Preparation of porous molecular crystals as nano-materials fabrication templates
| Project/Area Number |
25410092
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Functional solid state chemistry
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| Research Institution | Shizuoka University |
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Principal Investigator |
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| Co-Investigator(Kenkyū-buntansha) |
KOKADO Satoshi 静岡大学, 工学部, 准教授 (50377719)
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| Project Period (FY) |
2013-04-01 – 2016-03-31
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| Project Status |
Completed (Fiscal Year 2015)
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| Budget Amount *help |
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2015: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2014: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2013: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
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| Keywords | 有機結晶作製法 / 多孔質 / ナノ構造体 / 配向制御 / 多孔質有機結晶 |
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| Outline of Final Research Achievements |
Fabrication of nano-magnets on several substrates is an attractive field because of their potential use for high-density information storage. Control of the position and distance between nano-magnets is one of the remaining subjects of this field. Our approach to overcome this subject is arranging nano-magnets in crystal using various templates with desired morphology to direct formation of the magnets. Tetrathiafulvalenoquinone-1,3-dithiolemethide derivatives are one of the good candidate for constructing such templates. Because tetrathiafulvalenoquinone-1,3-dithiolemethide derivatives often form porous structures in their crystals and capture inorganic anions. But the size of the porous structures was not enough to capture molecular based magnets or magnetic metal aggregations. In order to enlarge the size of porous structures, we examined molecular arrangements of various methoxycarbonyl substituted tetrathiafulvalenoquinone-1,3-dithiolemethide derivatives.
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Report
(4 results)
Research Products
(36 results)
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[Journal Article] Synthesis, Electronic, and Crystal Structures of Methoxycarbonyl-substituted 2,5-Di(1,3-dithiol-2-ylidene)-1,3-dithiolane-4-thione Derivatives2014
Author(s)
Kazumasa Ueda, Hiroki Kusanagi, Hiroki Nanbo, Yoshiumi Kohno, Tomoe Egami, Keiko Miyabayashi, and Takeyuki Suzuki
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Journal Title
Chemistry Letters
Volume: 43
Issue: 8
Pages: 1224-1226
DOI
NAID
Related Report
Peer Reviewed / Acknowledgement Compliant
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