Synthesis and Reactivity of Dinuclear Complexes Supported by Linear Tetraphosphine Ligands
| Project/Area Number |
25410069
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | Nara Women's University |
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Principal Investigator |
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| Co-Investigator(Renkei-kenkyūsha) |
Tanase Tomoaki 奈良女子大学, 自然科学系, 教授 (50207156)
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| Project Period (FY) |
2013-04-01 – 2016-03-31
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| Project Status |
Completed (Fiscal Year 2015)
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| Budget Amount *help |
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2015: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2014: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2013: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
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| Keywords | 複核錯体 / 多核錯体 / 四座ホスフィン / 協同効果 / ロジウム / イリジウム / 銅 / 四座ホスフィン配位子 |
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| Outline of Final Research Achievements |
With an aim to develop new reaction promoted by cooperative effects from two proximate metal centers that would not be established by single metal center, synthesis and reactivities of dinuclear complexes supported by linear tetraphosphine dpmppp ligand were investigated. The aromatic C-H bond activation at dinuclear iridium complexes is assumed to proceed through a two-metal-cooperative pathway switching metal-to metal dative interactions on and off based on X-ray analysis and theoretical calculations.
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Report
(4 results)
Research Products
(53 results)
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[Journal Article] Synthesis, Magnetic Properties, and X-ray Spectroscopy of Divalent Cobalt(II) and Nickel(II) Cubanes [MII4(HL2)4(OAc)4]2015
Author(s)
A. Scheurer, J. Korzekwa, T. Nakajima, F. Hampel, A. Buling, C. Derks, M. Neumann, L. Joly, K. Petukhov, K. Gieb, P. Müller, K. Kuepper, and K. Meyer
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Journal Title
Eur. J. Inorg. Chem.
Volume: 2015
Issue: 11
Pages: 1872-1901
DOI
Related Report
Peer Reviewed
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[Journal Article] Electron-Deficient Pt2M2Pt2 Hexanuclear Metal Strings (M = Pt, Pd) Supported by Triphosphine Ligands2014
Author(s)
E. Goto, R. A. Begum, C. Ueno, A. Hosokawa, C. Yamamoto, K. Nakamae, B. Kure, T. Nakajima, T. Kajiwara, and T. Tanase
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Journal Title
Organometallics
Volume: ３３
Issue: 8
Pages: 1893-1904
DOI
Related Report
Peer Reviewed
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[Presentation] Wheel-Shaped Icosanuclear Homo- and Heterometallic Complexes of NiII, CoII, and CuII Ions Supported by Unsymmetrical Aminoalcohol Ligands2014
Author(s)
T. NAKAJIMA, K. SETO, F. HOSOKAWA, I. SHIMIZU, A. SCHEURER, B. KURE, T. KAJIWARA, T. TANASE , M. MIKURIYA
Organizer
The 41st International Conference on Coordination Chemistry (ICCC41)
Place of Presentation
シンガポール
Year and Date
2014-07-21
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