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Manipulation of the charge carrier dynamics at organic-molecule/metal-oxide interfaces by molecular dipole moment

Research Project

Project/Area Number 25410085
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Functional solid state chemistry
Research InstitutionTokyo Institute of Technology

Principal Investigator

Ozawa Kenichi  東京工業大学, 理工学研究科, 助教 (00282822)

Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2015: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2014: ¥260,000 (Direct Cost: ¥200,000、Indirect Cost: ¥60,000)
Fiscal Year 2013: ¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Keywords有機-酸化物接合界面 / エネルギー準位接続 / 双極子モーメント / キャリアダイナミクス / 光電子分光 / X線吸収分光 / core-hole clock分光 / 有機太陽電池 / 電荷移動 / バンドベンディング / 表面電気伝導度 / 四端子電気伝導測定 / 4端子電気伝導測定
Outline of Final Research Achievements

Effect of dipole moments of organic molecules on the transfer time of excited charge across molecule/metal-oxide junctions has been verified. Photoelectron spectroscopy, X-ray absorption spectroscopy and core-hole clock spectroscopy were utilized to examine the properties of the junctions between shuttle cock-type phthalocyanine films and strontium titanate surfaces. The charge transfer time from phthalocyanine to the oxide surface tends to be shorter if phthalocyanine has a larger dipole moment. However, the interaction strength and the energy-level alignment at the interface affect more drastically the transfer time.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (14 results)

All 2016 2015 2014

All Journal Article (2 results) (of which Peer Reviewed: 2 results,  Acknowledgement Compliant: 1 results) Presentation (12 results) (of which Int'l Joint Research: 2 results,  Invited: 2 results)

  • [Journal Article] Capturing transiently charged states at the C60/TiO2(110) interface by time-resolved soft X-ray photoelectron spectroscopy2016

    • Author(s)
      Kenichi Ozawa, Susumu Yamamoto, Ryu Yukawa, Kazuma Akikubo, Masato Emori, Hiroshi Sakama, Iwao Matsuda
    • Journal Title

      Organic Electronics

      Volume: 31 Pages: 98-103

    • DOI

      10.1016/j.orgel.2016.01.020

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electron-donor dye molecule on ZnO(10-10), (0001), and (000-1) studied by photoelectron spectroscopy and X-ray absorption spectroscopy2016

    • Author(s)
      Kenichi Ozawa, Masahiro Suzuki, Ryo Tochikubo, Hiroo Kato, Yuichi Sugizaki, Kazuyuki Edamoto, and Kazuhiko Mase
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 120 Issue: 16 Pages: 8653-8662

    • DOI

      10.1021/acs.jpcc.6b00454

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] フタロシアニン薄膜と酸化物の界面電子構造2016

    • Author(s)
      小澤健一,木村結香子,飛嶋健祐,加藤博雄,Marie D'Angelo,間瀬一彦
    • Organizer
      2015年度量子ビームサイエンスフェスタ
    • Place of Presentation
      つくば国際会議場
    • Year and Date
      2016-03-15
    • Related Report
      2015 Annual Research Report
  • [Presentation] 光電子分光によるチタン酸ストロンチウム表面での金属フタロシアニン吸着状態の検証と表面-吸着種間の電荷移動メカニズムの考察2015

    • Author(s)
      木村結花子,D'Angelo Marie,加藤博雄,間瀬一彦,小澤健一
    • Organizer
      2015年真空・表面科学合同講演会
    • Place of Presentation
      つくば国際会議場
    • Year and Date
      2015-12-01
    • Related Report
      2015 Annual Research Report
  • [Presentation] 時間分解光電子分光によるフラーレン/チタニア界面の光励起キャリア挙動の研究2015

    • Author(s)
      小澤健一,江森万里,坂間弘,湯川龍,秋久保一馬,山本達,松田巌
    • Organizer
      2015年真空・表面科学合同講演会
    • Place of Presentation
      つくば国際会議場
    • Year and Date
      2015-12-01
    • Related Report
      2015 Annual Research Report
  • [Presentation] 太陽エネルギー変換材料の光励起キャリアダイナミクス2015

    • Author(s)
      小澤健一
    • Organizer
      第54回化合物新磁性材料専門研究会
    • Place of Presentation
      東京大学本郷キャンパス
    • Year and Date
      2015-11-20
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] The behavior of photoexcited carriers at the C60/TiO2(110) interface2015

    • Author(s)
      K. Ozawa, S. Yamamoto, R. Yukawa, K. Akikubo, I. Matsuda, E. Masato, H. Sakama
    • Organizer
      The 15th International Conference on the Formation of Semiconductor Interface
    • Place of Presentation
      Hiroshima, Japan
    • Year and Date
      2015-11-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Correlation between adsorption state of pi-conjugated organic molecule on oxide surfaces and charge transfer across the organic/oxide interface2015

    • Author(s)
      K. Ozawa, M. Suzuki, R. Tochikubo, H. Kato, K. Mase
    • Organizer
      International Conference on Electron Spectroscopy and Structure 2015
    • Place of Presentation
      Stony Brook, NY, USA
    • Year and Date
      2015-09-28
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 電荷アクセプタ分子のSrTiO3(001)表面への吸着2015

    • Author(s)
      伊田直也,木村結花子,加藤博雄,間瀬一彦,小澤健一
    • Organizer
      第3回物構研サイエンスフェスタ
    • Place of Presentation
      筑波国際会議場(茨城県つくば市)
    • Year and Date
      2015-03-17
    • Related Report
      2014 Research-status Report
  • [Presentation] Cs吸着による有機/酸化物界面での電荷移動制御2015

    • Author(s)
      木村結花子,伊田直也,加藤博雄,間瀬一彦,小澤健一
    • Organizer
      第28回日本放射光学会年会・放射光科学合同シンポジウム
    • Place of Presentation
      立命館大学草津キャンパス(滋賀県草津市)
    • Year and Date
      2015-01-11
    • Related Report
      2014 Research-status Report
  • [Presentation] TCNQ吸着によるSrTiO3(001)表面の電子構造変化と電気伝導度変化の評価2014

    • Author(s)
      伊田直也,木村結花子,加藤博雄,間瀬一彦,小澤健一
    • Organizer
      第34回表面科学学術講演会
    • Place of Presentation
      島根県立産業交流会館(島根県松江市)
    • Year and Date
      2014-11-06
    • Related Report
      2014 Research-status Report
  • [Presentation] VUV/SX光を利用した表面化学研究の動向と展望2014

    • Author(s)
      小澤健一
    • Organizer
      フォトンファクトリー研究会「高輝度真空紫外・軟X線を利用した次世代サイエンス」
    • Place of Presentation
      高エネルギー加速器研究機構(茨城県つくば市)
    • Year and Date
      2014-10-18
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] 有機/酸化物界面の電荷移動制御2014

    • Author(s)
      小澤健一,木村結花子,三森悠平,加藤博雄
    • Organizer
      第27回日本表面科学会年会・放射光科学合同シンポジウム
    • Place of Presentation
      広島国際会議場(広島県)
    • Related Report
      2013 Research-status Report
  • [Presentation] π共役系色素分子と酸化物表面間の電荷授受制御2014

    • Author(s)
      木村結花子,伊田直也,加藤博雄,小澤健一
    • Organizer
      物構研サイエンスフェスタ2013
    • Place of Presentation
      つくば国際会議場(茨城県)
    • Related Report
      2013 Research-status Report

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Published: 2014-07-25   Modified: 2019-07-29  

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