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Development of the gas-phase electron diffraction apparatus for the structural determination of aerosols

Research Project

Project/Area Number 25410026
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Physical chemistry
Research InstitutionSophia University

Principal Investigator

KUZE Nobuhiko  上智大学, 理工学部, 准教授 (80286757)

Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2015: ¥520,000 (Direct Cost: ¥400,000、Indirect Cost: ¥120,000)
Fiscal Year 2014: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2013: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Keywords気体電子回折 / エアロゾル / クラスター / エアロダイナミック・レンズ
Outline of Final Research Achievements

The purpose of this research project is to establish a structure determination method of atmospheric aerosols. In order to achieve this objective, we have developed a gas electron diffraction GED apparatus. GED is a powerful experimental method for the precise structural determination for the gas molecule. In this study, we had designed and manufactured a new type of gas nozzle, aerodynamic lens, in order to efficiently generate a cluster or aerosol. It was covered by the metal jacket and attached to the vacuum chamber of GED apparatus. We also redesigned and developed the vacuum line of the apparatus to make the table-top size of the entire experimental apparatus. Further, new computer program was developed for the data analysis of the diffraction data. It can be used for the wide variety of the target molecules.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (14 results)

All 2016 2015 2014 2013 Other

All Journal Article (4 results) (of which Peer Reviewed: 4 results,  Open Access: 2 results,  Acknowledgement Compliant: 1 results) Presentation (10 results) (of which Int'l Joint Research: 3 results,  Invited: 2 results)

  • [Journal Article] Molecular structure and internal rotation of CH2Cl group of chloropropanone oxime: gas electron diffraction, microwave spectroscopy, and quantum chemical calculation studies2015

    • Author(s)
      Nobuhiko Kuze, Takashi Watado, Yuri Takahashi, Takeshi Sakaizumi, Osamu Ohashi, Minako Kiuchi, Kinya Iijima
    • Journal Title

      Structural Chemistry

      Volume: 26 Issue: 5-6 Pages: 1241-1257

    • DOI

      10.1007/s11224-015-0649-x

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] PCI effects and the gradual formation of Rydberg series due to photoelectron recapture, in the Auger satellite lines upon Xe 4d 5/2 photoionization2015

    • Author(s)
      Satoshi Kosugi, Masatomi Iizawa, Yu Kawarai, Yosuke Kuriyama, A L David Kilcoyne, Fumihiro Koike, Nobuhiko Kuze, Daniel S Slaughter, Yoshiro Azuma
    • Journal Title

      Journal of Physics B: Atomic, Molecular and Optical Physics

      Volume: 48 Issue: 11 Pages: 1150031-1150034

    • DOI

      10.1088/0953-4075/48/11/115003

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Molecular Structure and Internal Rotation of CF3 Group of Methyl Trifluoroacetate: Gas Electron Diffraction, Microwave Spectroscopy, and Quantum Chemical Calculation Studies2015

    • Author(s)
      Nobuhiko Kuze, Atsushi Ishikawa, Maho Kono, Takayuki Kobayashi, Noriyuki Fuchisawa, Takemasa Tsuji, Hiroshi Takeuchi
    • Journal Title

      Journal of Physical Chemistry A

      Volume: 119 Issue: 9 Pages: 1774-1786

    • DOI

      10.1021/jp508447b

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Microwave spectroscopy of AgCCH and AuCCH in the X 1Sigma+ states2013

    • Author(s)
      T. Okabayashi, H. Kubota, M. Araki, N. Kuze
    • Journal Title

      Chem. Phys. Lett.

      Volume: 577 Pages: 11-15

    • DOI

      10.1016/j.cplett.2013.05.027

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] 2D Potential Energy Surfaces of N-Benzylidene Aniline and 1, 3-Dichloropropanone Oxime by Gas Electron Diffraction and Computational Methods2016

    • Author(s)
      Nobuhiko Kuze
    • Organizer
      26th Austin Symposium on Molecular Structure and Dynamics @ Dallas
    • Place of Presentation
      Dallas, Texas, USA
    • Year and Date
      2016-03-06
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Effects of the anharmonic vibrational corrections on molecular structures of acetates and oximes: gas-phase electron diffraction and quantum-chemical studies2015

    • Author(s)
      Nobuhiko Kuze, Yuuki Tajimi and Atsushi Ishikawa
    • Organizer
      2015 International Chemical Congress of Pacific Basin Societies (Pacifichem 2015)
    • Place of Presentation
      Honolulu, Hawaii, USA
    • Year and Date
      2015-12-17
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Rotational spectrum and quantum chemical calutations for methyl trimethyl acetate2015

    • Author(s)
      Yuuki Tajimi, Rie Nomura and Nobuhiko Kuze
    • Organizer
      2015 International Chemical Congress of Pacific Basin Societies (Pacifichem 2015)
    • Place of Presentation
      Honolulu, Hawaii, USA
    • Year and Date
      2015-12-17
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Methyl trimethyl acetateのマイクロ波分光2015

    • Author(s)
      多治見雄暉, 野村梨絵, 石川敦士, 久世信彦
    • Organizer
      第9回分子科学討論会
    • Place of Presentation
      東京工業大学大岡山キャンパス
    • Year and Date
      2015-09-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] DETECTABILITY OF PROLATE SYMMETRIC-TOP MOLECULES IN DIFFUSE CLOUDS BY A “HOT-AXIS EFFECT”2014

    • Author(s)
      Mitsunori Araki, Shuro Takano, Nobuhiko Kuze, Takahiro Oyama, Koichi Tsukiyama
    • Organizer
      Workshop on Interstellar Matter 2014
    • Place of Presentation
      Institute of Low Temperature Science, Hokkaido University
    • Year and Date
      2014-10-16 – 2014-10-18
    • Related Report
      2014 Research-status Report
  • [Presentation] リメチル酢酸メチルのtert-ブチル基大振幅振動における分子構造への影響2014

    • Author(s)
      石川敦士, 久世信彦, 國井清美, 辻武正, 竹内浩, 小中重弘
    • Organizer
      第8回分子科学討論会
    • Place of Presentation
      広島大学 東広島キャンパス
    • Year and Date
      2014-09-21 – 2014-09-24
    • Related Report
      2014 Research-status Report
  • [Presentation] MOLECULAR STRUCTURES OF METHYL TRIMETHYLACETATE AND METHYL TRIFLUOROACETATE BY GAS-PHASE ELECTRON DIFFRACTION AND QUANTUM CHEMICAL CALCULATION

    • Author(s)
      Atsushi Ishikawa, Nobuhiko Kuze, Maho Kohno, Kiyomi Kunii, Noriyuki Fuchikawa, Takemasa Tsuji, Hiroshi Takeuchi, Shigehiro Konaka
    • Organizer
      25th Austin Symposium on Molecular Structure and Dynamics @ Dallas
    • Place of Presentation
      Dallas, Texas, USA
    • Related Report
      2013 Research-status Report
  • [Presentation] THREE TOPICS IN GAS-PHASE STRUCTURES OF MALTOL, DIACETYLENE AND ETHYLENE: GAS ELECTRON DIFFRACTION, IR AND MD STUDIES

    • Author(s)
      Nobuhiko Kuze, Ryosuke Tanemura, Ryo Noda, and Tomoko Soyama
    • Organizer
      25th Austin Symposium on Molecular Structure and Dynamics @ Dallas
    • Place of Presentation
      Dallas, Texas, USA
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] LARGE-AMPLITUDE MOTIONS FOR METHYL TRIFLUOROACETATE AND 2, 5-DIMETHYLFURAN BY GED, MW AND QUANTUM CHEMICAL CALCULATION

    • Author(s)
      Nobuhiko Kuze, Atsushi Ishikawa, Yuya Ono, Hiroshi Takeuchi, Shigehiro Konaka
    • Organizer
      15th European Symposium on Gas Electron Diffraction
    • Place of Presentation
      Frauenchiemsee, Germany
    • Related Report
      2013 Research-status Report
  • [Presentation] トリフルオロ酢酸メチルのCF3基大振幅振動における分子振動の非調和性の影響

    • Author(s)
      石川 敦士,久世 信彦,河野 麻帆,小林 孝行,辻 武正,竹内 浩,小中 重弘
    • Organizer
      第7回分子科学討論会
    • Place of Presentation
      京都テルサ,京都
    • Related Report
      2013 Research-status Report

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Published: 2014-07-25   Modified: 2019-07-29  

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