
      2014 Research-status Report
  • [Presentation] Catalyst Particles Formation by Ion Beam Irradiation at Solid-Liquid Interface2014

    • Author(s)
      T.Kobayashi, T. Yamaki, T. Hakoda and Y. Yamazaki
    • Organizer
      The 15th IUMRS-International Conference in Asia (IUMRS-ICA 2014)
    • Place of Presentation
      福岡大学(福岡県福岡市)
    • Year and Date
      2014-08-24 – 2014-08-30
    • Related Report
      2014 Research-status Report
  • [Presentation] Platinum nanoparticles deposition by proton irradiation in liquid

    • Author(s)
      Tomohiro Kobayashi
    • Organizer
      Surface modification on materials by ion beam 2013 (SMMIB2013)
    • Place of Presentation
      Kusadasi, Turkey
    • Related Report
      2013 Research-status Report
  • [Presentation] Platinum nanoparticles formation by MeV ion irradiation in liquid

    • Author(s)
      Tomohiro Kobayashi
    • Organizer
      第23回日本MRS年次大会
    • Place of Presentation
      横浜開港記念会館(神奈川)
    • Related Report
      2013 Research-status Report
  • [Presentation] Platinum nanoparticles formation by proton irradiation in liquid

    • Author(s)
      Tomohiro Kobayashi
    • Organizer
      20th International Workshop on Inelastic Ion-Surface Collisions (IISC-20)
    • Place of Presentation
      Wirrina cove, Australia
    • Related Report
      2013 Research-status Report
  • [Remarks] RIKEN Atomic Physics Laboratory

    • URL

      http://www.riken.jp/ap/

    • Related Report
      2014 Research-status Report
  • [Remarks] RIKEN Atomic Physics Laboratory

    • URL

      http://www.riken.jp/ap/

    • Related Report
      2013 Research-status Report
  • [Patent(Industrial Property Rights)] 微小白金担持セリアナノワイヤ電極とその製造方法2015

    • Inventor(s)
      小林知洋 森利之 山本春也 他4名
    • Industrial Property Rights Holder
      小林知洋 森利之 山本春也 他4名
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2015-009968
    • Filing Date
      2015-01-22
    • Related Report
      2014 Research-status Report

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Published: 2014-07-25   Modified: 2019-07-29  

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