Synthesis of New Heterobuckybowls
| Project/Area Number |
25410124
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Synthetic chemistry
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| Research Institution | Institute for Molecular Science |
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Principal Investigator |
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| Project Period (FY) |
2013-04-01 – 2016-03-31
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| Project Status |
Completed (Fiscal Year 2015)
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| Budget Amount *help |
¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2015: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2014: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2013: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
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| Keywords | バッキーボウル / ヘテロバッキーボウル / おわん型 / ヒドラジン / カルバゾール / 構造 / 酸化還元 |
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| Outline of Final Research Achievements |
We succeeded to synthesize a new heterobuckybowl, bow-shaped heteroatom-containing aromatic compound, possessing two neighboring nitrogen atoms in the bowl skeleton. It was revealed that the molecule possesses bowl and twist structures in the neutral state, a shallower bowl structure in the one-electron oxidized state, and a planar structure in the two-electron oxidized state. Since the molecule is reversibly oxidized and reduced, the structure can be changed an controlled between the curved and planar structures by transfer of electrons.
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Report
(4 results)
Research Products
(46 results)
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[Journal Article] Acid/Base-Regulated Reversible Electron Transfer Disproportionation of N-N linked Bicarbazole and Biacridine Derivatives2015
Author(s)
Palash Pandit,† Koji Yamamoto,† (†: equally contributed) Toshikazu Nakamura, Katsuyuki Nishimura, Yuki Kurashige, Takeshi Yanai, Go Nakamura, Shigeyuki Masaoka, Ko Furukawa, Yumi Yakiyama, Masaki Kawano and Shuhei Higashibayashi
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Journal Title
Chemical Science
Volume: 印刷中
Issue: 7
Pages: 4160-4173
DOI
Related Report
Peer Reviewed / Open Access / Acknowledgement Compliant
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[Presentation] ヒドラジノバッキーボウルの合成と性質2016
Author(s)
東林修平, Palash Pandit, 春木理恵, 足立伸一, 熊井玲児
Organizer
日本化学会第96春季年会
Place of Presentation
京都府京田辺市同志社大学京田辺キャンパス
Year and Date
2016-03-24
Related Report
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[Presentation] Acid-responsive electron transfer disproportionation of N-N linked bicarbazole derivatives2015
Author(s)
Palash Pandit, Koji Yamamoto, Toshikazu Nakamura, Katsuyuki Nishimura, Yuki Kurashige, Takeshi Yanai, Go Nakamura, Shigeyuki Masaoka, Ko Furukawa, Yumi Yakiyama, Masaki Kawano, Shuhei Higashibayashi
Organizer
16th International Symposium on Novel Aromatic Compounds
Place of Presentation
スペイン, マドリッドコンプルテンセ大学
Year and Date
2015-07-05
Related Report
Int'l Joint Research
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[Presentation] Columnar crystal structure and redox property of sumanenetrione2015
Author(s)
Shuhei Higashibayashi, Binod B. Shreshta, Yuki Morita, Kei Ohkubo, Shunichi Fukuzumi, Tatsuhiro Kojima, Masaki Kawano, Masahiro Ehara, Hidehiro Sakurai
Organizer
16th International Symposium on Novel Aromatic Compounds
Place of Presentation
スペイン, マドリッドコンプルテンセ大学
Year and Date
2015-07-05
Related Report
Int'l Joint Research
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[Presentation] ジアザヘリセン類の酸応答性電子移動不均化反応2015
Author(s)
東林修平, 山本浩司，Palash Pandit，中村敏和，西村勝之, 倉重佑輝，柳井毅，中村豪，正岡重行，古川貢, 焼山佑美, 河野正規
Organizer
第107回有機合成シンポジウム
Place of Presentation
東京都港区慶應義塾大学薬学部マルチメディア講堂
Year and Date
2015-06-09
Related Report
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[Presentation] スマネントリオンの結晶構造とアニオン種2014
Author(s)
東林修平, Binod Babu Shrestha, 森田悠紀, 大久保敬, 福住俊一, 小島達弘, 河野正規, 江原正博, 櫻井英博
Organizer
第25回基礎有機化学討論会
Place of Presentation
宮城県仙台市青葉区東北大学川内北キャンパス
Year and Date
2014-09-07 – 2014-09-09
Related Report
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[Presentation] C3 Symmetric Chrial Triazasumanene2013
Author(s)
Shuhei Higashibayashi, Qitao Tan, Sangita Karanjit, Masaki Kawano, Hidehiro Sakurai
Organizer
15th International Symposium on Novel Aromatic Compounds
Place of Presentation
Howard Civil Service International House, Taiwan, Taipei
Related Report
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