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Development of low-power consumption memory transistors with ferroelectric coordination polymers

Research Project

Project/Area Number 25410077
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Inorganic chemistry
Research InstitutionKinki University

Principal Investigator

OKUBO Takashi  近畿大学, 理工学部, 准教授 (90322677)

Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2015: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2014: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2013: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywords配位高分子 / 強誘電性 / トランジスタ / 薄膜化
Outline of Final Research Achievements

Organic field-effect transistors (OFETs) have attracted a considerable amount of interest as new environmentally thoughtful low-power consumption devices because they can be fabricated with low cost by the application of printed technologies such as inkjet printing on flexible substrates. In this research, we have attempted to create new ferroelectric coordination polymers in order to develop new memory FET devices working with low voltage. In this result, we successfully synthesized several new ferroelectric coordination polymers, and the dielectric and conducting properties have been revealed. In addition we found new fabrication methods for the coordination polymer thin films via solution processes, and they were applied to develop new FETs with ferroelectric coordination polymers.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (46 results)

All 2016 2015 2014 2013

All Journal Article (3 results) (of which Peer Reviewed: 3 results,  Open Access: 1 results,  Acknowledgement Compliant: 1 results) Presentation (40 results) (of which Int'l Joint Research: 5 results,  Invited: 3 results) Patent(Industrial Property Rights) (3 results)

  • [Journal Article] Synthesis, Crystal Structure, and Electroconducting Properties of a 1D Mixed-Valence Cu(I)–Cu(II) Coordination Polymer with a Dicyclohexyl Dithiocarbamate Ligand2015

    • Author(s)
      Kenji Nakatani, Kento Himoto, Yuki Kono, Yuuki Nakahashi, Haruho Anma, Takashi Okubo, Masahiko Maekawa and Takayoshi Kuroda-Sowa
    • Journal Title

      Crystals

      Volume: 5 Issue: 2 Pages: 215-225

    • DOI

      10.3390/cryst5020215

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] New one-dimensional mixed-valence coordination polymers including an iodine-bridged pentanuclear copper(I) cluster unit2014

    • Author(s)
      Takashi Okubo, Haruho Anma, Yuuki Nakahashi, Masahiko Maekawa, Takayoshi Kuroda-Sowa
    • Journal Title

      Polyhedron

      Volume: 69 Pages: 103-109

    • DOI

      10.1016/j.poly.2013.11.026

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] The first copper(I) coordination polymers self-assembled by 4,4'-biquinazoline2014

    • Author(s)
      M. Maekawa, A. Minamino, K. Sugimoto, T. Okubo, T. Kuroda-Sowa and M. Munakata
    • Journal Title

      Inorg. Chim. Acta.

      Volume: 414 Pages: 257-263

    • DOI

      10.1016/j.ica.2014.02.016

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] アルキルチオ基を導入したHATNA誘導体を用いた配位高分子の合成と物性評価2016

    • Author(s)
      武田和樹、中谷研二、大久保貴志、前川雅彦、黒田孝義
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] ハロゲン化銅とHATNA-Me6からなるd-π複合体を用いた太陽電池の作製2016

    • Author(s)
      堀井俊也、大久保貴志、前川雅彦、黒田孝義
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] チオシアン酸銅をバッファ層としたペロブスカイト太陽電池の作製と評価2016

    • Author(s)
      向井康智、大久保貴志、前川雅彦、黒田孝義
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] ハロゲン化銅とHAT-CN6からなるd-π複合体を用いた薄膜太陽電池の高効率化2016

    • Author(s)
      中村加奈、樋元健人、大久保貴志、前川雅彦、黒田孝義
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] ハロゲン化銅とtetrazineからなる新規配位高分子の合成と物性評価2016

    • Author(s)
      谷嶋晃樹、大久保貴志、前川雅彦、黒田孝義
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] HAT誘導体とハロゲン化銅からなるd-π複合体薄膜の成膜法の検討と薄膜太陽電池への応用2016

    • Author(s)
      樋元健人、中村加奈、大久保貴志、前川雅彦、黒田孝義
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] Crystal structures and carrier transport properties of mixed-valence coordination polymers with dithiocarbamate derivatives2015

    • Author(s)
      Takashi Okubo, Koki Tanishima, Yuki Kono, Kento Himoto, Kenji Nakatani, Masahiko Maekawa, Takayoshi Kuroda-Sowa
    • Organizer
      The International Chemical Congress of Pacific Basin Societies 2015 (Pacifichem 2015)
    • Place of Presentation
      Hawai (USA)
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis and carrier transport properties of semiconducting materials consisting of HAT derivatives and copper halides2015

    • Author(s)
      Kento Himoto, Takashi Okubo, Masahiko Maekawa, Takayoshi Kuroda-Sowa
    • Organizer
      The International Chemical Congress of Pacific Basin Societies 2015 (Pacifichem 2015)
    • Place of Presentation
      Hawai (USA)
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Development of thin film solar cells of d-π complexes using HATNA-Cl62015

    • Author(s)
      Yuki Kono, Kento Himoto, Kenji Nakatani, Koki Tanishima, Takashi Okubo, Masahiko Maekawa, Takayoshi Kuroda-Sowa
    • Organizer
      The International Chemical Congress of Pacific Basin Societies 2015 (Pacifichem 2015)
    • Place of Presentation
      Hawai (USA)
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis of nanoparticles of a copper coordination polymer with octamethylene ditiocarbamate and application to organic photovoltaics2015

    • Author(s)
      Kenji Nakatani, Takashi Okubo, Masahiko Maekawa, Takayoshi Kuroda-Sowa
    • Organizer
      The International Chemical Congress of Pacific Basin Societies 2015 (Pacifichem 2015)
    • Place of Presentation
      Hawai (USA)
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Crystal structures and conducting properties of 3D coordination polymers with dithiocarbamate derivatives2015

    • Author(s)
      Koki Tanishima, Takashi Okubo, Masahiko Maekawa, Takayoshi Kuroda-Sowa
    • Organizer
      The International Chemical Congress of Pacific Basin Societies 2015 (Pacifichem 2015)
    • Place of Presentation
      Hawai (USA)
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ベンゼンジチオカルボン酸誘導体を配位子としたニッケル錯体の合成および物性評価2015

    • Author(s)
      谷嶋晃樹・河野由樹・樋元健人・中谷研二・大久保貴志・前川雅彦・黒田孝義
    • Organizer
      錯体化学会第65回討論会
    • Place of Presentation
      奈良女子大学
    • Year and Date
      2015-09-21
    • Related Report
      2015 Annual Research Report
  • [Presentation] HATNA誘導体を配位子とするd-π複合体の開発と薄膜太陽電池への応用2015

    • Author(s)
      河野 由樹, 谷嶋 晃樹, 樋元 健人, 中谷 研二,大久保 貴志, 前川 雅彦, 黒田 孝義
    • Organizer
      第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋国際会議場
    • Year and Date
      2015-09-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] HAT誘導体とハロゲン化銅からなる半導体材料のキャリア輸送特性評価及び太陽電池への応用2015

    • Author(s)
      樋元健人, 河野由樹, 大久保貴志, 前川雅彦, 黒田孝義
    • Organizer
      第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋国際会議場
    • Year and Date
      2015-09-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] HATNA誘導体を含む配位高分子を光電変換層とした有機無機複合型太陽電池の開発2015

    • Author(s)
      中谷研二, 武田和樹, 大久保貴志, 前川雅彦, 黒田孝義
    • Organizer
      第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋国際会議場
    • Year and Date
      2015-09-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] ジチオカルバミン酸誘導体を配位子とした三次元配位高分子の構造と伝導性2015

    • Author(s)
      大久保貴志・中橋裕 貴・樋元健人・河野由樹・中谷研二・前川雅彦・黒田孝義
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日本大学船橋キャンパス(千葉)
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Research-status Report
  • [Presentation] HAT 誘導体とハロゲン化銅からなる半導体材料の開発及び キャリア輸送特性評価2015

    • Author(s)
      ○樋元健 人・河野由樹・中谷研二・大久保貴志・前川雅彦・黒田孝義
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日本大学船橋キャンパス(千葉)
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Research-status Report
  • [Presentation] ドナー・アクセプター部位を有するチオフェン誘導体の合成2015

    • Author(s)
      松本浩一・山田佑樹・柏村成史・大久保貴志・山口仁 宏
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日本大学船橋キャンパス(千葉)
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Research-status Report
  • [Presentation] 三座Schiff 塩基配位子を用いた鉄(III)錯体における構造とSCO 特性2015

    • Author(s)
      山尾典史・大久保貴志・前川雅彦・黒田孝 義
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日本大学船橋キャンパス(千葉)
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Research-status Report
  • [Presentation] ジチオカルボン酸ニッケル錯体を用いた配位高分子の合成とキャリア輸送特性2015

    • Author(s)
      谷嶋晃樹・中橋裕 貴・大地悠輔・河野由樹・大久保貴志・前川雅彦・黒田孝義
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日本大学船橋キャンパス(千葉)
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Research-status Report
  • [Presentation] オクタメチレンジチオカルバミン酸銅配位高分子微粒子の合 成と有機薄膜太陽電池への応用2015

    • Author(s)
      中谷研二・大久保貴志・前川雅彦・黒田孝義
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日本大学船橋キャンパス(千葉)
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Research-status Report
  • [Presentation] HATNA 誘導体を配位子とするd-π複合体を用いた薄膜太陽電池の開発2015

    • Author(s)
      河野由樹・藤野宏樹・坂 田稜磨・樋元健人・中谷研二・大久保貴志・前川雅彦・黒田孝義
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日本大学船橋キャンパス(千葉)
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Research-status Report
  • [Presentation] Photovoltaic Properties of Bulk Heterojunction Solar Cells Including Metal-Organic Frameworks2014

    • Author(s)
      Kenji Nakatani, Takashi Okubo, Masahiko Maekawa, Takayoshi Kuroda-Sowa
    • Organizer
      4th International Conference on Metal-Organic Frameworks and Open Framework Compounds (MOF2014)
    • Place of Presentation
      Kobe International Conference Center (Kobe)
    • Year and Date
      2014-09-28 – 2014-10-01
    • Related Report
      2014 Research-status Report
  • [Presentation] Structural Controls of Cu(I)-C2H4 Coordination Polymers with 4,4’-Bipyrimidine Directed by Anions and Solvents2014

    • Author(s)
      Masahiko Maekawa, Kunihisa Sugimoto, Takashi Okubo, Takayoshi Kuroda-Sowa, Megumu Munakata, Susumu Kitagawa
    • Organizer
      4th International Conference on Metal-Organic Frameworks and Open Framework Compounds (MOF2014)
    • Place of Presentation
      Kobe International Conference Center (Kobe)
    • Year and Date
      2014-09-28 – 2014-10-01
    • Related Report
      2014 Research-status Report
  • [Presentation] Crystal Structures and Charge-Carrier Transport Properties of Metal-Organic Frameworks with Dithiocarbamate Derivatives2014

    • Author(s)
      Takashi Okubo, Yuuki Nakahashi, Kento Himoto, Kenji Nakatani, Masahiko Maekawa, Takayoshi Kuroda-Sowa
    • Organizer
      4th International Conference on Metal-Organic Frameworks and Open Framework Compounds (MOF2014)
    • Place of Presentation
      Kobe International Conference Center (Kobe)
    • Year and Date
      2014-09-28 – 2014-10-01
    • Related Report
      2014 Research-status Report
  • [Presentation] ベンゼンジチオカルボン酸誘導体を配位子とした新規ニッケル錯体の合成および物性評価2014

    • Author(s)
      谷嶋晃樹・中橋裕貴・樋元健人・中谷研二・太地悠輔・西峯准・末永勇作・大久保貴志
    • Organizer
      錯体化学会第64回討論会
    • Place of Presentation
      中央大学後楽園キャンパス(東京)
    • Year and Date
      2014-09-18 – 2014-09-20
    • Related Report
      2014 Research-status Report
  • [Presentation] ジチオカルバミン酸銅錯体を用いた三次元配位高分子の結晶構造とキャリア輸送特性2014

    • Author(s)
      中橋裕貴・樋元健人・大久保貴志・前川雅彦・黒田孝義
    • Organizer
      錯体化学会第64回討論会
    • Place of Presentation
      中央大学後楽園キャンパス(東京)
    • Year and Date
      2014-09-18 – 2014-09-20
    • Related Report
      2014 Research-status Report
  • [Presentation] 3 次元構造を有するジチオカルバミン酸配位高分子薄膜のキャリア輸送特性 評価2014

    • Author(s)
      樋元健人,中橋裕貴,大久保貴志,前川雅彦,黒田孝義
    • Organizer
      第75回応用物理学会秋季学術講演会
    • Place of Presentation
      北海道大学(北海道)
    • Year and Date
      2014-09-17 – 2014-09-20
    • Related Report
      2014 Research-status Report
  • [Presentation] オクタメチレンジチオカルバミン酸銅配位高分子を増感色素に用いた色素増感型バルクへテロ接合型太陽電池の素子評価2014

    • Author(s)
      中谷研二,大久保貴志,前川雅彦,黒田孝義
    • Organizer
      第75回応用物理学会秋季学術講演会
    • Place of Presentation
      北海道大学(北海道)
    • Year and Date
      2014-09-17 – 2014-09-20
    • Related Report
      2014 Research-status Report
  • [Presentation] 強誘電性ジチオカルバミン酸配位高分子を用いた有機薄膜太陽電池の開発2014

    • Author(s)
      河野由樹,大久保貴志,前川雅彦,黒田孝義
    • Organizer
      第75回応用物理学会秋季学術講演会
    • Place of Presentation
      北海道大学(北海道)
    • Year and Date
      2014-09-17 – 2014-09-20
    • Related Report
      2014 Research-status Report
  • [Presentation] Development of Semiconducting Coordination Polymers for Thin-Film Solar Cells2014

    • Author(s)
      Takashi Okubo, Nakatani Kenji, Himoto Kento, Maekawa Masahiko, Kuroda-Sowa Takayoshi
    • Organizer
      The 41st International Conference on Coordination Chemistry (ICCC41)
    • Place of Presentation
      Suntec International Convention & Exhibition Centre (Singapore)
    • Year and Date
      2014-07-21 – 2014-07-25
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] Structures and Magnetic Properties of Novel M(II) Triangular Tri-Nuclear Complexes with an S-Shaped Hexadentate Ligand Derived From Phenazine2014

    • Author(s)
      Takayoshi Kuroda-Sowa, Ryotaro Yamaguchi, Kunihisa Sugimoto, Takashi Okubo, Masahiko Maekawa
    • Organizer
      The 41st International Conference on Coordination Chemistry (ICCC41)
    • Place of Presentation
      Suntec International Convention & Exhibition Centre (Singapore)
    • Year and Date
      2014-07-21 – 2014-07-25
    • Related Report
      2014 Research-status Report
  • [Presentation] New Mixed-Valence Coordination Polymers with Dithiocarbamate Ligands: Crystal Structure, Magnetic and Conductive Properties, and Application in Solar Cells2014

    • Author(s)
      Takashi Okubo, Shimpei Suzuki, Hideyuki Tanaka, Kenji Nakatani, Kyung Ho Kim, Masahiko Maekawa and Takayoshi Kuroda-Sowa
    • Organizer
      The 41st International Conference on Coordination Chemistry (ICCC41)
    • Place of Presentation
      Suntec International Convention & Exhibition Centre (Singapore)
    • Year and Date
      2014-07-21 – 2014-07-25
    • Related Report
      2014 Research-status Report
  • [Presentation] Photovoltaic Properties of Bulk Heterojunction Solar Cells Including Coordination Polymers2014

    • Author(s)
      Kenji Nakatani, Takashi Okubo, Masahiko Maekawa, Takayoshi Kuroda-Sowa
    • Organizer
      The 41st International Conference on Coordination Chemistry (ICCC41)
    • Place of Presentation
      Suntec International Convention & Exhibition Centre (Singapore)
    • Year and Date
      2014-07-21 – 2014-07-25
    • Related Report
      2014 Research-status Report
  • [Presentation] Structurally Diverse Copper(I) Ethylene Adducts with Related 3,6-BIS(2-PYRIDYL)-1,2,4,5-Tetrazine Ligands2014

    • Author(s)
      Masahiko Maekawa, Kunihisa Sugimoto, Takashi Okubo, Takayoshi Kuroda-Sowa, Megumu Munakata, Susumu Kitagawa
    • Organizer
      The 41st International Conference on Coordination Chemistry (ICCC41)
    • Place of Presentation
      Suntec International Convention & Exhibition Centre (Singapore)
    • Year and Date
      2014-07-21 – 2014-07-25
    • Related Report
      2014 Research-status Report
  • [Presentation] 配位高分子の構造・キャリア制御と薄膜太陽電池への展開2014

    • Author(s)
      大久保貴志
    • Organizer
      分子研研究会「金属クラスター錯体・高分子状金属錯体を舞台とした構造・機能化学の最前線」
    • Place of Presentation
      分子科学研究所(京都府京田辺市)
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] ハロゲン化銅 (I) ラダー骨格を含む配位高分子の構造、キャリア輸送特性および太陽電池への展開2013

    • Author(s)
      大久保貴志、中谷研二、金 敬鎬 、前川雅彦、黒田孝義
    • Organizer
      第74回応用物理学会秋季学術講演会
    • Place of Presentation
      同志社大学京田辺キャンパス(京都府京田辺市)
    • Related Report
      2013 Research-status Report
  • [Presentation] 配位高分子の構造・キャリア制御と薄膜太陽電池への展開2013

    • Author(s)
      大久保貴志
    • Organizer
      第19回錯体化学若手の会 中部・東海地区勉強会
    • Place of Presentation
      分子科学研究所(愛知県東岡崎市)
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] ジチオカルバミン酸配位高分子を添加したバルクへテロ接合型太陽電池の作製と素子評価2013

    • Author(s)
      中谷研二・柳へい秀・田川康祐・大久保貴志・前川雅彦・黒田孝義
    • Organizer
      錯体化学会第63回討論会
    • Place of Presentation
      琉球大学千原キャンパス(沖縄県中頭郡)
    • Related Report
      2013 Research-status Report
  • [Presentation] 強誘電性配位高分子の微粒子化および成膜法の探索2013

    • Author(s)
      大久保貴志・樋元健人・河野由樹・田中秀征・前川雅彦・黒田孝義
    • Organizer
      錯体化学会第63回討論会
    • Place of Presentation
      琉球大学千原キャンパス(沖縄県中頭郡)
    • Related Report
      2013 Research-status Report
  • [Patent(Industrial Property Rights)] 半導体材料2015

    • Inventor(s)
      大久保貴志、樋元健人、河野由樹、中谷研二、前川雅彦、黒田孝義
    • Industrial Property Rights Holder
      大久保貴志、樋元健人、河野由樹、中谷研二、前川雅彦、黒田孝義
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2015-030098
    • Filing Date
      2015-02-18
    • Related Report
      2014 Research-status Report
  • [Patent(Industrial Property Rights)] 配位高分子薄膜およびそれを備えた薄膜太陽電池の製造方法2013

    • Inventor(s)
      大久保貴志、樋元健人、前川雅彦、黒田孝義
    • Industrial Property Rights Holder
      大久保貴志、樋元健人、前川雅彦、黒田孝義
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2013-213073
    • Filing Date
      2013-10-10
    • Related Report
      2013 Research-status Report
  • [Patent(Industrial Property Rights)] 配位高分子微粒子および配位高分子薄膜の製造方法2013

    • Inventor(s)
      大久保貴志、樋元健人、前川雅彦、黒田孝義
    • Industrial Property Rights Holder
      大久保貴志、樋元健人、前川雅彦、黒田孝義
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2013-213072
    • Filing Date
      2013-10-10
    • Related Report
      2013 Research-status Report

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Published: 2014-07-25   Modified: 2019-07-29  

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