Synthesis and Reactivity of Dinuclear Complexes Supported by Linear Tetraphosphine Ligands

• Project/Area Number: 25410069
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Multi-year Fund
• Section: 一般
• Research Field: Inorganic chemistry
• Research Institution: Nara Women's University
• Principal Investigator: Takayuki Nakajima 奈良女子大学, 自然科学系, 准教授 (80322676)
• Co-Investigator(Renkei-kenkyūsha): Tanase Tomoaki 奈良女子大学, 自然科学系, 教授 (50207156)
• Project Period (FY): 2013-04-01 – 2016-03-31
• Project Status: Completed (Fiscal Year 2015)
• Budget Amount: ¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000); Fiscal Year 2015: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000); Fiscal Year 2014: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000); Fiscal Year 2013: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
• Keywords: 複核錯体 / 多核錯体 / 四座ホスフィン / 協同効果 / ロジウム / イリジウム / 銅 / 四座ホスフィン配位子

Outline of Final Research Achievements

With an aim to develop new reaction promoted by cooperative effects from two proximate metal centers that would not be established by single metal center, synthesis and reactivities of dinuclear complexes supported by linear tetraphosphine dpmppp ligand　were investigated. The aromatic C-H bond activation at dinuclear iridium complexes is assumed to proceed through a two-metal-cooperative pathway switching metal-to metal dative interactions on and off based on X-ray analysis and theoretical calculations.

Research Products

• [Journal Article] Systematic Synthesis of Di-, Tri-, and Tetranuclear Homo- and Heterometal Complexes Using a Mononuclear Copper Synthon with a Tetradentate Aminoalcohol Ligand (2016)
  • Author(s): T. Nakajima, C. Yamashiro, M. Taya, B. Kure, T. Tanase
  • Journal Title: Eur. J. Inorg. Chem. Volume: 2016
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Electron-rich Linear Triplatinum Complexes Stabilized by a Spinning Tetraphosphine, Tris(diphenylphosphinomethyl)phosphine (2016)
  • Author(s): Tanase, T.; Koike, K.; Uegaki, M.; Hatada, S.; Nakamae, K.; Kure, B.; Ura, Y.; Nakajima, T.
  • Journal Title: Dalton Trans. Volume: 45 Issue: 17 Pages: 7209-7214
  • DOI: 10.1039/c6dt00624h
  • Peer Reviewed
• [Journal Article] Oxidative Addition of an Aromatic ortho C-H bond of Tetraphosphine to Asymmetric Diiridium(I) Centers (2016)
  • Author(s): Nakajima, T.; Noda, S.; Sakamoto, M.; Matsui, A.; Nakamae, K.; Kure, B.; Ura, Y.; Tanase, T.
  • Journal Title: Dalton Trans. Volume: 45 Issue: 11 Pages: 4747-4761
  • DOI: 10.1039/c5dt04725k
  • Peer Reviewed
• [Journal Article] Gold and Silver Chains Supported by Linear Hexaphosphine Ligands (2015)
  • Author(s): Tanse, T.; Chikanishi, M.; Morita, K.; Nakamae, K.; Kure, B.; Nakajima, T.
  • Journal Title: Chem. Asian J. Volume: 10 Issue: 12 Pages: 2619-2623
  • DOI: 10.1002/asia.201500876
  • Peer Reviewed
• [Journal Article] Synthesis and Structures of Binuclear RhIII and IrIII Complexes Supported by a Tetraphosphine, meso- or ran- bis{[(diphenylphosphinomethyl)phenyl]phosphino}methane (2015)
  • Author(s): Tanase, T.; Yoshii, A.; Otaki, R.; Nakamae, K.; Mikita, Y.; Kure, B.; Nakajima, T.
  • Journal Title: J. Organomet. Chem. Volume: 797 Pages: 37-45
  • DOI: 10.1016/j.jorganchem.2015.07.033
  • Peer Reviewed
• [Journal Article] Synthesis, Magnetic Properties, and X-ray Spectroscopy of Divalent Cobalt(II) and Nickel(II) Cubanes [MII4(HL2)4(OAc)4] (2015)
  • Author(s): A. Scheurer, J. Korzekwa, T. Nakajima, F. Hampel, A. Buling, C. Derks, M. Neumann, L. Joly, K. Petukhov, K. Gieb, P. Müller, K. Kuepper, and K. Meyer
  • Journal Title: Eur. J. Inorg. Chem. Volume: 2015 Issue: 11 Pages: 1872-1901
  • DOI: 10.1002/ejic.201402988
  • Peer Reviewed
• [Journal Article] Self-Alignment of Low-Valent Octanuclear Palladium Atoms (2015)
  • Author(s): Kanako Nakamae, Yukie Takemura, Bunsho Kure, Takayuki Nakajima, Yasutaka Kitagawa, Tomoaki Tanase
  • Journal Title: Angew. Chem. Int. Ed. Volume: 54 Issue: 3 Pages: 1016-1021
  • DOI: 10.1002/anie.201409511
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Facile Insertion of Carbon Dioxide into Cu2(μ-H) Dinuclear Units Supported by Tetraphosphine Ligands (2014)
  • Author(s): Kanako Nakamae, Bunsho Kure, Takayuki Nakajima, Yasuyuki Ura, Tomoaki Tanase
  • Journal Title: Chem. Asian J. Volume: 9 Issue: 11 Pages: 3106-3110
  • DOI: 10.1002/asia.201402900
  • Peer Reviewed
• [Journal Article] Tetranuclear Nickel and Cobalt Complexes with an Incomplete Double-Cubane Structure - Homo- and Heterometallic Complexes and Their 1D Coordination Polymers (2014)
  • Author(s): T. Nakajima, K. Seto, A. Scheurer, B. Kure, T. Kajiwara, T. Tanase, M. Mikuriya, H. Sakiyama
  • Journal Title: Eur. J. Inorg. Chem Volume: 2014 Issue: 29 Pages: 5021-5033
  • DOI: 10.1002/ejic.201402536
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Synthesis and Structures of Pd2M2 (M = Cu, Au) and Pd2M (M = Cu, Ag) Mixed-metal Complexes Supported by NPPN Tetradentate Ligands (2014)
  • Author(s): T. Nakajima, M. Tsuji, N. Hamada, Y. Fukushima, B. Kure, T. Tanase
  • Journal Title: J. Organomet. Chem. Volume: 768 Pages: 61-67
  • DOI: 10.1016/j.jorganchem.2014.06.022
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Systematic Heterodinuclear Complexes with MM′(μ-meppp) Centers that Tune the Properties of a Nesting Hydride (M = Ni, Pd, Pt; M′ = Rh, Ir; H2meppp = meso -1,3-Bis[(mercaptoethyl)phenylphosphino]propane) (2014)
  • Author(s): B. Kure, M. Sano, T. Nakajima, T. Tanase
  • Journal Title: Organometallics Volume: 33 Issue: 15 Pages: 3950-3965
  • DOI: 10.1021/om500410f
  • Peer Reviewed
• [Journal Article] One-dimensional Anisotropic Metal Organic Module Containing a Pt6 Chain Terminated with Redox Active Ferrocenyl Units (2014)
  • Author(s): T. Tanase, C. Yamamoto, B. Kure, and T. Nakajima
  • Journal Title: Chem. Lett. Volume: ４３ Issue: 6 Pages: 913-915
  • DOI: 10.1246/cl.140161
  • NAID: 130004868205
  • Peer Reviewed
• [Journal Article] Electron-Deficient Pt2M2Pt2 Hexanuclear Metal Strings (M = Pt, Pd) Supported by Triphosphine Ligands (2014)
  • Author(s): E. Goto, R. A. Begum, C. Ueno, A. Hosokawa, C. Yamamoto, K. Nakamae, B. Kure, T. Nakajima, T. Kajiwara, and T. Tanase
  • Journal Title: Organometallics Volume: ３３ Issue: 8 Pages: 1893-1904
  • DOI: 10.1021/om401211d
  • Peer Reviewed
• [Journal Article] Strongly Luminous Tetranuclear Gold(I) Complexes Supported by Tetraphosphine Ligands, meso- or rac-Bis[(diphenylphosphinomethyl)phenylphosphino]methane (2014)
  • Author(s): T. Tanase, R. Otaki, T. Nishida, H. Takenaka, Y. Takemura, B. Kure, T. Nakajima, Y. Kitagawa, T. Tsubomura
  • Journal Title: Chem. Euro. J. Volume: 20 Issue: 6 Pages: 1577-1596
  • DOI: 10.1002/chem.201303729
  • Peer Reviewed
• [Journal Article] Configurational Isomerization of Dinuclear Iridium and Rhodium Complexes with a Series of NPPN Ligands, 2-PyCH2(Ph)P(CH2)nP(Ph)CH2-2-Py (Py = pyridyl, n = 2-4) (2013)
  • Author(s): T. Nakajima, Y. Fukushima, M. Tsuji, N. Hamada, B. Kure, and T. Tanase
  • Journal Title: Organometallics Volume: ３２ Issue: 24 Pages: 7470-7477
  • DOI: 10.1021/om400965j
  • Peer Reviewed
• [Journal Article] Flexible, linear, tetranuclear palladium complexes supported by tetrapho sphine ligands with electron-withdrawing groups (2013)
  • Author(s): 棚瀬知明, 中前佳那子
  • Journal Title: Dalton Trans Volume: VOL.42 Issue: 45 Pages: 15941-15952
  • DOI: 10.1039/c3dt51433a
  • Peer Reviewed
• [Journal Article] Reversible Dioxygen Binding on Asymmetric Dinuclear Rhodium Centres (2013)
  • Author(s): T. Nakajima, M. Sakamoto, S. Kurai, B. Kure, and T. Tanase
  • Journal Title: Chem. Commun. Volume: ４９ Issue: 46 Pages: 5250-5252
  • DOI: 10.1039/c3cc41815d
  • Peer Reviewed
• [Presentation] 四座ホスフィン配位子を用いたロジウム(I)四核錯体の小分子との反応 (2016)
  • Author(s): 青木里紗、佐藤佳月、大滝理紗、久禮文章、中島隆行、棚瀬知明
  • Organizer: 日本化学会第96回春季年会
  • Place of Presentation: 同志社大学（京田辺）
  • Year and Date: 2016-03-26
• [Presentation] 四座ホスフィンdpmppeを支持配位子としたイリジウム二核錯体の合成と反応性 (2016)
  • Author(s): 大石愛、久禮文章、中島隆行、棚瀬知明
  • Organizer: 日本化学会第96回春季年会
  • Place of Presentation: 同志社大学（京田辺）
  • Year and Date: 2016-03-26
• [Presentation] キラルな四座ホスフィン配位子 rac-dpmppm により支持された直鎖状パラジウム八核錯体の酸化還元挙動 (2016)
  • Author(s): 金子由妃乃、山本佳奈、森田惟美、中前佳那子、久禮文章、中島隆行、棚瀬知明
  • Organizer: 日本化学会第96回春季年会
  • Place of Presentation: 同志社大学（京田辺）
  • Year and Date: 2016-03-26
• [Presentation] 四座ホスフィンに支持された銅(Ⅰ)三核及び四核ヒドリド錯体の合成と反応性 (2016)
  • Author(s): 上領美彩、八軒可奈恵、久禮文章、中島隆行、棚瀬知明
  • Organizer: 日本化学会第96回春季年会
  • Place of Presentation: 同志社大学（京田辺）
  • Year and Date: 2016-03-26
• [Presentation] 六座ホスフィン配位子に支持されたAu(I) 7核錯体の合成と構造 (2016)
  • Author(s): 三木田ゆみな、近西澪、中前佳那子、久禮文章、中島隆行、棚瀬知明
  • Organizer: 日本化学会第96回春季年会
  • Place of Presentation: 同志社大学（京田辺）
  • Year and Date: 2016-03-26
• [Presentation] Activation of Hydrosilanes by Novel Dithilate-Bridged NiIr Dinuclear Complexes Supported by a P2S2 Tetradentate Ligand (2016)
  • Author(s): 久禮文章、渡邉夏妃、佐野三記江、中前佳那子、中島隆行、棚瀬知明
  • Organizer: 日本化学会第96回春季年会
  • Place of Presentation: 同志社大学（京田辺）
  • Year and Date: 2016-03-25
• [Presentation] 四座ホスフィン dpmppp に支持された非対称イリジウム(I)二核中心におけるオルトメタル化反応 (2016)
  • Author(s): 松井彩、坂本美由紀、久禮文章、中島隆行、棚瀬知明
  • Organizer: 日本化学会第96回春季年会
  • Place of Presentation: 同志社大学（京田辺）
  • Year and Date: 2016-03-25
• [Presentation] 分岐型四座ホスフィンに支持されたイソシアニドを末端配位子とする直鎖状白金三核錯体の合成と性質 (2016)
  • Author(s): 小池 香菜子、上垣美帆、中前佳那子、久禮文章、中島隆行、棚瀬知明
  • Organizer: 日本化学会第96回春季年会
  • Place of Presentation: 同志社大学（京田辺）
  • Year and Date: 2016-03-25
• [Presentation] Syntheses and Structures of Copper Hydride Clusters Supported by Multidentate Phosphine Ligands (2016)
  • Author(s): 中前佳那子、上領美彩、久禮文章、中島隆行、棚瀬知明
  • Organizer: 日本化学会第96回春季年会
  • Place of Presentation: 同志社大学（京田辺）
  • Year and Date: 2016-03-24
• [Presentation] ビスイソシアニドで連結した直鎖状パラジウム八核錯体ポリマーの合成と性質 (2016)
  • Author(s): 宮野晴香、中前佳那子、久禮文章、中島隆行、吉村倫一、棚瀬知明
  • Organizer: 日本化学会第96回春季年会
  • Place of Presentation: 同志社大学（京田辺）
  • Year and Date: 2016-03-24
• [Presentation] Redox Properties of Linear Octanuclear Palladium Complexes Supported by Tetraphosphine Ligands (2015)
  • Author(s): 中前佳那子、久禮文章、中島隆行、棚瀬知明
  • Organizer: The 2015 International Chemical Congress of Pacific Basin Societies (Pacifichem)
  • Place of Presentation: Honolulu
  • Year and Date: 2015-12-17
  • Int'l Joint Research
• [Presentation] A Linear Hexanuclear Platinum Trihydride Complex Supported by Triphosphine Ligands (2015)
  • Author(s): 山本佳奈、久禮文章、中島隆行、棚瀬知明
  • Organizer: The 2015 International Chemical Congress of Pacific Basin Societies (Pacifichem)
  • Place of Presentation: Honolulu
  • Year and Date: 2015-12-17
  • Int'l Joint Research
• [Presentation] 四座ホスフィンで支持した銅9 核および銅16 核ヒドリドクラスターの 構造と電子状態 (2015)
  • Author(s): 中前佳那子、久禮文章、中島隆行、棚瀬知明
  • Organizer: 第65回錯体化学討論会
  • Place of Presentation: 奈良女子大学（奈良）
  • Year and Date: 2015-09-22
• [Presentation] 四座ホスフィン配位子dpmppp によって支持された電子不足なロジウム二核中心へのHCl の酸化的付加 (2015)
  • Author(s): 松井彩、坂本美由紀、久禮文章、中島隆行、棚瀬知明
  • Organizer: 第65回錯体化学討論会
  • Place of Presentation: 奈良女子大学（奈良）
  • Year and Date: 2015-09-22
• [Presentation] ハロゲン末端配位子とキラルな四座ホスフィンで支持した 直鎖状パラジウム八核錯体の合成と構造 (2015)
  • Author(s): 山本佳奈、森田惟美、中前佳那子、久禮文章、中島隆行、棚瀬知明
  • Organizer: 第65回錯体化学討論会
  • Place of Presentation: 奈良女子大学（奈良）
  • Year and Date: 2015-09-21
• [Presentation] ビスイソシアニドまたは長鎖アルキルイソシアニドが配位した直鎖状パラジウム八核錯体の合成と性質 (2015)
  • Author(s): 宮野晴香、中前佳那子、久禮文章、中島隆行、棚瀬知明
  • Organizer: 第65回錯体化学討論会
  • Place of Presentation: 奈良女子大学（奈良）
  • Year and Date: 2015-09-21
• [Presentation] キラルな四座ホスフィン配位子 rac-dpmppm により支持された直鎖状パラジウム八核錯体の合成と性質 (2015)
  • Author(s): 森田惟美、大滝理紗、中前佳那子、久禮文章、中島隆行、棚瀬知明
  • Organizer: 日本化学会第95回春季年会
  • Place of Presentation: 船橋
  • Year and Date: 2015-03-28
• [Presentation] 四座ホスフィン配位子によって支持された電子不足なロジウム二核中心への HCl の酸化的付加 (2015)
  • Author(s): 松井彩、坂本美由紀、久禮文章、中島隆行、棚瀬知明
  • Organizer: 日本化学会第95回春季年会
  • Place of Presentation: 船橋
  • Year and Date: 2015-03-28
• [Presentation] 長鎖アルキル基を有するイソシアニドが軸配位した直鎖状パラジウム八核錯体の合成と性質 (2015)
  • Author(s): 宮野晴香、中前佳那子、山本知依、久禮文章、中島隆行、棚瀬知明
  • Organizer: 日本化学会第95回春季年会
  • Place of Presentation: 船橋
  • Year and Date: 2015-03-28
• [Presentation] イソシアニドを軸配位子とする直鎖状パラジウム四核錯体の合成と性質 (2015)
  • Author(s): 中前佳那子、久禮文章、中島隆行、棚瀬知明
  • Organizer: 日本化学会第95回春季年会
  • Place of Presentation: 船橋
  • Year and Date: 2015-03-27
• [Presentation] 四座ホスフィンを用いた多核銅(I)ヒドリド錯体の合成と反応性 (2015)
  • Author(s): 八軒可奈恵、牧野純子、久禮文章、中島隆行、棚瀬知明
  • Organizer: 日本化学会第95回春季年会
  • Place of Presentation: 船橋
  • Year and Date: 2015-03-27
• [Presentation] P2S2型四座配位子を有するNiIIRhIおよびNiIIIrI二核錯体の合成と構造及び反応性 (2015)
  • Author(s): 渡邉夏妃、佐野三記江、久禮文章、中島隆行、棚瀬知明
  • Organizer: 日本化学会第95回春季年会
  • Place of Presentation: 船橋
  • Year and Date: 2015-03-27
• [Presentation] 分岐型四座ホスフィンで支持された直鎖状白金三核錯体の合成 (2015)
  • Author(s): 上垣美帆、畠田聡子、久禮文章、中島隆行、棚瀬知明
  • Organizer: 日本化学会第95回春季年会
  • Place of Presentation: 船橋
  • Year and Date: 2015-03-26
• [Presentation] 四座ホスフィンで支持した直鎖状パラジウム八核錯体の酸化還元挙動 (2014)
  • Author(s): 中前佳那子、久禮文章、中島隆行、棚瀬知明
  • Organizer: 第64回錯体化学討論会
  • Place of Presentation: 東京
  • Year and Date: 2014-09-18
• [Presentation] 多座ホスフィン配位子に支持された同種および異種金属Ag多核錯体の合成と構造・性質 (2014)
  • Author(s): 近西澪、大滝理紗、久禮文章、中島隆行、棚瀬知明
  • Organizer: 第64回錯体化学討論会
  • Place of Presentation: 東京
  • Year and Date: 2014-09-18
• [Presentation] ビスカルボキシラト架橋マンガン二核錯体の合成と糖リン酸エステルとの反応 (2014)
  • Author(s): 中井絢子、久禮文章、中島隆行、棚瀬知明
  • Organizer: 第64回錯体化学討論会
  • Place of Presentation: 東京
  • Year and Date: 2014-09-18
• [Presentation] 三座ホスフィンで支持された直鎖白金多核錯体の集積 (2014)
  • Author(s): 山本佳奈、久禮文章、中島隆行、棚瀬知明
  • Organizer: 第64回錯体化学討論会
  • Place of Presentation: 東京
  • Year and Date: 2014-09-18
• [Presentation] Cage-Type Copper Hydride Clusters Supported By Tetraphosphine Ligands (2014)
  • Author(s): 中前佳那子、久禮文章、中島隆行、棚瀬知明
  • Organizer: The 41st International Conference on Coordination Chemistry (ICCC41)
  • Place of Presentation: シンガポール
  • Year and Date: 2014-07-22
• [Presentation] Wheel-Shaped Icosanuclear Homo- and Heterometallic Complexes of NiII, CoII, and CuII Ions Supported by Unsymmetrical Aminoalcohol Ligands (2014)
  • Author(s): T. NAKAJIMA, K. SETO, F. HOSOKAWA, I. SHIMIZU, A. SCHEURER, B. KURE, T. KAJIWARA, T. TANASE , M. MIKURIYA
  • Organizer: The 41st International Conference on Coordination Chemistry (ICCC41)
  • Place of Presentation: シンガポール
  • Year and Date: 2014-07-21
• [Presentation] Heterodinuclear Complexes with MM’(μ-meppp) Cores (M = Ni, Pd, Pt; M’ = Rh, Ir) That Tune the Properties of a Nesting Hydride (2014)
  • Author(s): 久禮文章、佐野三記江、中島隆行、棚瀬知明
  • Organizer: the XXVI International Conference on Organometallic Chemistry (ICOMC 2014)
  • Place of Presentation: 札幌
  • Year and Date: 2014-07-17
• [Presentation] Reduction of Carbon Dioxide with Copper Hydride Complexes Supported by Tetraphosphine (2014)
  • Author(s): 中前佳那子、久禮文章、中島隆行、浦康之、棚瀬知明
  • Organizer: the XXVI International Conference on Organometallic Chemistry (ICOMC 2014)
  • Place of Presentation: 札幌
  • Year and Date: 2014-07-15
• [Presentation] Reversible Dioxygen Binding on Asymmetric Dinuclear Rhodium Centers (2014)
  • Author(s): 中島隆行、坂本美由紀、野田紗世、久禮文章、棚瀬知明
  • Organizer: the XXVI International Conference on Organometallic Chemistry (ICOMC 2014)
  • Place of Presentation: 札幌
  • Year and Date: 2014-07-14
• [Presentation] Reversible Dioxygen Binding on Asymmetric Dinuclear Rhodium Centers
  • Author(s): T. Nakajima, M. Sakamoto, S. Noda, B. Kure, T. Tanase
  • Organizer: Internationai Symposium on Catalysis and Fine Chemicals 2013
  • Place of Presentation: 北京
• [Presentation] Reversible Dioxygen Binding on Asymmetric Dinuclear Rhodium Centers Supported by a Tetraphosphine Ligand dpmppp
  • Author(s): M. Sakamoto, S. Noda, B. Kure, T. Nakajima, T. Tanase
  • Organizer: The 2nd Japan-France Coordination Chemistry Symposium 2013
  • Place of Presentation: 奈良
• [Presentation] Reactions of Dinuclear Rhodium Complexes Supported by a Tetraphosphine Ligand with HCl
  • Author(s): 坂本美由紀, 久禮文章, 中島隆行, 棚瀬知明
  • Organizer: 日本化学会第94春季年会
  • Place of Presentation: 名古屋
• [Presentation] Synthesis and Structures of Dinuclear Iridium Complexes Supported by a Tetraphosphine Ligand Dpmppp.
  • Author(s): 坂本美由紀, 野田紗世, 久禮文章, 中島隆行, 棚瀬知明
  • Organizer: 第63回錯体化学討論会
  • Place of Presentation: 那覇