Synthesis and functionalization of multilayered [3.3]cyclophanes
| Project/Area Number |
25410050
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Organic chemistry
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| Research Institution | Oita University |
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Principal Investigator |
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| Project Period (FY) |
2013-04-01 – 2016-03-31
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| Project Status |
Completed (Fiscal Year 2015)
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| Budget Amount *help |
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2015: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2014: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2013: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
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| Keywords | シクロファン / 渡環π電子相互作用 / 分子ワイヤー / 色素増感剤 / パラシクロファン |
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| Outline of Final Research Achievements |
I examined the synthesis of multilayered [3.3]para and metacyclophanes to perform a systematic study on the transannular π-electronic interaction by both through-space and/or through-bond electronic interactions.
In addition, in the donor (D) -bridge (B)- acceptor (A) systems that incorporated [3.3]cyclophanes, I succeeded the synthesis of all four possible isomers of dibromo[3.3]paracyclophanes, i.e., pseudogeminal, pseudoortho, pseudometa, and pseudopara isomers. In the [3.3]metacyclophane systems, I succeeded the synthesis of three- and four-layered dibromo[3.3]metacyclophanes, and incorporated the acceptor (naphthalimide) and the donor (carbazole) moieties into both ends benzene rings.
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Report
(4 results)
Research Products
(25 results)
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[Journal Article] Synthesis, Physical Properties, and Structure of TIPS-Difuranoacenes2014
Author(s)
Watanabe, M.; Chien, C-T.; Lin, Y-D.; Chang Y. J.; Wen, Y-S.; Goto, K.; Shibahara, M.; Shinmyozu, T.; Chow, T. J
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Journal Title
Tetrahedron Lett
Volume: 55
Issue: 8
Pages: 1424-1427
DOI
Related Report
Peer Reviewed
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