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Structural study of F-type iclsahedral quasicrystals and related compounds in Al-transition metal alloys

Research Project

Project/Area Number 25400354
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Condensed matter physics II
Research InstitutionTohoku University

Principal Investigator

Fujita Nobuhisa  東北大学, 多元物質科学研究所, 助教 (70431468)

Co-Investigator(Renkei-kenkyūsha) TAKAKURA HIROYUKI  北海道大学, 工学研究科, 准教授 (30284483)
TSAI AN-PANG  東北大学, 多元物質科学研究所, 教授 (90225681)
Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2015: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2014: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2013: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywords準結晶 / 近似結晶 / クラスタ / カノニカルセル / 準周期タイリング / アルミ合金 / X線回折 / 電子線回折トモグラフィ / 構造解析 / X線回折
Outline of Final Research Achievements

Although more than 30 years have passed since quasicrystals were discovered, their structural details have remained to be unclarified to a large extent posing one of the greatest mysteries in materials science. In order to elucidate the structure of Al-based icosahedral quasicrystals, we first aim at searching for novel approximant phases, namely crystals with similar local structures to that of the quasicrystals. Then we attempt to analyze the structure of new approximants using single-crystal X-ray diffraction to extract any information regarding the structural propserties of the quasicrystals. Overall, these attempts culminate in the discoveries of a few novel approximant crystals, whereas their structures turn out to be composed of two kinds of clusters forming a dense packing. We also propose a new theoretical model describing the arrangement of the clusters in the quasicrystals.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (19 results)

All 2015 2014 2013 Other

All Int'l Joint Research (2 results) Journal Article (2 results) (of which Peer Reviewed: 1 results) Presentation (14 results) (of which Int'l Joint Research: 3 results,  Invited: 5 results) Remarks (1 results)

  • [Int'l Joint Research] Stockholm University(Sweden)

    • Related Report
      2015 Annual Research Report
  • [Int'l Joint Research] KAIST(韓国)

    • Related Report
      2015 Annual Research Report
  • [Journal Article] 準結晶と高次元結晶学2014

    • Author(s)
      藤田伸尚
    • Journal Title

      金属

      Volume: 84 Pages: 332-340

    • Related Report
      2014 Research-status Report
  • [Journal Article] Cluster-packing geometry for Al-based F-type icosahedral alloys2013

    • Author(s)
      Nobuhisa Fujita, Hikari Takano, Akiji Yamamoto, An-Pang Tsai
    • Journal Title

      Acta Crystallographica Section A

      Volume: 69 Issue: 3 Pages: 322-340

    • DOI

      10.1107/s0108767313005035

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] 準周期カノニカルセルタイリングの発見2015

    • Author(s)
      藤田伸尚
    • Organizer
      第20回準結晶研究会
    • Place of Presentation
      東京理科大学(東京都葛飾区)
    • Year and Date
      2015-12-17
    • Related Report
      2015 Annual Research Report
  • [Presentation] Al-Pd-Ru系近似結晶の単結晶作製およびその構造評価2015

    • Author(s)
      畠山勇輔、藤田伸尚、大橋諭、蔡安邦
    • Organizer
      日本金属学会2015年秋期講演大会
    • Place of Presentation
      九州大学(福岡県福岡市)
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] Mg-Cd-Yb準結晶/Mg界面の整合性2015

    • Author(s)
      大橋諭、藤田伸尚、蔡安邦
    • Organizer
      日本金属学会2015年秋期講演大会
    • Place of Presentation
      九州大学(福岡県福岡市)
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] Networks of icosahedral clusters in intermetallics: from periodic to quasiperiodic2015

    • Author(s)
      Nobuhisa Fujita
    • Organizer
      Shape Up 2015 - Exercises in Materials Geometry and Topology
    • Place of Presentation
      Berlin (Germany)
    • Year and Date
      2015-09-14
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Quasiperiodic Canonical-Cell Tiling with Cubic Symmetry2015

    • Author(s)
      Nobuhisa Fujita
    • Organizer
      Aperiodic 2015
    • Place of Presentation
      Prague (the Czech Republic)
    • Year and Date
      2015-08-30
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Quasiperiodic canonical-cell tiling with cubic symmetry2015

    • Author(s)
      Nobuhisa Fujita
    • Organizer
      29th European Crystallographic Meeting
    • Place of Presentation
      Rovinj (Croatia)
    • Year and Date
      2015-08-23
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 正二十面体対称カノニカルセルタイリングの存在可能性2015

    • Author(s)
      藤田伸尚
    • Organizer
      日本物理学会第70回年次大会
    • Place of Presentation
      早稲田大学
    • Year and Date
      2015-03-22
    • Related Report
      2014 Research-status Report
  • [Presentation] Canonical-cell approach to cluster packing in icosahedral quasicrystals2014

    • Author(s)
      Nobuhisa Fujita
    • Organizer
      RIMS coorperative research: Mathematical model of quasi-crystals and related topics
    • Place of Presentation
      京都大学数理解析研究所
    • Year and Date
      2014-10-27
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] 正二十面体準結晶の高次近似結晶におけるクラスタの局所的配列自由度2014

    • Author(s)
      藤田伸尚
    • Organizer
      日本物理学会2014年秋季大会
    • Place of Presentation
      中部大学
    • Year and Date
      2014-09-08
    • Related Report
      2014 Research-status Report
  • [Presentation] 正二十面体準結晶におけるクラスタ充填問題への幾何学的アプローチ2014

    • Author(s)
      藤田伸尚
    • Organizer
      日本応用数理学会2014年度年会-数学協働プログラム:数理科学の物質・材料科学への応用
    • Place of Presentation
      政策研究大学院大学
    • Year and Date
      2014-09-04
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] Cluster-packing geometry for icosahedral alloys2014

    • Author(s)
      Nobuhisa Fujita
    • Organizer
      RIMS International Conference: Mathematical Challenge to a New Phase of Materials Science
    • Place of Presentation
      京都大学数理解析研究所
    • Year and Date
      2014-08-04
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] 点集合置換法による長周期カノニカルセルタイリングの作製II

    • Author(s)
      藤田伸尚
    • Organizer
      日本物理学会2013年秋季大会
    • Place of Presentation
      徳島大学常三島キャンパス
    • Related Report
      2013 Research-status Report
  • [Presentation] 複雑秩序物質の構造の分類

    • Author(s)
      藤田伸尚
    • Organizer
      日本物理学会第69回年次大会
    • Place of Presentation
      東海大学湘南キャンパス
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Al-based F-type icosahedral alloys - a novel view from X-ray crystallography -

    • Author(s)
      Nobuhisa Fujita
    • Organizer
      12th International Conference on Quasicrystals
    • Place of Presentation
      ポーランド,クラクフ
    • Related Report
      2013 Research-status Report
    • Invited
  • [Remarks] 準結晶の幾何学模型の作製及びそれに基づく構造安定性及び物性の解明

    • URL

      http://www.tagen.tohoku.ac.jp/center/CENIM/field_mdmf_lab_members.html#p02

    • Related Report
      2013 Research-status Report

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Published: 2014-07-25   Modified: 2022-01-31  

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