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Cross-Correlated Physical Properties of Molecular Materials in Dimensional Crossover Region

Research Project

Project/Area Number 25400367
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Condensed matter physics II
Research InstitutionKyoto University

Principal Investigator

Maesato Mitsuhiko  京都大学, 理学(系)研究科(研究院), 准教授 (60324604)

Co-Investigator(Renkei-kenkyūsha) IMAKUBO Tatsurou  長岡技術科学大学, 工学部, 准教授 (60291332)
Research Collaborator Brooks James S.  米国フロリダ州立大学, 国立強磁場研究所, 教授
Collet Eric  仏国レンヌ大学, 教授
Ouahab Lahcene  仏国レンヌ大学, 教授
Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2015: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2014: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2013: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Keywords磁性伝導体 / π-d複合体 / 強磁場物性 / 分子性導体 / 磁性 / 伝導性 / 強相関電子系
Outline of Final Research Achievements

Utilizing iodine-bonding interactions and a mixed-anion approach, we synthesized a series of molecular conductors (DIETSe)2FeBr4xCl4(1-x) [0 < x < 1] while keeping the isostructure. Physical property measurements of the high-quality single crystals at low temperatures down to 0.3 K and high magnetic fields up to 45 T demonstrated simultaneous control of both spin and charge degrees of freedom. We succeeded in introducing large hysteresis associated with a spin-flop transition in both magnetic moment and magnetoresistance in mixed-anion salts, which has never been observed in other π-d hybrid systems. We also found intriguing magnetic field-induced phase transitions and quantum oscillations at high fields.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (40 results)

All 2016 2015 2014 2013 Other

All Int'l Joint Research (1 results) Journal Article (12 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 12 results,  Acknowledgement Compliant: 8 results,  Open Access: 2 results) Presentation (27 results) (of which Int'l Joint Research: 4 results)

  • [Int'l Joint Research] NHMFL(米国)

    • Related Report
      2015 Annual Research Report
  • [Journal Article] Interplay between spin-density wave and 3d local moments with random exchange in a molecular conductor2016

    • Author(s)
      G. Kawaguchi, M. Maesato, T. Komatsu, T. Imakubo, H. Kitagawa
    • Journal Title

      Phys. Rev. B

      Volume: 93 Issue: 7

    • DOI

      10.1103/physrevb.93.075124

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Conducting π-Columns of Highly Symmetric Coronene, the Smallest Fragment of Graphene2016

    • Author(s)
      Y. Yoshida, K. Isomura, H. Kishida, Y. Kumagai, M. Mizuno, M. Sakata, T. Koretsune, Y. Nakano, H. Yamochi, M. Maesato, G. Saito
    • Journal Title

      Chem. Eur. J.

      Volume: 22 Issue: 17 Pages: 6023-6030

    • DOI

      10.1002/chem.201505023

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Unconventional Magnetic and Resistive Hysteresis in an Iodine-Bonded Molecular Conductor2015

    • Author(s)
      Genta Kawaguchi, Mitsuhiko Maesato, Tokutaro Komatsu, Hiroshi Kitagawa, Tatsuro Imakubo, Andhika Kiswandhi, David Graf, James S. Brooks
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 54 Issue: 35 Pages: 10169-10172

    • DOI

      10.1002/anie.201503824

    • NAID

      120005674647

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Spin-disordered quantum phases in a quasi-one-dimensional triangular lattice2015

    • Author(s)
      Yukihiro Yoshida, Hiroshi Ito, Mitsuhiko Maesato, Yasuhiro Shimizu , Hiromi Hayama, Takaaki Hiramatsu, Yuto Nakamura, Hideo Kishida, Takashi Koretsune, Chisa Hotta and Gunzi Saito
    • Journal Title

      Nature Physics

      Volume: 11 Issue: 8 Pages: 679-683

    • DOI

      10.1038/nphys3359

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Local response to light excitation in the charge-ordered phase of (EDO-TTF)2SbF62015

    • Author(s)
      M. Servol, N. Moisan, E. Collet, H. Cailleau, W. Kaszub, L. Toupet, D. Boschetto, T. Ishikawa, A. Moreac, S. Koshihara, M. Maesato, M. Uruichi, X. F. Shao, Y. Nakano, H. Yamochi, G. Saito, M. Lorenc
    • Journal Title

      Phys. Rev. B

      Volume: 92 Issue: 2

    • DOI

      10.1103/physrevb.92.024304

    • NAID

      120005997937

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Ambient-Pressure Organic Superconductor κ-(ET)2Ag(CN)[N(CN)2] Formed with Polymeric Silver(I) Complex Anion2015

    • Author(s)
      Y. Yoshida, H. Hayama, M. Ishikawa, A. Otsuka, H. Yamochi, Y. Nakamura, H. Kishida, H. Ito, M. Maesato, G. Saito
    • Journal Title

      J. Phys. Soc. Jpn.

      Volume: 84 Issue: 12 Pages: 123801-123801

    • DOI

      10.7566/jpsj.84.123801

    • NAID

      120006027082

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Hybrid Materials of Ni NP@MOF prepared by a Simple Synthetic Method2015

    • Author(s)
      M. Mukoyoshi, H. Kobayashi, K. Kusada, M. Hayashi, T. Yamada, M. Maesato, Jared M. Taylor, Y. Kubota, K. Kato, M. Takata, T. Yamamoto, S. Matsumura, H. Kitagawa
    • Journal Title

      Chemical Communications

      Volume: 51 Issue: 62 Pages: 10169-10172

    • DOI

      10.1039/c5cc04663g

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Quantum spin liquid: design of a quantum spin liquid next to a superconducting state based on a dimer-type ET Mott insulator2015

    • Author(s)
      T. Hiramatsu, Y. Yoshida, G. Saito, A. Otsuka, H. Yamochi, M. Maesato, Y. Shimizu, H. Ito, H. Kishida
    • Journal Title

      J. Mater. Chem. C

      Volume: 3 Issue: 6 Pages: 1378-1388

    • DOI

      10.1039/c4tc01701c

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Metallic and Mott Insulating Spin-frustrated Antiferromagnetic States in Ionic Fullerene Complexes with Two-dimensional Hexagonal C60- Packing Motif2014

    • Author(s)
      D. V. Konarev, S. S. Khasanov, A. Otsuka, M. Maesato, M. Uruichi, K. Yakushi, A. F. Shevchun, H. Yamochi, G. Saito, R. N. Lyubovskaya
    • Journal Title

      Chem. Eur. J.

      Volume: 20 Issue: 24 Pages: 7268-7277

    • DOI

      10.1002/chem.201304763

    • Related Report
      2014 Research-status Report 2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Isotropic Three-Dimensional Molecular Conductor Based on Coronene Radical Cation2014

    • Author(s)
      Y. Yoshida, M. Maesato, Y. Kumagai, M. Mizuno, K. Isomura, H. Kishida, M. Izumi, Y. Kubozono, A. Otsuka, H. Yamochi, G. Saito, K. Kirakci, S. Cordier, C. Perrin
    • Journal Title

      Eur. J. Inorg. Chem.

      Volume: 2014 Issue: 24 Pages: 3871-3878

    • DOI

      10.1002/ejic.201400119

    • Related Report
      2014 Research-status Report 2013 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Exploration of Charge-Transfer Solids Utilizing Nucleobases: Nanoarchitectures by Hydrogen-Bonds in the Ionic Assemblies of Guanine and TCNQ Derivatives2013

    • Author(s)
      T. Murata, G. Saito, K. Nakamura, M.Maesato, T. Hiramatsu, Y. Yoshida
    • Journal Title

      Cryst.Growth Des.

      Volume: (印刷中) Issue: 7 Pages: 2778-2792

    • DOI

      10.1021/cg400059h

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Charge-Transfer Solids Using Nucleobase: Supramolecular Architectures Composed of Cytosine and [Ni(dmit)2] Assembled by Multiple Hydrogen Bonds and Heteroatomic Contacts2013

    • Author(s)
      Y. Yoshida, 他6名
    • Journal Title

      Chem. Eur.J.

      Volume: (印刷中) Issue: 37 Pages: 12325-12335

    • DOI

      10.1002/chem.201300865

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] Peculiar Electronic States and Hysteresis Phenomena in the π-d Mixed Crystal System (DIETSe)2FeBr4xCl4(1-x)2016

    • Author(s)
      Genta Kawaguchi, Mitsuhiko Maesato, Tokutaro Komatsu, Tatsuro Imakubo, Andhika Kiswandhi, David Graf, Hiroshi Kitagawa
    • Organizer
      日本化学会第96回春季年会
    • Place of Presentation
      同志社大学 京田辺キャンパス
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] 量子スピン系κ-(ET)2B(CN)4の低温電子状態2016

    • Author(s)
      前里光彦, 川口玄太, 道岡千城, 巴山洋美, 吉田幸大, 齋藤軍治, 北川宏
    • Organizer
      日本物理学会第71回年次大会
    • Place of Presentation
      東北学院大学 泉キャンパス
    • Year and Date
      2016-03-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] π-d系混晶(DIETSe)2FeBr4xCl4(1-x)におけるヒステリシス現象2016

    • Author(s)
      川口玄太, 前里光彦, 小松徳太郎, 今久保達郎, David Graf, 北川宏
    • Organizer
      日本物理学会第71回年次大会
    • Place of Presentation
      東北学院大学 泉キャンパス
    • Year and Date
      2016-03-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] High pressure and high magnetic field studies of the spin gapped organic Mott insulator with distorted triangular lattice2015

    • Author(s)
      Mitsuhiko Maesato, Yukihiro Yoshida, Yasuhiro Shimizu, Takaaki Hiramatsu, Gunzi Saito, Hiroshi Kitagawa
    • Organizer
      Pacifichem2015
    • Place of Presentation
      Hawaii, Honolulu
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Correlations between magnetism and conductivity in quasi-one-dimensional π-d molecular conductors (DIETSe)2FeBr4xCl4(1-x)2015

    • Author(s)
      Genta Kawaguchi, Mitsuhiko Maesato, Tokutaro Komatsu, Hiroshi Kitagawa, Tatsuro Imakubo, Andhika Kiswandhi, David Graf, James Brooks
    • Organizer
      Pacifichem2015
    • Place of Presentation
      Hawaii, Honolulu
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] π-d系混晶(DIETSe)2FeBr3Clの相図2015

    • Author(s)
      川口玄太, 前里光彦, 小松徳太郎, 北川宏, 今久保達郎, David Graf, Andhika Kiswandhi, James S. Brooks
    • Organizer
      日本物理学会2015年秋季大会
    • Place of Presentation
      関西大学 千里山キャンパス
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] π-d複合系(DIETSe)2FeBr3Clの強磁場物性2015

    • Author(s)
      川口玄太, 前里光彦, 小松徳太郎, 北川宏, 今久保達郎, David Graf, Andhika Kiswandhi, James S. Brooks
    • Organizer
      第9回分子科学討論会
    • Place of Presentation
      東京工業大学 大岡山キャンパス
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] Quantum spin systems in κ-ET salts2015

    • Author(s)
      Mitsuhiko Maesato, Yasuhiro Shimizu, Akihiro Otsuka, Takaaki Hiramatsu, Yukihiro Yoshida, Gunzi Saito
    • Organizer
      11th International Symposium on Crystalline Organic Metals, Superconductors and Magnets (ISCOM)
    • Place of Presentation
      Gogging, Germany
    • Year and Date
      2015-09-06
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Spin-charge coupling in a series of π-d molecular conductors (DIETSe)2FeBr4xCl4(1-x)2015

    • Author(s)
      Genta Kawaguchi, Mitsuhiko Maesato, Tokutaro Komatsu, Hiroshi Kitagawa, Tatsuro Imakubo, Andhika Kiswandhi, David Graf, James Brooks
    • Organizer
      11th International Symposium on Crystalline Organic Metals, Superconductors and Magnets (ISCOM)
    • Place of Presentation
      Gogging, Germany
    • Year and Date
      2015-09-06
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 三角格子スピン液体κ-(ET)2Ag2(CN)3の低温物性2015

    • Author(s)
      前里光彦,吉田幸大,平松孝章,齋藤軍治,道岡千城,北川宏
    • Organizer
      日本物理学会第70回年次大会
    • Place of Presentation
      早稲田大学 早稲田キャンパス
    • Year and Date
      2015-03-21 – 2015-03-24
    • Related Report
      2014 Research-status Report
  • [Presentation] π-d系混晶(DIETSe)2MBr3Cl [M = Fe, Ga]の磁性と伝導性2015

    • Author(s)
      川口玄太,前里光彦,小松徳太郎,北川宏,今久保達郎,D. Graf,A. Kiswandhi,J. S. Brooks
    • Organizer
      日本物理学会第70回年次大会
    • Place of Presentation
      早稲田大学 早稲田キャンパス
    • Year and Date
      2015-03-21 – 2015-03-24
    • Related Report
      2014 Research-status Report
  • [Presentation] π-d系混晶(DIETSe)2FeBr3Clの磁性と伝導性2015

    • Author(s)
      川口玄太,前里光彦,小松徳太郎,北川宏,今久保達郎,D. Graf,A. Kiswandhi,J. S. Brooks
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日本大学 理工学部船橋キャンパス/薬学部
    • Year and Date
      2015-03-21 – 2015-03-24
    • Related Report
      2014 Research-status Report
  • [Presentation] 有機固体の次元クロスオーバー領域における特異な磁性と伝導性2014

    • Author(s)
      前里光彦
    • Organizer
      短期研究会「有機固体化学の最前線」
    • Place of Presentation
      愛媛大学 理学部総合研究棟
    • Year and Date
      2014-12-11 – 2014-12-12
    • Related Report
      2014 Research-status Report
  • [Presentation] ヨウ素結合型πd混晶系(DIETSe)2MBr4xCl4(1-x) [M = Fe, Ga]の特異な物性2014

    • Author(s)
      川口玄太,前里光彦,北川宏,今久保達郎,D. Graf,A. Kiswandhi,J. S. Brooks
    • Organizer
      第8回分子科学討論会
    • Place of Presentation
      広島大学 東広島キャンパス
    • Year and Date
      2014-09-21 – 2014-09-24
    • Related Report
      2014 Research-status Report
  • [Presentation] フラストレートスピン三角格子系のモット転移と超伝導2014

    • Author(s)
      前里光彦,吉田幸大,平松孝章,齋藤軍治,北川宏
    • Organizer
      日本物理学会2014年秋季大会
    • Place of Presentation
      中部大学 春日井キャンパス
    • Year and Date
      2014-09-07 – 2014-09-10
    • Related Report
      2014 Research-status Report
  • [Presentation] π-d系(DIETSe)2MBr2Cl2 [M = Fe, Ga]の特異な磁性と伝導性2014

    • Author(s)
      川口玄太,前里光彦,北川宏,今久保達郎
    • Organizer
      日本物理学会2014年秋季大会
    • Place of Presentation
      中部大学 春日井キャンパス
    • Year and Date
      2014-09-07 – 2014-09-10
    • Related Report
      2014 Research-status Report
  • [Presentation] Spin Liquid and Superconductivity in Molecular Conductors2014

    • Author(s)
      M. Maesato
    • Organizer
      Gordon Research Conference, “Conductivity & Magnetism in Molecular Materials”
    • Place of Presentation
      Bates College, Lewiston, ME, USA
    • Year and Date
      2014-08-04 – 2014-08-07
    • Related Report
      2014 Research-status Report
  • [Presentation] Spin-Charge Coupling in the π-d Molecular Conductors (DIETSe)2MBr4xCl4(1-x) [M = Fe, Ga]2014

    • Author(s)
      G. Kawaguchi, M. Maesato, H. Kitagawa, T. Imakubo, D. Graf,A. Kiswandhi,J. S. Brooks
    • Organizer
      Gordon Research Conference, “Conductivity & Magnetism in Molecular Materials”
    • Place of Presentation
      Bates College, Lewiston, ME, USA
    • Year and Date
      2014-08-04 – 2014-08-07
    • Related Report
      2014 Research-status Report
  • [Presentation] Superconductivity Emerging from Spin Liquid2014

    • Author(s)
      M. Maesato, T. Hiramatsu, Y. Yoshida, Y. Shimizu, A. Otsuka, G. Saito, H. Kitagawa
    • Organizer
      International Conference on Science and Technology of Synthetic Metals (ICSM) 2014
    • Place of Presentation
      Turku, Finland
    • Year and Date
      2014-06-30 – 2014-07-05
    • Related Report
      2014 Research-status Report
  • [Presentation] High magnetic field studies of π-d molecular conductors (DIETSe)2MBr4xCl4(1-x) [M = Fe, Ga]2014

    • Author(s)
      G. Kawaguchi, M. Maesato, H. Kitagawa, T. Imakubo, D. Graf,A. Kiswandhi,J. S. Brooks
    • Organizer
      International Conference on Science and Technology of Synthetic Metals (ICSM) 2014
    • Place of Presentation
      Turku, Finland
    • Year and Date
      2014-06-30 – 2014-07-05
    • Related Report
      2014 Research-status Report
  • [Presentation] Quantum spin liquid and pressure-induced superconductivity in molecular conductors2014

    • Author(s)
      M. Maesato
    • Organizer
      OIST International Workshop on Novel Quantum Materials and Phases (NQMP2014)
    • Place of Presentation
      OIST, Okinawa, Japan
    • Year and Date
      2014-05-14 – 2014-05-17
    • Related Report
      2014 Research-status Report
  • [Presentation] (DIETSe)2MBr2Cl2 [M = Ga, Fe]の強磁場物性2014

    • Author(s)
      川口玄太,前里光彦,北川宏,今久保達郎,D. Graf,A. Kiswandhi,J. S. Brooks
    • Organizer
      日本物理学会 第69回年次大会
    • Place of Presentation
      東海大学 湘南キャンパス
    • Related Report
      2013 Research-status Report
  • [Presentation] π-d系有機導体(DIETSe)2MBr4xCl4(1-x) [M = Ga, Fe]の高圧力・強磁場下における物性2014

    • Author(s)
      川口玄太,前里光彦,北川宏,今久保達郎,D. Graf,A. Kiswandhi,J. S. Brooks
    • Organizer
      日本化学会 第94春季年会
    • Place of Presentation
      名古屋大学 東山キャンパス
    • Related Report
      2013 Research-status Report
  • [Presentation] Anomalous Magnetotransport in DIETSe salts2013

    • Author(s)
      M. Maesato, G. Kawaguchi, H. Kitagawa, T. Imakubo, G. Saito,A. Kiswandhi, D. Graf, J.S. Brooks
    • Organizer
      The 10th International Symposium on Crystalline Organic Metals Superconductors and Ferromagnets (ISCOM2013)
    • Place of Presentation
      Montreal, Quebec, Canada
    • Related Report
      2013 Research-status Report
  • [Presentation] Systematic studies of π-d hybrid molecular conductors2013

    • Author(s)
      G. Kawaguchi, M. Maesato, H. Kitagawa, T. Imakubo, Kiswandhi, D. Graf, J.S. Brooks
    • Organizer
      The 10th International Symposium on Crystalline Organic Metals Superconductors and Ferromagnets (ISCOM2013)
    • Place of Presentation
      Montreal, Quebec, Canada
    • Related Report
      2013 Research-status Report
  • [Presentation] 新規スピン液体の圧力誘起超伝導2013

    • Author(s)
      前里光彦,平松孝章,吉田幸大,齋藤軍治,北川宏
    • Organizer
      日本物理学会 2013年秋季大会
    • Place of Presentation
      徳島大学
    • Related Report
      2013 Research-status Report
  • [Presentation] スピン液体に隣接した圧力誘起超伝導2013

    • Author(s)
      前里光彦,平松孝章,吉田幸大,清水康弘,齋藤軍治,北川宏
    • Organizer
      第54回高圧討論会
    • Place of Presentation
      朱鷺メッセ 新潟コンベンションセンター
    • Related Report
      2013 Research-status Report

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Published: 2014-07-25   Modified: 2022-01-27  

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