| Budget Amount *help |
¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2015: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2014: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2013: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
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| Outline of Final Research Achievements |
We succeeded to synthesize a new heterobuckybowl, bow-shaped heteroatom-containing aromatic compound, possessing two neighboring nitrogen atoms in the bowl skeleton. It was revealed that the molecule possesses bowl and twist structures in the neutral state, a shallower bowl structure in the one-electron oxidized state, and a planar structure in the two-electron oxidized state. Since the molecule is reversibly oxidized and reduced, the structure can be changed an controlled between the curved and planar structures by transfer of electrons.
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