Synthesis and Characterization of Azulene-fused helicenes
| Project/Area Number |
25410096
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Functional solid state chemistry
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| Research Institution | Kyushu University |
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Principal Investigator |
Suemune Hiroshi 九州大学, 薬学研究科(研究院), 教授 (20095897)
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| Project Period (FY) |
2013-04-01 – 2016-03-31
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| Project Status |
Completed (Fiscal Year 2015)
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| Budget Amount *help |
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2015: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2014: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2013: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
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| Keywords | アズレン / ヘリセン / 有機薄膜太陽電池 / 塩化白金触媒 / 環化異性化反応 |
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| Outline of Final Research Achievements |
In this study, azulene-fused helicenes (AZHs) possessing a nonplanar helical π-conjugated architecture have been synthesized and characterized, and their electrochemical properties were studied. Our research project consists of the following three parts; 1) Development of new synthetic method for substituted azulenes via Pt(II)-catalyzed intramolecular ring expanding cycloisomerization. 2) Synthesis of AZHs and evaluation of its physical properties and self-assembly. 3) The study as an n-type electron acceptor in organic photovoltaic (OPV) applications.
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Report
(4 results)
Research Products
(53 results)
