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Formation of neutral gas-cluster beam with high velocity and its application to SIMS

Research Project

Project/Area Number 25410147
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Analytical chemistry
Research InstitutionUniversity of Hyogo

Principal Investigator

Mochiji Kozo  兵庫県立大学, 工学(系)研究科(研究院), 教授 (40347521)

Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2015: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2014: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2013: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Keywordsクラスターイオン / 衝突 / 解離 / 弾性定数 / ヤング率 / 金属 / グラフェン / 衝撃応力 / 分子動力学シミュレーション / 質量スペクトル / 原子間ポテンシャル / 中性化率
Outline of Final Research Achievements

A mass spectrometry of dissociated ions of argon cluster ions (Ar1500+) in collision with several kinds of metal is carried out. In the mass spectra at collision energies less than 5 eV/atom, the branching ratio for the ion yield of Ar2+ to total ions detected, representing the ease of dissociation, is found to be significantly different for each metal. Magnitude correlation in the branching ratio well corresponds with that in the impact force caused by the collision. The impact force is calculated based on the Young’s modulus. This result indicates that dissociation of Ar cluster ions can probe a mechanical property of the material such as Young’s modulus. We apply this method to probe a graphene layer on copper. The branching ratio for graphene on copper is five times lower than that for bare copper. The calculated results obtained by molecular dynamics simulation proved that the graphene layer acts as a buffer against the impact force of the cluster ion upon collision.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (10 results)

All 2016 2015 2014 2013 Other

All Journal Article (2 results) (of which Peer Reviewed: 2 results,  Open Access: 1 results,  Acknowledgement Compliant: 2 results) Presentation (7 results) (of which Int'l Joint Research: 1 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Argon cluster ions cleaning and probing a graphene layer on copper2015

    • Author(s)
      Kozo Mochiji, Norio Inui, Ryousuke Asa, Kousuke Moritani
    • Journal Title

      e-Journal of Surface Science and Nanotechnology

      Volume: 13 Pages: 167-173

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Mass spectrometric analysis of the dissociation of argon cluster ions in collision with several kinds of metal2014

    • Author(s)
      Kozo Mochiji, Naoki Se, Norio Inui and Kousuke Moritani
    • Journal Title

      Rapid communications in Mass Spectrometry

      Volume: 28 Issue: 19 Pages: 2141-2146

    • DOI

      10.1002/rcm.7004

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] 解離性イオン散乱を用いたグラフェンの弾性プローブ2016

    • Author(s)
      持地広造、乾 徳夫、盛谷浩右
    • Organizer
      第63回応用物理学会春季学術講演会
    • Place of Presentation
      東京工業大学大岡山キャンパス(目黒区)
    • Year and Date
      2016-03-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] Dissociative scattering of argon cluster ions as a probe for mechanical properties of material surfaces2015

    • Author(s)
      Kozo Mochiji, Norio Inui, Kousuke Moritani
    • Organizer
      第16回『イオンビームによる表面・界面解析』特別研究会
    • Place of Presentation
      奈良女子大学(奈良市)
    • Year and Date
      2015-12-05
    • Related Report
      2015 Annual Research Report
  • [Presentation] Mass spectrometric method to probe a graphene on copper by using argon cluster ions2015

    • Author(s)
      Kozo Mochiji, Norio Inui, Ryousuke Asa, Kousuke Moritani
    • Organizer
      NN15 Nanotechnology Conference
    • Place of Presentation
      Thessaloniki (Greece)
    • Year and Date
      2015-07-06
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Arクラスターイオンの衝突誘起解離2014

    • Author(s)
      阿佐亮祐、乾 徳夫、盛谷浩右、持地広造
    • Organizer
      第34回表面科学学術講演会
    • Place of Presentation
      島根県立産業交流会館
    • Year and Date
      2014-11-06 – 2014-11-08
    • Related Report
      2014 Research-status Report
  • [Presentation] Arクラスターイオンの衝突解離に関する一考察

    • Author(s)
      瀬 直己、持地広造、乾 徳夫、盛谷浩右
    • Organizer
      第74回応用物理学秋季学術講演会
    • Place of Presentation
      同志社大学京田辺キャンパス
    • Related Report
      2013 Research-status Report
  • [Presentation] Arクラスターイオンの衝突誘起解離

    • Author(s)
      瀬 直己、持地広造、乾 徳夫、盛谷浩右
    • Organizer
      真空・表面科学合同講演会
    • Place of Presentation
      つくば国際会議場
    • Related Report
      2013 Research-status Report
  • [Presentation] クラスターイオンの衝突解離に関する弾性力学的考察

    • Author(s)
      阿佐亮祐、瀬 直己、乾 徳夫、盛谷浩右、持地広造
    • Organizer
      機械学会 情報・知能・精密機器部門講演会
    • Place of Presentation
      東洋大学白山キャンパス
    • Related Report
      2013 Research-status Report
  • [Patent(Industrial Property Rights)] 材料機械強度測定方法2013

    • Inventor(s)
      持地広造、乾 徳夫、盛谷浩右
    • Industrial Property Rights Holder
      兵庫県立大学
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2013-183207
    • Filing Date
      2013-09-04
    • Related Report
      2013 Research-status Report

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Published: 2014-07-25   Modified: 2019-07-29  

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