Synthesis of distorted pi conjugated molecules by intermolecular radical reactions
Project/Area Number |
25410039
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Research Category |
Grant-in-Aid for Scientific Research (C)
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Allocation Type | Multi-year Fund |
Section | 一般 |
Research Field |
Organic chemistry
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Research Institution | Nagoya University |
Principal Investigator |
Hiroto Satoru 名古屋大学, 工学(系)研究科(研究院), 助教 (30547427)
|
Project Period (FY) |
2013-04-01 – 2016-03-31
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Project Status |
Completed (Fiscal Year 2015)
|
Budget Amount *help |
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2015: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2014: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2013: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
|
Keywords | ポルフィリン / π曲面 / ヘリセン / バッキーボウル / フラーレン包接 / キラル誘起 / キラル発光 / フラーレン / キャリア移動度 / 歪み / ねじれ / π共役分子 / 酸化的縮環反応 |
Outline of Final Research Achievements |
Curved-π conjugated molecules have attracted considerable intersts for the potential application to novel molecular devices based on the unique properties originating from the curved-π surface. In this project, we have achieved novel kinds of curved-π molecules with brilliant functions under mild reaction conditions, which are originated in conventional aniline and phenol oxidations. Accordingly, we have succeeded in the synthesis of highly twisted porphyrin oligomers with the largest twisting angle reported before. In addition, we disclosed the high chiral emissive feature of π-extended helicenes based on anthracenes. Finally, we have accomplished the synthesis of nitrogen-embedded buckybowl, which has been impossible to be synthesized under conventional conditions.
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Report
(4 results)
Research Products
(56 results)
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[Journal Article] Near-IR Absorbing Nickel(II) Porphyrinoids Prepared by Regioselective Insertion of Silylenes into Antiaromatic Nickel(II) Norcorrole2014
Author(s)
Takaki Fukuoka, Kenya Uchida, Young Mo Sung, Ji-Young Shin, Shintaro Ishida, Dr. Jong Min Lim, Satoru Hiroto, Ko Furukawa, Dongho Kim, Takeaki Iwamoto, Hiroshi Shinokubo
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Journal Title
Angewandte Chemie, International Edition
Volume: 53
Issue: 6
Pages: 1506-1509
DOI
Related Report
Peer Reviewed / Acknowledgement Compliant
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