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Self-ordering of liquid polymeric sulfur induced by spatial constraint - grazing-incident small-angle neutron scattering

Research Project

Project/Area Number 25400435
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Biological physics/Chemical physics/Soft matter physics
Research Institution一般財団法人総合科学研究機構(総合科学研究センター(総合科学研究室)及び東海事業センター(利用研究促進部))

Principal Investigator

Sakaguchi Yoshifumi  一般財団法人総合科学研究機構(総合科学研究センター(総合科学研究室)及び東海事業, その他部局等, 副主任研究員 (20397590)

Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2015: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2014: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2013: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Keywords自己秩序化 / 液体イオウ / 高分子 / 斜入射 / 中性子散乱 / ナノ構造 / 薄膜
Outline of Final Research Achievements

Our final goal of this project was to pursue self-ordering of liquid polymeric sulfur in a confined space using Grazing-Incidence Small-Angle Neutron Scattering (GISANS). However, it became difficult to perform the GISANS measurement in the research period due to a strong delay of the installation of the GISANS option on the beam line. Therefore, we set new realistic objectives of the project; a preparatory research using grazing-incidence measurement system, and the sample environment instrument installation for the GISANS experiment. For the former one, we performed time-resolved neutron reflectivity measurement for silver photo-diffusion into amorphous chalcogenide and the kinetics was clarified. For the latter one, we specially produced a furnace for small-angle neutron scattering instrument and the furnace became available on the small-angle neutron scattering instrument at the MLF in J-PARC.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (30 results)

All 2016 2015 2014 2013 Other

All Int'l Joint Research (3 results) Journal Article (7 results) (of which Int'l Joint Research: 3 results,  Peer Reviewed: 6 results,  Open Access: 2 results,  Acknowledgement Compliant: 5 results) Presentation (19 results) (of which Int'l Joint Research: 1 results) Book (1 results)

  • [Int'l Joint Research] ボイジー州立大学(米国)

    • Related Report
      2015 Annual Research Report
  • [Int'l Joint Research] ラザフォード アップルトン研究所(英国)

    • Related Report
      2015 Annual Research Report
  • [Int'l Joint Research] ラウエ ランジュバン研究所(フランス)

    • Related Report
      2015 Annual Research Report
  • [Journal Article] Processes of silver photo-diffusion into Ge-chalcogenide probed by neutron reflectivity technique2016

    • Author(s)
      Y. Sakaguchi, H. Asaoka, Y. Uozumi, Y. Kawakita, T. Ito, M. Kubota, D. Yamazaki, K. Soyama, G. Sheoran and M. Mitkova
    • Journal Title

      Physica Status Solidi A

      Volume: online Issue: 7 Pages: 1894-1903

    • DOI

      10.1002/pssa.201533037

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Measurement of Transient Photo-induced Changes in Thin Films at J-PARC – Time-resolved Neutron Reflectivity Measurements of Silver Photo-diffusion2015

    • Author(s)
      Yoshifumi SAKAGUCHI, Hidehito ASAOKA, Yuki UOZUMI, Yukinobu, KAWAKITA, Takayoshi ITO, Masato KUBOTA, Dai YAMAZAKI, Kazuhiko SOYAMA, Mahesh AILAVAJHALA, Kasandra WOLF, Maria MITKOVA, and Maximilian W. A. SKODA
    • Journal Title

      JPS Conf. Proc.

      Volume: 8 Pages: 031023-031023

    • DOI

      10.7566/jpscp.8.031023

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Dynamics of silver photo-diffusion into Ge-chalcogenide films: time-resolved neutron reflectometry2015

    • Author(s)
      Y Sakaguchi, H Asaoka, Y Uozumi, Y Kawakita, T Ito, M Kubota, D Yamazaki, K Soyama, M Ailavajhala, M R Latif, K Wolf, M Mitkova and M W A Skoda,
    • Journal Title

      Journal of Physics: Conference Series

      Volume: 619 Pages: 012046-012046

    • DOI

      10.1088/1742-6596/619/1/012046

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Measurement of Transient Photo-induced Changes in Thin Films at J-PARC – Time-resolved Neutron Reflectivity Measurements of Silver Photo-diffusion into Ge-chalcogenide Films2015

    • Author(s)
      Y. Sakaguchi, H. Asaoka, Y. Uozumi, Y. Kawakita, T. Ito, M. Kubota, D. Yamazaki, K. Soyama, M. Ailavajhala, K. Wolf, M. Mitkova, and M. W. A. Skoda
    • Journal Title

      JPS Conference Proceedings

      Volume: 未定

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Dynamics of silver photo-diffusion into Ge-chalcogenide films: time-resolved neutron reflectometry2015

    • Author(s)
      Y. Sakaguchi, H. Asaoka, Y. Uozumi, Y. Kawakita, T. Ito, M. Kubota, D. Yamazaki, K. Soyama, M. Ailavajhala, M. R. Latif, K. Wolf, M. Mitkova, and M. W. A. Skoda
    • Journal Title

      Journal of Physics: Conference Series

      Volume: 未定

    • Related Report
      2014 Research-status Report
    • Acknowledgement Compliant
  • [Journal Article] Studies of silver photo-diffusion dynamics in Ag/GexS1-x (x=0.2 and 0.4) films by means of neutron reflectometry2014

    • Author(s)
      Y. Sakaguchi, H. Asaoka, Y. Uozumi, Y. Kawakita, T. Ito, M. Kubota, D. Yamazaki, K. Soyama, M. Ailavajhala, M. R. Latif, M. Mitkova
    • Journal Title

      Can. J. Phys.

      Volume: 92 Issue: 7/8 Pages: 654-658

    • DOI

      10.1139/cjp-2013-0593

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Studies of silver photodiffusion dynamics in Ag/GexS1-x (x = 0.2 and 0.4) films using neutron reflectometry2014

    • Author(s)
      Y. Sakaguchi, H. Asaoka, Y. Uozumi, Y. Kawakita, T. Ito, M. Kubota, D. Yamazaki, K. Soyama, M. Ailavajhala, M.R. Latif, and M. Mitkova
    • Journal Title

      Canadian Journal of Physics

      Volume: 92

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] アモルファスGeカルコゲナイド薄膜への銀の光拡散の中性子反射率測定による研究 V2016

    • Author(s)
      坂口佳史 、朝岡秀人 、魚住雄輝 、近藤啓悦 、川北至信、伊藤崇芳、久保田正人、山崎大、曽山和彦、Mahesh Aillavajhara、Maria Mitkova
    • Organizer
      日本物理学会 第71回年次大会
    • Place of Presentation
      東北学院大学泉キャンパス
    • Year and Date
      2016-03-21
    • Related Report
      2015 Annual Research Report
  • [Presentation] アモルファスGeカルコゲナイドへの銀の光拡散の時間分解中性子反射率測定2015

    • Author(s)
      坂口佳史、朝岡秀人、魚住雄輝、川北至信、伊藤崇芳、久保田正人、山崎大、曽山和彦、G. Sheoran、M. Mitkova、P. Gutfreund、R. Cubitt
    • Organizer
      日本中性子科学会 第15回年会
    • Place of Presentation
      和光市民文化センター「サンアゼリア」 埼玉県和光市
    • Year and Date
      2015-12-11
    • Related Report
      2015 Annual Research Report
  • [Presentation] Processes of silver photo-diffusion into Ge-chalcogenide probed by neutron reflectivity technique2015

    • Author(s)
      Y. Sakaguchi, H. Asaoka, Y. Uozumi, Y. Kawakita, T. Ito, M. Kubota, D. Yamazaki, K. Soyama, G. Sheoran, and M. Mitkova
    • Organizer
      26th International Conference on Amorphous and nanocrystalline Semiconductors
    • Place of Presentation
      EUROGRESS, Aachen, Germany
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 空間的束縛を受けた液体イオウ高分子の自己秩序化2015

    • Author(s)
      坂口佳史
    • Organizer
      東京大学物性研究所短期研究会 ガラス転移と周辺分野の科学
    • Place of Presentation
      東京大学物性研究所 千葉県柏市
    • Year and Date
      2015-07-30
    • Related Report
      2015 Annual Research Report
  • [Presentation] アモルファスGeカルコゲナイド薄膜への銀の光拡散の中性子反射率測定による研究 IV2015

    • Author(s)
      坂口佳史1 、朝岡秀人2 、魚住雄輝2 、川北至信2 、 伊藤崇芳1 、久保田正人2 、山崎大2 、曽山和彦2 、Kasandra Wolf3 、Maria Mitkova
    • Organizer
      日本物理学会 第70回年次大会
    • Place of Presentation
      早稲田大学早稲田キャンパス
    • Year and Date
      2015-03-22
    • Related Report
      2014 Research-status Report
  • [Presentation] 中性子反射率測定による アモルファスカルコゲナイドへの銀の光拡散の研究2015

    • Author(s)
      坂口佳史1、朝岡秀人2、魚住雄輝2、川北至信2、伊藤崇芳1、久保田正人2、山崎大2、曽山和彦2、K. Wolf3、M. Mitkova3
    • Organizer
      第6回MLFシンポジウム
    • Place of Presentation
      つくば国際会議場
    • Year and Date
      2015-03-17
    • Related Report
      2014 Research-status Report
  • [Presentation] 光照射下の銀/アモルファスGeカルコゲナイド薄膜の時分割中性子反射率測定 II2014

    • Author(s)
      坂口佳史1、朝岡秀人2、魚住雄輝2、川北至信2、伊藤崇芳1、久保田正人2、山崎大2、曽山和彦2、M. Ailavajhala 3、K. Wolf3、M. Mitkova
    • Organizer
      日本中性子科学会第14回年会
    • Place of Presentation
      北海道立道民活動センター「かでる2・7」
    • Year and Date
      2014-12-11
    • Related Report
      2014 Research-status Report
  • [Presentation] Light irradiation experiments at J-PARC - installation and demonstration2014

    • Author(s)
      Yoshifumi Sakaguchi1, Koji Munakata1, Motoyuki Ishikado1, Yasuhiro Yamauchi2, Wataru Kambara2, Seiko Ohira-Kawamura2, Yukinobu Kawakita2, Tetsuya Yokoo3, Tomokazu Aso1 and Kazuya Aizawa1
    • Organizer
      International Collaboration on Advanced Neutron Sources XXI
    • Place of Presentation
      茨城県民文化センター
    • Year and Date
      2014-09-30 – 2014-10-02
    • Related Report
      2014 Research-status Report
  • [Presentation] 中性子反射率測定による Geカルコゲナイド薄膜への銀の光拡散の研究 III2014

    • Author(s)
      坂口佳史、朝岡秀人、魚住雄輝、川北至信、 伊藤崇芳、久保田正人 、山崎大 、曽山和彦、M. Ailavajhala、K. Wolf、M. Mitkova、M. W. A. Skoda
    • Organizer
      第75回応用物理学会秋季学術講演会
    • Place of Presentation
      北海道大学
    • Year and Date
      2014-09-18
    • Related Report
      2014 Research-status Report
  • [Presentation] アモルファスGeカルコゲナイド薄膜への銀の光拡散の中性子反射率測定による研究 III2014

    • Author(s)
      坂口佳史、朝岡秀人、魚住雄輝、川北至信、 伊藤崇芳、久保田正人 、山崎大 、曽山和彦、M. Ailavajhala、K. Wolf、M. Mitkova、M. W. A. Skoda
    • Organizer
      日本物理学会2014年秋季大会
    • Place of Presentation
      中部大学
    • Year and Date
      2014-09-08
    • Related Report
      2014 Research-status Report
  • [Presentation] Dynamics of silver photo-diffusion into Ge-chalcogenide films: time-resolved neutron reflectometry2014

    • Author(s)
      Y. Sakaguchi, H. Asaoka, Y. Uozumi, Y. Kawakita, T. Ito, M. Kubota, D. Yamazaki, K. Soyama, M. Ailavajhala, M. R. Latif, K. Wolf, M. Mitkova, and M. W. A. Skoda
    • Organizer
      6th International Conference on Optical, Optoelectronic and Photonic Materials and Applications
    • Place of Presentation
      Leeds, UK
    • Year and Date
      2014-07-28
    • Related Report
      2014 Research-status Report
  • [Presentation] Transient measurement for photo-induced changes in J-PARC - time-resolved neutron reflectivity measurement for silver photo-diffusion into Ge-chalcogenide films-2014

    • Author(s)
      Y. Sakaguchi, H. Asaoka, Y. Uozumi, Y. Kawakita, T. Ito, M. Kubota, D. Yamazaki, K. Soyama, M. Ailavajhala, K. Wolf, M. Mitkova, and M. W. A. Skoda
    • Organizer
      The 2nd International Symposium on Science at J-PARC
    • Place of Presentation
      つくば国際会議場
    • Year and Date
      2014-07-14
    • Related Report
      2014 Research-status Report
  • [Presentation] Studies of Silver Photo-Diffusion Dynamics in Ag/GexS1-x (x=0.2 and 0.4) Films by Means of Neutron Reflectometry2013

    • Author(s)
      Y. Sakaguchi
    • Organizer
      The 25th International Conference on Amorphous and Nanocrystalline Semiconductors
    • Place of Presentation
      トロント カナダ
    • Related Report
      2013 Research-status Report
  • [Presentation] Time-resolved neutron reflectivity measurements for silver photo-diffusion in Ag/Ge-S films2013

    • Author(s)
      Y. Sakaguchi
    • Organizer
      Light and Particle Beams in Materials Science 2013
    • Place of Presentation
      つくば国際会議場、 つくば
    • Related Report
      2013 Research-status Report
  • [Presentation] Investigation on In-plane Structure of Thin Films by Use of Glazing Incidence Neutron Diffraction-Test Experiment on Polarized Neutron Reflectometer at J-PARC-2013

    • Author(s)
      Y. Sakaguchi, T. Kawasaki, T. Hanashima (発表者), et al.
    • Organizer
      The 12th Asia Pacific Physics Conference of AAPPS
    • Place of Presentation
      幕張メッセ 千葉
    • Related Report
      2013 Research-status Report
  • [Presentation] 中性子反射率測定法による Geカルコゲナイド薄膜への銀の光拡散の研究 II2013

    • Author(s)
      坂口佳史
    • Organizer
      第74回応用物理学会秋季学術講演会
    • Place of Presentation
      同志社大学 京田辺
    • Related Report
      2013 Research-status Report
  • [Presentation] アモルファスGeカルコゲナイド薄膜への銀の光拡散の中性子反射率測定による研究 II2013

    • Author(s)
      坂口佳史
    • Organizer
      日本物理学会2013年秋季大会
    • Place of Presentation
      徳島大学 徳島
    • Related Report
      2013 Research-status Report
  • [Presentation] 光照射下の 銀/アモルファスGeカルコゲナイド薄膜の 時分割中性子反射率測定2013

    • Author(s)
      坂口佳史
    • Organizer
      日本中性子科学会第13回年会
    • Place of Presentation
      さわやかちば県民プラザ (千葉県柏市)
    • Related Report
      2013 Research-status Report
  • [Presentation] Time-resolved neutron reflectivity measurements of Ag/Ge-chalcogenide films during illumination by visible light: investigation of the silver photo-diffusion kinetics

    • Author(s)
      Y. Sakaguchi
    • Organizer
      Third International Workshop SKIN2014 -Studying Kinetics with Neutrons
    • Place of Presentation
      ラウエ・ランジュバン研究所 グルノーブル フランス共和国
    • Related Report
      2013 Research-status Report
  • [Book] N氏の新たなる冒険(日本中性子科学会 世界結晶年IYCr2014記念特別号)(パンフレット扱)2014

    • Author(s)
      日本中性子科学会 編集 (編集委員長として関係)
    • Total Pages
      46
    • Publisher
      (株)マックグラフィックアーツ
    • Related Report
      2014 Research-status Report

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Published: 2014-07-25   Modified: 2022-01-31  

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