| Budget Amount *help |
¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2015: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2014: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2013: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
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| Outline of Final Research Achievements |
In this study, magnesium-promoted reductive introduction of a functional group to aromatic compounds was investigated because magnesium is commercially available and relatively cheap. Moreover, an abnormal and regioselective carbon-carbon bond formation was a special theme in this coupling reaction. As a result, next reactions with a carbon-carbon bond or carbon-silicon bond formation were found in this research.; fixation of carbon dioxide to carbonyl group of benzoic acid esters, synthesis of acetylenic compounds with the transposition of the triple bond from aromatic conjugated ynones under acylation conditions, silylation of vinylpyridines at the terminal carbon atom of the vinyl group and double silylation of cinnamic acid esters with a leaving group at beta-position of the carbonyl group.
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