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Preparation of porous molecular crystals as nano-materials fabrication templates

Research Project

Project/Area Number 25410092
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Functional solid state chemistry
Research InstitutionShizuoka University

Principal Investigator

Ueda Kazumasa  静岡大学, 工学部, 教授 (10275290)

Co-Investigator(Kenkyū-buntansha) KOKADO Satoshi  静岡大学, 工学部, 准教授 (50377719)
Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2015: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2014: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2013: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Keywords有機結晶作製法 / 多孔質 / ナノ構造体 / 配向制御 / 多孔質有機結晶
Outline of Final Research Achievements

Fabrication of nano-magnets on several substrates is an attractive field because of their potential use for high-density information storage. Control of the position and distance between nano-magnets is one of the remaining subjects of this field. Our approach to overcome this subject is arranging nano-magnets in crystal using various templates with desired morphology to direct formation of the magnets. Tetrathiafulvalenoquinone-1,3-dithiolemethide derivatives are one of the good candidate for constructing such templates. Because tetrathiafulvalenoquinone-1,3-dithiolemethide derivatives often form porous structures in their crystals and capture inorganic anions. But the size of the porous structures was not enough to capture molecular based magnets or magnetic metal aggregations. In order to enlarge the size of porous structures, we examined molecular arrangements of various methoxycarbonyl substituted tetrathiafulvalenoquinone-1,3-dithiolemethide derivatives.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (36 results)

All 2016 2015 2014 2013

All Journal Article (9 results) (of which Peer Reviewed: 9 results,  Open Access: 3 results,  Acknowledgement Compliant: 4 results) Presentation (27 results) (of which Int'l Joint Research: 7 results,  Invited: 6 results)

  • [Journal Article] Anomalous Hall effects in pseudo-single-crystal gamma'-Fe4N thin films2016

    • Author(s)
      Kazuki Kabara, Masakiyo Tsunoda, and Satoshi Kokado
    • Journal Title

      AIP Advances

      Volume: 6 Issue: 5

    • DOI

      10.1063/1.4942550

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Transverse anisotropic magnetoresistance effects in pseudo-single-crystal gamma'-Fe4N thin films2016

    • Author(s)
      Kazuki Kabara, Masakiyo Tsunoda, and Satoshi Kokado
    • Journal Title

      AIP Advances

      Volume: 6 Issue: 5

    • DOI

      10.1063/1.4943923

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Twofold and Fourfold Symmetric Anisotropic Magnetoresistance Effect in A Model with Crystal Field2015

    • Author(s)
      Satoshi Kokado and Masakiyo Tsunoda
    • Journal Title

      J. Phys. Soc. Jpn.

      Volume: 84 Issue: 9

    • DOI

      10.7566/jpsj.84.094710

    • NAID

      120005649704

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Synthesis, Electronic, and Crystal Structures of Methoxycarbonyl-substituted 2,5-Di(1,3-dithiol-2-ylidene)-1,3-dithiolane-4-thione Derivatives2014

    • Author(s)
      Kazumasa Ueda, Hiroki Kusanagi, Hiroki Nanbo, Yoshiumi Kohno, Tomoe Egami, Keiko Miyabayashi, and Takeyuki Suzuki
    • Journal Title

      Chemistry Letters

      Volume: 43 Issue: 8 Pages: 1224-1226

    • DOI

      10.1246/cl.140288

    • NAID

      130004427127

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Annealing effects on nitrogen site ordering and anisotropic magnetoresistance in pseudo-single-crystal gamma'-Fe4N films2014

    • Author(s)
      Kazuki Kabara, Masakiyo Tsunoda, Satoshi Kokado
    • Journal Title

      Applied Physics Express

      Volume: 7 Issue: 6 Pages: 063003-063003

    • DOI

      10.7567/apex.7.063003

    • Related Report
      2014 Research-status Report 2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Quantitative analysis of anisotropic magnetoresistance in Co2MnZ and Co2FeZ epitaxial thin films2014

    • Author(s)
      Y. Sakuraba, S. Kokado, Y. Hirayama, T. Furubayashi, H. Sukegawa, S. Li, Y. K. Takahashi, and K. Hono
    • Journal Title

      Appl. Phys. Lett.

      Volume: 104 Issue: 17

    • DOI

      10.1063/1.4874851

    • Related Report
      2014 Research-status Report 2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Anisotropic magnetoresistance effect of a strong ferromagnet : magnetization direction dependence in a model with crystal field2014

    • Author(s)
      S. Kokado and M. Tsunoda
    • Journal Title

      Phys. Status Solidi C

      Volume: 11 Issue: 5-6 Pages: 1026-1032

    • DOI

      10.1002/pssc.201300736

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Zigzag Arrangement of Bromo-substituted 2,5-Di(1,3-dithiol-2-ylidene)-1,3-dithiolane-4-thione Derivatives and Their Physical Properties2013

    • Author(s)
      Kazumasa Ueda, Kei Kunimoto, Kousuke Henmi, Keiko Miyabayashi, and Kenji Yoza
    • Journal Title

      Chem. Lett

      Volume: 42 Issue: 11 Pages: 1420-1422

    • DOI

      10.1246/cl.130704

    • NAID

      130004426841

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Anisotropic Magnetoresistance Effect : General Expression of AMR Ratio and Intuitive Explanation for Sign of AMR Ratio2013

    • Author(s)
      S. Kokado and M. Tsunoda
    • Journal Title

      Advanced Materials Research

      Volume: 750-752 Pages: 750-752

    • DOI

      10.4028/www.scientific.net/amr.750-752.978

    • NAID

      120005317559

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] Anisotropic Magnetoresistance Effects in Fe, Co, Ni, Fe4N, and Half-Metallic Ferromagnet: Systematic Analysis and Intuitive Explanation2016

    • Author(s)
      Satoshi Kokado, Masakiyo Tsunoda
    • Organizer
      2016 Materials Research Society Spring Meeting & Exhibit
    • Place of Presentation
      Phoenix Convention Center (Phoenix, Arizona, USA)
    • Year and Date
      2016-03-29
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 近赤外領域に吸収を持つアルキルチオ置換2,5-ジ(1,3-ジチオール-2-イリデン)-1,3-ジチオラン-4-チオン誘導体の合成と固体での光物性2016

    • Author(s)
      植田一正、草薙弘樹、中條航希
    • Organizer
      日本化学会第96春季年会(2016)
    • Place of Presentation
      同志社大学(京田辺市,京都府)
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] Theoretical Study on Twofold and Fourfold Symmetric Anisotropic Magnetoresistance Effect2016

    • Author(s)
      Satoshi Kokado, Masakiyo Tsunoda
    • Organizer
      American Physical Society March Meeting 2016
    • Place of Presentation
      Baltimore Convention Center (Baltimore, Maryland, USA)
    • Year and Date
      2016-03-17
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Twofold and Fourfold Symmetric Anisotropic Magnetoresistance Effect in a Model with Crystal Field2016

    • Author(s)
      Satoshi Kokado, Masakiyo Tsunoda
    • Organizer
      DPG Spring Meeting 2016 (ドイツ物理学会)
    • Place of Presentation
      University of Regensburg (Regensburg, Germany)
    • Year and Date
      2016-03-10
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Anomalous Hall effect in pseudo-single-crystal gamma'-Fe4N thin films2016

    • Author(s)
      Kazuki Kabara, Masakiyo Tsunoda, Satoshi Kokado
    • Organizer
      13th Joint MMM-Intermag Conference
    • Place of Presentation
      HILTON SAN DIEGO BAYFRONT (San Diego, USA)
    • Year and Date
      2016-01-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Transverse anisotropic magnetoresistance effects in pseudo-single-crystal gamma'-Fe4N thin films2016

    • Author(s)
      Kazuki Kabara, Masakiyo Tsunoda, Satoshi Kokado
    • Organizer
      13th Joint MMM-Intermag Conference
    • Place of Presentation
      HILTON SAN DIEGO BAYFRONT (San Diego, USA)
    • Year and Date
      2016-01-14
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 強磁性体の異方性磁気抵抗効果:波動関数を用いた直感的説明2016

    • Author(s)
      古門聡士, 角田匡清
    • Organizer
      応用物理学会新領域研究「強的秩序とその操作に関わる研究グループ第1回研究会」
    • Place of Presentation
      東京工業大学キャンパス・イノベーションセンター(港区、東京都)
    • Year and Date
      2016-01-04
    • Related Report
      2015 Annual Research Report
  • [Presentation] Anisotropic Magnetoresistance Effects in Fe, Co, Ni, Fe4N, and Half-Metallic Ferromagnet: Systematic Analysis and Intuitive Explanation2015

    • Author(s)
      古門 聡士, 伊東卓哉, 和田竜太朗, 角田匡清
    • Organizer
      13th RIEC International Workshop on Spintronics
    • Place of Presentation
      東北大学電気通信研究所(仙台市、宮城県)
    • Year and Date
      2015-11-19
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Fe4N擬単結晶薄膜の異方性磁気抵抗効果と異常ホール効果2015

    • Author(s)
      角田匡清, 鹿原和樹, 古門聡士
    • Organizer
      電子情報通信学会磁気記録・情報ストレージ研究会
    • Place of Presentation
      大阪大学吹田キャンパス工学研究科マテリアル生産科学専攻(吹田市、大阪府)
    • Year and Date
      2015-10-22
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 擬単結晶γ’-Fe4N薄膜の異常ホール効果2015

    • Author(s)
      鹿原和樹, 角田匡清, 古門聡士
    • Organizer
      日本磁気学会
    • Place of Presentation
      名古屋大学(名古屋市、愛知県)
    • Year and Date
      2015-09-09
    • Related Report
      2015 Annual Research Report
  • [Presentation] Mn4N薄膜の異方性磁気抵抗効果と異常ホール効果2015

    • Author(s)
      鹿原和樹, 角田匡清, 古門聡士
    • Organizer
      日本磁気学会
    • Place of Presentation
      名古屋大学(名古屋市、愛知県)
    • Year and Date
      2015-09-09
    • Related Report
      2015 Annual Research Report
  • [Presentation] (2)Size-effect of Alkylthio Groups on Solid State Optical Properties of MethoxyCarbonyl Substituted 2,5-Di(1,3-dithiol-2-ylidene)-1,3-dithiolane-4-thione Derivatives2015

    • Author(s)
      K. Ueda
    • Organizer
      The Seventh East Asia Symposium on Functional Dyes and Advanced Materials (EAS7)
    • Place of Presentation
      Osaka Prefecture University (Sakai, Osaka, Japan)
    • Year and Date
      2015-09-02
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Fe4N薄膜の異方性磁気抵抗効果:理論的研究2015

    • Author(s)
      古門聡士、角田匡清
    • Organizer
      みちのく磁性談話会
    • Place of Presentation
      宮城蔵王ロイヤルホテル(刈田郡、宮城県)
    • Year and Date
      2015-06-06
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] メトキシカルボニル置換2,5-ジ(1,3-ジチオール-2-イリデン)-1,3-ジチオラン-4-チオンの粉末反射スペクトルに及ぼすアルキルチオ基の効果2015

    • Author(s)
      植田 一正・草薙 弘樹・森 寛顕
    • Organizer
      日本化学会大95春季年会(2015)
    • Place of Presentation
      日本大学船橋キャンパス、船橋市、千葉県
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Research-status Report
  • [Presentation] Intuitive Explanation of Anisotropic Magnetoresistance (AMR) Effect and Necessary Condition for Half-Metallic Ferromagnet ``Negative AMR''2015

    • Author(s)
      Satoshi Kokado, Yuta Kitagawa, Takuya Ito, and Masakiyo Tsunoda
    • Organizer
      Deutsche Physikalische Gesellschaft (DPG) Spring Meeting
    • Place of Presentation
      Technische Universitat Berlin, Berlin, Germany
    • Year and Date
      2015-03-15 – 2015-03-20
    • Related Report
      2014 Research-status Report
  • [Presentation] 強磁性体の異方性磁気抵抗効果の理論的研究2015

    • Author(s)
      古門聡士
    • Organizer
      電気通信研究所共同プロジェクト研究会
    • Place of Presentation
      東北大学電気通信研究所、仙台市、宮城県
    • Year and Date
      2015-02-20
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] Novel approach to investigate spin-polarization in half-metallic Heusler compounds via anisotropic magnetoresistance effect2014

    • Author(s)
      Y. Sakuraba, S. Kokado, Y. Hirayama, T. Furubayashi, H. Sukegawa, S. Li, Y. K. Takahashi, and K. Hono
    • Organizer
      The 59th Annual Magnetism and Magnetic Materials Conference
    • Place of Presentation
      Hilton Hawaiian Village Conference Center, Hawaii, USA
    • Year and Date
      2014-11-03 – 2014-11-07
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] 異方性磁気抵抗(AMR)効果の直感的説明とハーフメタリック強磁性体の必要条件「負のAMR」2014

    • Author(s)
      古門聡士,北川佑太,角田匡清
    • Organizer
      応用物理学会
    • Place of Presentation
      北海道大学札幌キャンパス、札幌市、北海道
    • Year and Date
      2014-09-17 – 2014-09-20
    • Related Report
      2014 Research-status Report
  • [Presentation] 近赤外領域に吸収を持つメトキシカルボニル置換2,5-ジ(1,3-ジチオール-2-イリデン)-1,3-ジチオラン-4-チオン誘導体の合成と固体での光物性2014

    • Author(s)
      植田一正・草薙弘樹・南保宏樹・河野芳海・宮林恵子・江上智恵・鈴木健之
    • Organizer
      第25回基礎有機化学討論会
    • Place of Presentation
      東北大学川内北キャンパス、仙台市、宮城県
    • Year and Date
      2014-09-07 – 2014-09-09
    • Related Report
      2014 Research-status Report
  • [Presentation] γ’-Fe4N擬単結晶薄膜の異方性磁気抵抗効果 ~規則度依存性~2014

    • Author(s)
      鹿原和樹,角田匡清,古門聡士
    • Organizer
      日本磁気学会
    • Place of Presentation
      慶応義塾大学日吉キャンパス、横浜市、神奈川県
    • Year and Date
      2014-09-02 – 2014-09-05
    • Related Report
      2014 Research-status Report
  • [Presentation] ハーフメタルホイスラー合金薄膜における異方性磁気抵抗効果の定量解析2014

    • Author(s)
      桜庭裕弥,古門聡士,平山悠介,古林孝夫,介川裕章,李 松田,高橋有紀子,宝野和博
    • Organizer
      日本磁気学会
    • Place of Presentation
      慶応義塾大学日吉キャンパス、横浜市、神奈川県
    • Year and Date
      2014-09-02 – 2014-09-05
    • Related Report
      2014 Research-status Report
  • [Presentation] メトキシカルボニル置換2,5-ジ(1,3-ジチオール-2-イリデン)-1,3-ジチオラン-4-チオン誘導体の合成と固体での光物性2014

    • Author(s)
      植田 一正・草薙 弘樹・南保 宏貴・河野 芳海・宮林 恵子・江上 智恵
    • Organizer
      日本化学会第94春季年会(2014)
    • Place of Presentation
      名古屋大学、名古屋
    • Related Report
      2013 Research-status Report
  • [Presentation] SYNTHESIS OF 2,5-DI(1,3-DITHIOLE-2-YLIDENE)-1,3-DITHOLANE-4THIONE DERIVATIVES AND THEIR APPLICATION TO DYE-SENSITIZED SOLAR CELLS2013

    • Author(s)
      Kazumasa Ueda, Hiroki Kusanagi, and Hiroki Nanbo
    • Organizer
      6th East Asia Symposium on Functional Dyes and Advanced Materials (EAS6)
    • Place of Presentation
      National Tsing Hua University, Hsinchu, Taiwan
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Crystal Structures and Solid State Optical Properties of 2,5-Di(1,3-dithiol-2-ylidene)-1,3-dithiolane-4-thione Derivatives2013

    • Author(s)
      Kazumasa Ueda, Hiroki Kusanagi
    • Organizer
      10th International Symposium on Crystalline Organic Metals Superconductors and Ferromagnets (ISCOM2013)
    • Place of Presentation
      Hotel Delta Centre-Ville, Montreal, Quebec, Canada
    • Related Report
      2013 Research-status Report
  • [Presentation] Anisotropic Magnetoresistance Effect: General Expression of AMR Ratio and Intuitive Explanation for Sign of AMR Ratio2013

    • Author(s)
      Satoshi Kokado, Masakiyo Tsunoda
    • Organizer
      3rd International Conference on Advanced Engineering Materials and Technology (AEMT 2013)
    • Place of Presentation
      Wantai International Hotel, Zhangjiajie, China
    • Related Report
      2013 Research-status Report
  • [Presentation] Theoretical Study of Anisotropic Magnetoresistance Effect: Magnetization Direction Dependence in A System with Crystal Field2013

    • Author(s)
      Satoshi Kokado, Masakiyo Tsunoda
    • Organizer
      Donostia International Conference on Nanoscaled Magnetism and Applications (DICNMA)
    • Place of Presentation
      The Miramar Palace, San Sebastian, Spain
    • Related Report
      2013 Research-status Report
  • [Presentation] 強磁性体の異方性磁気抵抗効果:結晶場を考慮に入れた模型での磁化方向依存性2013

    • Author(s)
      古門聡士、角田匡清
    • Organizer
      日本物理学会
    • Place of Presentation
      徳島大学(常三島キャンパス)、徳島
    • Related Report
      2013 Research-status Report

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Published: 2014-07-25   Modified: 2019-07-29  

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