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Surface Structure of Porous Coordination Polymer Thin film

Research Project

Project/Area Number 25410074
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Inorganic chemistry
Research InstitutionInternational Christian University

Principal Investigator

CHUN Wang Jae  国際基督教大学, 教養学部, 教授 (40344501)

Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2015: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2014: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2013: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Keywords配位高分子薄膜 / 単結晶酸化物表面 / X線吸収微細構造 / 表面X線吸収微細構造 / 修飾金単結晶表面 / 表面科学
Outline of Final Research Achievements

The governing factors in orientation controlled surface metal organic frameworks (SURMOFs) on solid substrates (e.g. metal oxides and metals) have explored with synchrotron radiation X-ray absorption fine structure and various surface scientific techniques (XPS, Surface XRD, SEM etc.). The project 1) established a facile characterization technique for ultra thin SURMOFs, and 2) unraveled that the surface structure of substrates and adsorption structure of ligands have an important role in the orientation of SURMOFs.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (23 results)

All 2016 2015 2014 2013 Other

All Journal Article (6 results) (of which Peer Reviewed: 6 results,  Open Access: 1 results,  Acknowledgement Compliant: 2 results) Presentation (16 results) Remarks (1 results)

  • [Journal Article] Co-immobilization of a palladium-bisphosphine complex and strong organic base on a silica surface for heterogeneous synergistic catalysis2016

    • Author(s)
      K. Motokura, K. Saitoh, H. Noda, Y. Uemura, W.-J. Chun, A. Miyaji, S. Yamaguchi, T. Baba
    • Journal Title

      ChemCatChem

      Volume: 8 Issue: 2 Pages: 331-335

    • DOI

      10.1002/cctc.201501178

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Finding the Most Catalytically Active Platinum Clusters With Low Atomicity2015

    • Author(s)
      Takane Imaoka, Hirokazu Kitazawa, Wang-Jae Chun, Kimihisa Yamamoto
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 54 Issue: 34 Pages: 9810-9815

    • DOI

      10.1002/anie.201504473

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Heterogeneous double-activation catalysis: Rh complex and tertiary amine on the same solid surface for the 1,4-addition reaction of aryl- and alkylboronic acids2015

    • Author(s)
      H. Noda, K. Motokura, W.-J. Chun, A. Miyaji, S. Yamaguchi, T. Baba
    • Journal Title

      Catalysis Science and Technology

      Volume: 5 Issue: 5 Pages: 2714-2727

    • DOI

      10.1039/c5cy00133a

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Fine tuning and orientation control of surface Cu complexes on TiO2(110) premodified with mercapto compounds: the effect of different mercapto group positions2013

    • Author(s)
      Satoru Takakusagi, Hirotaka Nojima, Hiroko Ariga, Hiromitsu Uehara, Kotaro Miyazaki, Wang-Jae Chun, Yasuhiro Iwasawa, Kiyotaka Asakura
    • Journal Title

      Physical Chemistry Chemical Physics

      Volume: 15 Issue: 33 Pages: 14080-14088

    • DOI

      10.1039/c3cp51425k

    • NAID

      120005451566

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Anisotropic growth of a nickel trimer formed on a highly-stepped TiO2(110) surface2013

    • Author(s)
      Hiromitsu Uehara, Muhammad Haneef Bin Hanaffi, Yuichiro Koike, Keisuke Fujikawa, Shushi Suzuki, Hiroko Ariga, Satoru Takakusagi, Wang-Jae Chun, Yasuhiro Iwasawa, Kiyotaka Asakura
    • Journal Title

      Chemical Physics Letters

      Volume: 570 Pages: 64-69

    • DOI

      10.1016/j.cplett.2013.02.053

    • NAID

      120005307929

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] ine tuning and orientation control of surface Cu complexes on TiO2(110) premodified with mercapto compounds: the effect of different mercapto group positions2013

    • Author(s)
      Takakusagi, Satoru; Nojima, Hirotaka; Ariga, Hiroko; Uehara, Hiromitsu; Miyazaki, Kotaro; Chun, Wang-Jae; Iwasawa, Yasuhiro; Asakura, Kiyotaka
    • Journal Title

      Physical Chemistry Chemical Physics

      Volume: 15 Pages: 14080-14088

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] 三次元Cu-MOF2層の金基板上への逐次構築2016

    • Author(s)
      長谷真理子、田旺帝、近藤敏啓
    • Organizer
      日本化学会 第96春季年会
    • Place of Presentation
      同志社大学、京都府京都市
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] The Structure of Cu and Fe-Metal Organic Framework (MOF) thin film on TiO2(110) surface2016

    • Author(s)
      田旺帝, 橋本深雪, 近藤敏啓
    • Organizer
      第33回PFシンポジウム
    • Place of Presentation
      つくば国際会議場、茨城県つくば市
    • Year and Date
      2016-03-15
    • Related Report
      2015 Annual Research Report
  • [Presentation] TiO2(110)表面におけるCu及び Fe系多孔性配位高分子薄膜の構造解明2015

    • Author(s)
      田旺帝, 橋本深雪, 近藤敏啓
    • Organizer
      第35回表面科学学術講演会
    • Place of Presentation
      つくば国際会議場、茨城県つくば市
    • Year and Date
      2015-12-01
    • Related Report
      2015 Annual Research Report
  • [Presentation] 同一表面に固定化したRh錯体と3級アミンによるアリール及びアルキルホウ酸 のシクロヘキセノンへの 1,4-付加反応2015

    • Author(s)
      野田 寛人・本倉 健・田 旺帝・宮地 輝光・山口 渉・馬場 俊秀
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      船橋、千葉
    • Year and Date
      2015-03-27 – 2015-03-30
    • Related Report
      2014 Research-status Report
  • [Presentation] TiO2(110)表面における多孔性配位高分子の薄膜構造2015

    • Author(s)
      橋本深雪,岡嶋賢,原賢二,近藤敏啓,田旺帝
    • Organizer
      第32回PFシンポジウム
    • Place of Presentation
      つくば
    • Year and Date
      2015-03-17 – 2015-03-18
    • Related Report
      2014 Research-status Report
  • [Presentation] Au(111)電極表面上に形成されたPd UPD層の偏光全反射蛍光XAFS構造解析2015

    • Author(s)
      増田卓也,上原広充,高草木達,田旺帝,近藤敏啓,朝倉清高,魚崎浩平
    • Organizer
      電気化学会第82回大会
    • Place of Presentation
      横浜国立大学
    • Year and Date
      2015-03-15 – 2015-03-17
    • Related Report
      2014 Research-status Report
  • [Presentation] TiO2(110)表面への多孔性配位高分子薄膜構築とその構造解析2014

    • Author(s)
      橋本深雪,岡嶋賢,原賢二,近藤敏啓,田旺帝
    • Organizer
      第34回表面科学学術講演会
    • Place of Presentation
      島根県・松江市
    • Year and Date
      2014-11-06 – 2014-11-08
    • Related Report
      2014 Research-status Report
  • [Presentation] 非魔法数金属クラスターの精密合成と触媒活性評価2014

    • Author(s)
      今岡 享稔, 北澤 啓和, 田 旺帝, 山元 公寿
    • Organizer
      第8回分子科学討論会
    • Place of Presentation
      広島大学東広島キャンパス 6. 招待講演 なし
    • Year and Date
      2014-09-24
    • Related Report
      2014 Research-status Report
  • [Presentation] 原子数制御によるサブナノ白金クラスターの特異的高活性化2014

    • Author(s)
      今岡 享稔, 北澤 啓和, 田 旺帝, 山元 公寿
    • Organizer
      錯体化学会第64回討論会
    • Place of Presentation
      中央大学 後楽園キャンパス
    • Year and Date
      2014-09-19
    • Related Report
      2014 Research-status Report
  • [Presentation] One-atom Controlled Synthesis of Subnano Pt Clusters for Fuel Cell2014

    • Author(s)
      Hirokazu Kitazawa,Takane Imaoka,Wang Jae Chun,Kimihisa Yamamoto
    • Organizer
      65th Annual Meeting of the International Society of Electrochemistry EPFL
    • Place of Presentation
      Lausanne, Switzerland
    • Year and Date
      2014-09-01
    • Related Report
      2014 Research-status Report
  • [Presentation] Structural Studies on Metal-Organic Frameworks Thin Films on TiO2(110)2014

    • Author(s)
      M. Hashimoto, S. Okajima, K. Hara, W.-J. Chun, and T. Kondo
    • Organizer
      248th ACS National Meeting
    • Place of Presentation
      San Francisco (U.S.A.)
    • Year and Date
      2014-08-10 – 2014-08-14
    • Related Report
      2014 Research-status Report
  • [Presentation] Immobilization of Cu and Ru complexes to organic ligand in periodic mesoporous organosilicas2014

    • Author(s)
      Nobuhiro Ishito, Kenji Hara, Wang Jae Chun, Yoshifumi Maegawa, Shinji Inagaki, Atsushi Fukuoka
    • Organizer
      TOCAT7
    • Place of Presentation
      Kyoto
    • Year and Date
      2014-06-01 – 2014-06-06
    • Related Report
      2014 Research-status Report
  • [Presentation] Ultra-thin [Cu3(BTC)2]n Film on TiO2 (110) Probed by Polarization-Dependent Total Reflection Fluorescence XAFS2014

    • Author(s)
      Satoshi Okajima, Miyuki Hashimoto, Kenji Hara, Toshihiro Kondo, Wang Jae Chun
    • Organizer
      International Symposium on Coordination Programming (ISCP2014)
    • Place of Presentation
      東京大学伊藤国外学術研究センター
    • Related Report
      2013 Research-status Report
  • [Presentation] 偏光全反射蛍光XAFSによるTiO2(110)表面上のHKUST-1超薄膜の構造解析2014

    • Author(s)
      岡嶋 賢, 橋本深雪, 芦間英典, 近藤敏啓, 原 賢二, 田 旺帝
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学東山キャンパス
    • Related Report
      2013 Research-status Report
  • [Presentation] Photoelectrochemical CO2 Reduction Reaction at Si(111) Electrodes Modified by Molecular Layers with Viologen Moiety and Various Metal Complexes2013

    • Author(s)
      Masuda, Y. Sun, H. Fukumitsu, H. Uehara, S. Takakusagi, W.-J. Chun, T. Kondo, K. Asakura, and K. Uosaki
    • Organizer
      The 64th Annual Meeting of the International Society of Electrochemistry
    • Place of Presentation
      Santiago de Qeretaro, Mexico
    • Related Report
      2013 Research-status Report
  • [Presentation] TiO2(110)表面における多孔性配位高分子[Cu3(BTC)2(H2O)3]n薄膜の構造解析2013

    • Author(s)
      岡嶋 賢, 橋本深雪, 近藤敏啓, 原 賢二, 田 旺帝
    • Organizer
      第33回表面科学学術講演会
    • Place of Presentation
      つくば国際会議場
    • Related Report
      2013 Research-status Report
  • [Remarks] RESEARCHERID supported by Thomson Reuters

    • URL

      http://www.researcherid.com/rid/K-2094-2012

    • Related Report
      2015 Annual Research Report

URL: 

Published: 2014-07-25   Modified: 2019-07-29  

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