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Research for large thermoelectric responses of transition metal oxides by controlling nanostructure

Research Project

Project/Area Number 25400378
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Condensed matter physics II
Research InstitutionKagoshima University

Principal Investigator

Okuda Tetsuji  鹿児島大学, 理工学域工学系, 准教授 (20347082)

Co-Investigator(Kenkyū-buntansha) SAITOH Tomohiko  東京理科大学, 理学部, 教授 (30311129)
KAJIMOTO Ryoichi  独立行政法人日本原子力研究開発機構, その他部局等, 主任研究員 (30391254)
Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2015: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2014: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2013: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywords熱電材料 / 遷移金属酸化物 / 熱電特性 / 酸化物半導体 / Jahn-Teller歪 / フラストレーション / 光電子分光 / 非弾性中性子散乱 / 電界ドーピング
Outline of Final Research Achievements

In this research, we have investigated a mechanism of enhancement of thermoelectric property in the electron-doped SrTiO3 by a substitution of Mn ions. By measurements of macroscopic properties such as thermoelectric property, Hall coefficient, magnetic property, and specific heat, and that of phonon excitations by an inelastic neutron scattering measurement, we have shown the possibility that the enhancement is caused by a nontrivial enhancement of low-energy phonon excitation and an enhancement of Seebeck coefficient due to some interaction between itinerant electrons and localized spins of Mn ions.
Furthermore, we have investigated a magnetic excitation of antiferromagnetic triangular lattice CuCrO2 which is one of candidates of p-type thermoelectric oxides by an inelastic neutron scattering measurement and have clarified electronic structures of hole-doped CuCrO2 and the related materials by photoemission spectroscopy.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (42 results)

All 2016 2015 2014 2013

All Journal Article (13 results) (of which Peer Reviewed: 13 results,  Acknowledgement Compliant: 4 results,  Open Access: 1 results) Presentation (29 results) (of which Int'l Joint Research: 4 results,  Invited: 7 results)

  • [Journal Article] Universal Behaviors of the Phonon Thermal Conductivity Associated with the Charge/Orbital Ordering in Transition-Metal Oxides2016

    • Author(s)
      T. Katsufuji, T. Okuda, T. Murata, T. Kanzaki, K. Takayama, and A. Kajita
    • Journal Title

      Journal of the Physical Society of Japan

      Volume: 85 Issue: 1 Pages: 013703-013703

    • DOI

      10.7566/jpsj.85.013703

    • NAID

      40020699673

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Development of Spin Correlations in the Geometrically Frustrated Triangular-Lattice Heisenberg Antiferromagnet CuCrO22015

    • Author(s)
      Ryoichi Kajimoto, Keisuke Tomiyasu, Kenji Nakajima, Seiko Ohira-Kawamura, Yasuhiro Inamura, and Tetsuji Okuda
    • Journal Title

      Journal of the Physical Society of Japan

      Volume: 7884 Issue: 7 Pages: 074708-074708

    • DOI

      10.7566/jpsj.84.074708

    • NAID

      210000133629

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Hybridization gap formation in Kondo insulator YB12 obesrved using time-resolved photoemission spectroscopy2015

    • Author(s)
      M. Okawa, Y. Ishida, M. Takahashi, T. Shimada, F. Iga, T. Takabatake, T. Saitoh, and S. Shin
    • Journal Title

      Phys. Rev. B

      Volume: 92 Issue: 16

    • DOI

      10.1103/physrevb.92.161108

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Electronic Phase Transition in Hollandite Titanate BaxTi8O16+x2015

    • Author(s)
      R. Murata, T. Sato, T. Okuda, Y. Horibe, H. Tsukasaki, S. Mori, N. Yamaguchi, K. Sugimoto, S. Kawaguchi, M. Takata, and T. Katsufuji
    • Journal Title

      Physical Review B

      Volume: 92 Issue: 22

    • DOI

      10.1103/physrevb.92.220408

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effects of Mn substitution on the thermoelectric properties of the electron-doped perovskite Sr1-xLaxTiO32014

    • Author(s)
      T. Okuda, H. Hata, T. Eto, K. Nishina, H. Kuwahara, M. Nakamura, and R. Kajimoto
    • Journal Title

      Journal of Physics: Conference Series

      Volume: 588, part 2 Issue: 2 Pages: 022035-022035

    • DOI

      10.1088/1742-6596/568/2/022035

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Low-Energy Spin Fluctuations in CuCrO2 and Cu0.85Ag0.15CrO2 Studied by Inelastic Neutron Scattering2014

    • Author(s)
      R. Kajimoto, K. Nakajima, S. Ohira-Kawamura, Y. Inamura, T. Okuda, and K. Tomiyasu
    • Journal Title

      JPS Conference Proceedings

      Volume: 3

    • DOI

      10.7566/jpscp.3.014018

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Cu-O-Cr Hybridization Effects on the Electronic Structure of a Hole-Doped Delafossite Oxide CuCr1-xMgxO22014

    • Author(s)
      M. Okawa, T. Yokobori, K. Konishi, R. Takei, K. Katayama, S. Oozono, T. Shinmura, T. Okuda, H. Wadati, E. Sakai, K. Ono, H. Kumigashira, M. Oshima, T. Sugiyama, E. Ikenaga, N. Hamada, and T. Saitoh
    • Journal Title

      JPS Conference Proceedings

      Volume: 3

    • DOI

      10.7566/jpscp.3.017027

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Effects of Mg, Ag, and Al substitutions on magnetic excitations in the triangular-lattice antiferromagnet CuCrO22013

    • Author(s)
      R. Kajimoto, K. Nakajima, S. Ohira-Kawamura, Y. Inamura, K. Kakurai, T. Hokazono, S. Oozono and T. Okuda
    • Journal Title

      J. Phys. Soc. Jpn.

      Volume: 82 Issue: 5 Pages: 054702-054702

    • DOI

      10.7566/jpsj.82.054702

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Electronic structure of hole-doped delafossite oxides CuCr_1-_xMg_xO_22013

    • Author(s)
      T. Yokobori, M. Okawa, K. Konishi, R. Takei, K. Katayama, S. Oozono, T. Shinmura, T. Okuda, H. Wadati, E. Sakai, K. Ono, H. Kumigashira, M. Oshima, T. Sugiyama, E. Ikenaga, N. Hamada, and T. Saitoh
    • Journal Title

      Phys. Rev. B

      Volume: 87 Issue: 19 Pages: 195124-195124

    • DOI

      10.1103/physrevb.87.195124

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Power-law dependence of low-temperature magnetic specific heat for hole-doped delafossite CuCr1-xMgxO22013

    • Author(s)
      T. Okuda, S. Miyasaka
    • Journal Title

      J. Phys. Soc. Jpn.

      Volume: 82 Issue: 6 Pages: 065001-065001

    • DOI

      10.7566/jpsj.82.065001

    • NAID

      210000132618

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Magnetotransport Property of the Hole-doped Delafossite CuCr0.97Mg0.03O2 with a Spin-3/2 Antiferromagnetic Triangular Sublattice2013

    • Author(s)
      T. Okuda, S. Oozono, T. Kihara, and M. Tokunaga
    • Journal Title

      J. Korean Phys. Soc

      Volume: 62 Issue: 12 Pages: 2168-2172

    • DOI

      10.3938/jkps.62.2168

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Low-temperature thermoelectric properties of the electron-doped perovskites Sr1-xCaxTi1-yNbyO32013

    • Author(s)
      T.Okuda, J.Fukuyado, K.Narikiyo, M.Akaki, H.Kuwahara
    • Journal Title

      Journal of the Korean Physical Society

      Volume: 63(3) Issue: 3 Pages: 428-432

    • DOI

      10.3938/jkps.63.428

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Transport Properties of Anatase-TiO2-Polycrystalline-Film Field-Effect-Transistors Having Electrolyte Gate layers2013

    • Author(s)
      R. Horita, K. Ohtani, T. Kai, Y. Murao, H. Nishida, T. Toya, K. Seo, M. Sakai, and T. Okuda
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 52 Issue: 11R Pages: 115803-115803

    • DOI

      10.7567/jjap.52.115803

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] 電子ドープβ-Ga2O3の熱電特性2016

    • Author(s)
      草原彰吾, 久永達郎, 奥田哲治
    • Organizer
      日本物理学会 第71回年次大会
    • Place of Presentation
      東北学院大学 泉キャンパス (宮城県、仙台市)
    • Year and Date
      2016-03-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] Cu1+xMn1-xO2(x=0, 0.05)の電子構造2016

    • Author(s)
      加藤諒, 大川万里生, 和達大樹, 吉田鉄平, 小野寛太, 池永英司, 奥田哲治, 齋藤智彦
    • Organizer
      第29回日本放射光学会年会・放射光科学合同シンポジウム
    • Place of Presentation
      東京大学柏の葉キャンパス駅前サテライト・柏の葉カンファレンスセンター(三井ガーデンホテル柏の葉)・オークビレッジ柏の葉 (千葉県、柏市)
    • Year and Date
      2016-01-09
    • Related Report
      2015 Annual Research Report
  • [Presentation] 粉末非弾性中性子散乱によるSrTiO3のフォノンに対する元素置換効果2015

    • Author(s)
      梶本亮一、中村充孝、菊地龍弥、畑博人、江藤貴弘、草原彰吾、奥田哲治
    • Organizer
      日本中性子科学会第15回年会
    • Place of Presentation
      和光市民文化センター (埼玉県、和光市)
    • Year and Date
      2015-12-10
    • Related Report
      2015 Annual Research Report
  • [Presentation] Mn置換した電子ドープSrTiO3の低温比熱2015

    • Author(s)
      奥田哲治, 江藤貴弘, 畑博人, 草原彰吾, 仁科康佑, 桑原英樹, 中村充孝, 梶本亮一
    • Organizer
      日本物理学会 2015度秋季大会
    • Place of Presentation
      関西大学 千里山キャンパス (大阪府、吹田市)
    • Year and Date
      2015-09-25
    • Related Report
      2015 Annual Research Report
  • [Presentation] 新たな酸化物熱電材料の探索2015

    • Author(s)
      奥田哲治
    • Organizer
      日本熱電学会 第12回学術講演会
    • Place of Presentation
      九州大学 筑紫地区総合研究棟(C-Cube) (福岡県、春日市)
    • Year and Date
      2015-09-07
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Angle-resolved photoemission study of a thermoelectric and multiferroic delafossite CuCrO22015

    • Author(s)
      R. Kato, M. Okawa, K. Ono, T. Okuda, and T. Saitoh
    • Organizer
      The 12th International Workshop on Strong Correlations and Angle-Resolved Photoemission Spectroscopy
    • Place of Presentation
      UPMC Couvent des Cordeliers, Paris, France
    • Year and Date
      2015-07-05
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] SrTiO3の熱電特性に対する元素置換効果とフォノン異常2015

    • Author(s)
      梶本亮一
    • Organizer
      ミニ研究会「量子ビーム物性研究の展開」
    • Place of Presentation
      東北大学金属材料研究所 (宮城県、仙台市)
    • Year and Date
      2015-07-02
    • Related Report
      2015 Annual Research Report
  • [Presentation] Hole Doping Effect on the Magnetic State of Triangular Lattice Antiferromagnet CuCrO22015

    • Author(s)
      Tetsuji Okuda
    • Organizer
      The collaborative conference on 3D and Materials Research (CC3DMR)
    • Place of Presentation
      Busan, Korea
    • Year and Date
      2015-06-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Effect of Hole Doping on the Magnetic State of Delafossite CuCrO22015

    • Author(s)
      Tetsuji Okuda
    • Organizer
      Energy Materials Nanotechnology (EMN)
    • Place of Presentation
      Qingdao, China
    • Year and Date
      2015-06-14
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Thermoelectric Responses of Transition Metal Oxides Having Spin/Orbital Correlations2015

    • Author(s)
      Tetsuji Okuda
    • Organizer
      The BIT's 4th Annual World Congress of Advanced Materials-2015
    • Place of Presentation
      Chongqing, China
    • Year and Date
      2015-05-27
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] デラフォサイト型酸化物CuMO2 (M=Al,Cr,Fe)との比較によるクレドネライト型酸化物CuMnO2の電子構造2015

    • Author(s)
      加藤諒, 大川万里生, 和達大樹, 吉田鉄平, 小野寛太, 池永英司, 奥田哲治, 齋藤智彦
    • Organizer
      日本物理学会
    • Place of Presentation
      早稲田大学, 東京都新宿区
    • Year and Date
      2015-03-21 – 2015-03-24
    • Related Report
      2014 Research-status Report
  • [Presentation] La, Mn 置換したSrTiO3 におけるフォノン異常と熱電特性2015

    • Author(s)
      梶本亮一, 中村充孝, 畑博人, 江藤貴弘, 奥田哲治
    • Organizer
      第3回物構研サイエンスフェスタ & 第6回MLFシンポジウム
    • Place of Presentation
      つくば国際会議場(エポカルつくば), 茨城県つくば市
    • Year and Date
      2015-03-17 – 2015-03-18
    • Related Report
      2014 Research-status Report
  • [Presentation] CuMO2 (M = Al,Cr,Mn,Fe)の電子構造2015

    • Author(s)
      加藤諒, 大川万里生, 和達大樹, 吉田鉄平, 小野寛太, 池永英司, 奥田哲治, 斎藤智彦
    • Organizer
      第28回日本放射光学会年会
    • Place of Presentation
      立命館大学, 滋賀県草津市
    • Year and Date
      2015-01-10 – 2015-01-12
    • Related Report
      2014 Research-status Report
  • [Presentation] ホイスラー合金Ru2-xFexCrSi の熱電能と熱伝導率2014

    • Author(s)
      重松 理史,春森 浩平, 西迫 裕也, 重田 出, 奥田 哲治,三浦 良雄, 山内 徹, 廣井 政彦
    • Organizer
      第6回半導体材料・デバイスフォーラム
    • Place of Presentation
      都城ロイヤルホテル, 宮崎県都城市
    • Year and Date
      2014-12-21
    • Related Report
      2014 Research-status Report
  • [Presentation] N-type Oxide Thermoelecric Materials Having Spin/Orbital Correlations2014

    • Author(s)
      T. Okuda
    • Organizer
      The 31st International Korea-Japan Seminar on Ceramics
    • Place of Presentation
      Changwon, Korea
    • Year and Date
      2014-11-26 – 2014-11-29
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] CuCrO2の電子構造と磁気特性・輸送特性の関係2014

    • Author(s)
      加藤 諒, 大川万里生, 和達大樹, 吉田徹平, Kozina Xeniya, 池永英司, 小野寛太, 奥田哲治, 齋藤智彦
    • Organizer
      第75回日本応用物理学会秋季学術講演会
    • Place of Presentation
      北海道大学, 北海道札幌市
    • Year and Date
      2014-09-17 – 2014-09-20
    • Related Report
      2014 Research-status Report
  • [Presentation] La, Mn置換したSrTiO3におけるフォノン異常2014

    • Author(s)
      梶本亮一, 中村充孝, 畑博人, 江藤貴弘, 奥田哲治
    • Organizer
      日本物理学会
    • Place of Presentation
      中部大学, 愛知県春日井市
    • Year and Date
      2014-09-07 – 2014-09-10
    • Related Report
      2014 Research-status Report
  • [Presentation] ホイスラー合金Ru2-xFexCrSiの熱電特性2014

    • Author(s)
      重松理史, 春森浩平, 西迫裕也, 重田出, 奥田哲治, 山内徹, 廣井政彦
    • Organizer
      日本物理学会
    • Place of Presentation
      中部大学, 愛知県春日井市
    • Year and Date
      2014-09-07 – 2014-09-10
    • Related Report
      2014 Research-status Report
  • [Presentation] デラフォサイト型酸化物CuMO2 (M=Cr, Fe, Al)の電子構造2014

    • Author(s)
      加藤諒, 大川万里生, 小野寛太, 奥田哲治, 齋藤智彦
    • Organizer
      日本物理学会
    • Place of Presentation
      中部大学, 愛知県春日井市
    • Year and Date
      2014-09-07 – 2014-09-10
    • Related Report
      2014 Research-status Report
  • [Presentation] Effects of Mn Subsitution on the Thermoelectric Properties of the Electron-doped Perovskite Sr1-xLaxTiO32014

    • Author(s)
      T. Okuda, H. Hata, T. Etoh, K. Nishina, H. Kuwahara, M. Nakamura, and R. Kajimoto
    • Organizer
      The 27th International Conference on Low Temperature Physics (LT27)
    • Place of Presentation
      Buenos Aires, Argentina
    • Year and Date
      2014-08-06 – 2014-08-13
    • Related Report
      2014 Research-status Report
  • [Presentation] Effects of Mn substitution on the Thermoelectric Properties of the Electron-doped Perovskite SrTiO32014

    • Author(s)
      T. Okuda
    • Organizer
      EMN summer meeting
    • Place of Presentation
      Cancun, Mexico
    • Year and Date
      2014-06-09 – 2014-06-12
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] 電子ドープSrTiO3の熱電特性におけるMn置換効果2014

    • Author(s)
      畑博人、江藤貴弘、白石陽介、奥田哲治
    • Organizer
      日本物理学会 第69回年次大会
    • Place of Presentation
      東海大学湘南キャンパス
    • Related Report
      2013 Research-status Report
  • [Presentation] 光電子分光によるデラフォサイト型酸化物CuMO2 (M=Al,Fe)の電子構造の研究2014

    • Author(s)
      加藤諒、大川万里生、和達大樹、吉田鉄平、Xeniya Kozina、池永英司、小野寛太、奥田哲治、齋藤智彦
    • Organizer
      日本物理学会 第69回年次大会
    • Place of Presentation
      東海大学湘南キャンパス
    • Related Report
      2013 Research-status Report
  • [Presentation] Effect of Mn Substitution of the Thermoelectric Properties of the Electron-doped Perovskite SrTiO32014

    • Author(s)
      T. Okuda
    • Organizer
      EMN Summer Meeting
    • Place of Presentation
      カンクン(メキシコ)
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Low-Energy Spin Fluctuations in CuCrO2 andCu0.85Ag0.15CrO2 Studied by Inelastic Neutron Scattering2013

    • Author(s)
      Ryoichi Kajimoto, Kenji Nakajima, Seiko Ohira-Kawamura, Yasuhiro Inamura,Tetsuji Okuda, and Keisuke Tomiyasu
    • Organizer
      The international conference of strongly correlated electron systems
    • Place of Presentation
      東京大学
    • Related Report
      2013 Research-status Report
  • [Presentation] 三角格子反強磁性体CuCrO2における磁気散漫散乱2013

    • Author(s)
      梶本亮一,中島健次,河村聖子,稲村泰弘,奥田哲治,富安啓輔
    • Organizer
      日本物理学会 2013年秋季大会
    • Place of Presentation
      徳島大学
    • Related Report
      2013 Research-status Report
  • [Presentation] Ba2Ti6O13の合成と熱電特性2013

    • Author(s)
      待鳥雄祐,新村崇,江藤貴弘,後田慎太郎,奥田哲治
    • Organizer
      日本物理学会 2013年秋季大会
    • Place of Presentation
      徳島大学
    • Related Report
      2013 Research-status Report
  • [Presentation] ペロブスカイト型酸化物Sr1-xLaxTi1-yMnyO3の熱電特性2013

    • Author(s)
      畑博人,白石陽介,奥田哲治
    • Organizer
      日本物理学会 2013年秋季大会
    • Place of Presentation
      徳島大学
    • Related Report
      2013 Research-status Report
  • [Presentation] 三角格子反強磁性体CuCrO2における低エネルギー におけるスピン揺らぎ2013

    • Author(s)
      梶本亮一、中島健次、河村聖子、稲村泰弘、富安啓輔、奥田哲治
    • Organizer
      中性子科学会
    • Place of Presentation
      ちば県民プラザ(千葉県柏市柏の葉)
    • Related Report
      2013 Research-status Report

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Published: 2014-07-25   Modified: 2020-05-15  

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