| Budget Amount *help |
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2015: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2014: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2013: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
|
|---|
| Outline of Final Research Achievements |
Novel Dibenzosilaborins, in which the two benzene rings are bridged by a silicon atom and a boron atom, have been synthesized. The molecular structure and electronic structure of the dibenzosilaborins were investigated. X-ray crystallographic analysis of the compounds revealed that the geometries of the dibenzosilaborins are almost planar. DFT calculations revealed that the pπ orbitals on the benzene rings, the vacant p orbital on the boron atom, and the σ* orbital on the silicon atom are interacted wit each other, which lowers the energy level of LUMO.
|
