Synthesis, absorption and fluorescent properties of functionalized azulene derivatives
| Project/Area Number |
25410046
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Organic chemistry
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| Research Institution | Yamaguchi University |
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Principal Investigator |
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| Project Period (FY) |
2013-04-01 – 2016-03-31
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| Project Status |
Completed (Fiscal Year 2015)
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| Budget Amount *help |
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2015: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2014: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2013: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
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| Keywords | アズレン / 光機能 / ビアズレン / 発光 / 呈色 / π電子系 |
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| Outline of Final Research Achievements |
1,1'-Bi(2-pyridylazulene), in which pyridyl moieties were coupled to a biazulenyl framework for hydrogen bonding between the two azulenyl skeletons. The longest wavelength absorption band of this compound underwent a blue shift or red shift depending on the amount of trifluoroacetic acid added. In addition, single crystals of the mono-protonated species were successfully obtained as the tetrafluoroborate salt. The X-ray diffraction analysis of the salt revealed an intramolecular hydrogen bond between the two pyridyl moieties, giving a racemic mixture of axial chiral species.
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Report
(4 results)
Research Products
(11 results)
