| Budget Amount *help |
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2015: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2014: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2013: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
|
|---|
| Outline of Final Research Achievements |
It is well-known that the metal ion can be obtained by oxidation of elemental metal. For example, copper(II) ion showing the blue color is formed by the oxidation of copper metal. The highest valence state of copper ion can be considered to be +IV state in general. However formation of the highest valence state of the metal ions are quite difficult due to their instability, and therefore detailed properties of the highest valence state metal complexes are still unclear. In this project, determination of the detailed electronic structures of the highest oxidation state of metal complexes, especially copper(IV) and nickel(IV) complexes as formal oxidation number with diphenolate salen ligand, has been attempted.
|
