Development of simultaneous measurement system of XANES and UV-vis absorption spectrometer

• Project/Area Number: 25410156
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Multi-year Fund
• Section: 一般
• Research Field: Analytical chemistry
• Research Institution: Fukuoka University
• Principal Investigator: Kurisaki Tsutomu 福岡大学, 理学部, 准教授 (20268973)
• Project Period (FY): 2013-04-01 – 2016-03-31
• Project Status: Completed (Fiscal Year 2015)
• Budget Amount: ¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000); Fiscal Year 2015: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000); Fiscal Year 2014: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000); Fiscal Year 2013: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
• Keywords: 装置開発 / 可視吸収スペクトル / 溶存構造 / 金属錯体 / X-ray / 同時測定 / 紫外可視吸収スペクトル / XAFSスペクトル

Outline of Final Research Achievements

We started to design and develop our simultaneous measurement system of XANES and UV-vis absorption spectrometer. This spectrometer consists of in-situ X-ray absorption laboratory spectrometer and multi-channel Photo Detector system. We performed the spectrum measurement of copper complexes in aqueous solution. The measured spectra are in agreement with the spectra using commercially available spectrometer

Research Products

• [Journal Article] Analytical Chemistry Study on Cannon Balls Prepared at Late Edo and Meiji Period from Saga, Izumo and South Morioka (2015)
  • Author(s): H. Wakita, T. Kurisaki, Y.Ohbana, T. Yamaguchi, C. Numako, T. Yokoyama, S.Nagano
  • Journal Title: Proc. 5th International Symposium on History of Indigenous Knowledge Volume: 5 Pages: 127-137
  • Peer Reviewed
• [Journal Article] Acid-base behavior and Al^<3+> complex formation of synthesized 2,3-dihydr oxyterephthalic acid (DHTPA) at pH 3 as a model compound of Inogash ira fulvic acid (IFA) (2014)
  • Author(s): Tsutomu Kurisaki, Mayumi Etou, Yoshihiro Okaue, Hisanobu Waikita and Takushi Yokoyama
  • Journal Title: Polyhedron Volume: 72 Pages: 135-139
  • DOI: 10.1016/j.poly.2014.02.006
  • Peer Reviewed / Open Access
• [Journal Article] Analysis of Historical Iron Samples Distribute all over Japan by Means of ICP-MS and Portable Type XRF (2014)
  • Author(s): Y.Obana, T.Kurisaki, C.Numako, S.Nagano, T.Yokoyama, T.Yamaguchi, H.Wakita
  • Journal Title: Proceedings of the 4th International Symposium on History of Indigenous Knowledge Volume: 4 Pages: 138-144
  • Peer Reviewed
• [Journal Article] Synthesis and Equilibrium Study of Nickel(II), Copper(II), and Zinc(II) Complexes with N,N',N'',N''',N'''',N'''''-Hexakis(2-aminoethyl)-1,4,7,10,13,16-hexaazacyclooctadecane in an Aqueous Solution (2013)
  • Author(s): T. Kurisaki, Y. Matsuki, H. Wakita
  • Journal Title: Polyhedron Volume: 65 Pages: 200-205
  • DOI: 10.1016/j.poly.2013.08.031
  • Peer Reviewed
• [Journal Article] 13C and 27Al NMR Study of Complexation between Aluminium Ion and Simple Dicarboxylic Acids under an Acidic Condition: New Peak Assignments of 27Al NMR Spectra of Mixed Solutions of Al3+ and Simple Dicarboxylic Acids (2013)
  • Author(s): M. Etou, T. Kurisaki, Y. Okaue, H. Wakita, T. Yokoyama
  • Journal Title: Anal. Sci. Volume: 29 Pages: 843-848
  • NAID: 10031190641
  • Peer Reviewed
• [Journal Article] Bromo(1,4,7,10,13-pentaazacyclohexa decane)cobalt(III) Bromide (2013)
  • Author(s): T. Kurisaki, M. Hamano, H. Wakita
  • Journal Title: Dihydrate, Acta Cryst. E Volume: 69 Issue: 4 Pages: 179-180
  • DOI: 10.1107/s1600536813004947
  • Peer Reviewed
• [Journal Article] Characterization and photocatalytic activity of nitrogen-doped titanium(IV) oxide prepared by doping titania with TiN powder (2013)
  • Author(s): M. Iwase, K. Yamada, T. Kurisaki, H.Wakita
  • Journal Title: Applied Catalysis A Volume: 455 Pages: 86-91
  • DOI: 10.1016/j.apcata.2013.01.016
  • Peer Reviewed
• [Presentation] Analytical Chemistry Study on Cannon Balls Prepared at Late Edo and Meiji Period from Saga, Izumo and South Morioka (2015)
  • Author(s): H. Wakita, T. Kurisaki, Y.Ohbana, T. Yamaguchi, C. Numako, T. Yokoyama, S.Nagano
  • Organizer: 5th International Symposium on History of Indigenous Knowledge
  • Place of Presentation: 佐賀
  • Year and Date: 2015-11-10
  • Int'l Joint Research / Invited
• [Presentation] 質量分析法による近世に製造された歴史鉄試料中に含まれる微量元素および鉛の分析 (2015)
  • Author(s): 栗崎 敏, 尾花 侑亮, 沼子 千弥, 横山拓史, 長野暹, 脇田久伸, 山口敏男
  • Organizer: 分析化学会第64年会
  • Place of Presentation: 福岡
  • Year and Date: 2015-09-10
• [Presentation] Ｘ線分光法によるレアメタル元素の溶存状態 (2015)
  • Author(s): 脇田久伸、栗崎敏
  • Organizer: 分析化学会第64年会
  • Place of Presentation: 福岡
  • Year and Date: 2015-09-09
• [Presentation] ICP-MS法とX線分析法を用いた幕末から明治初期までの歴史鉄試料に含まれる微量元素の定量 (2014)
  • Author(s): 尾花 侑亮、栗崎 敏、沼子 千弥、横山拓史、長野暹、脇田久伸、山口敏男
  • Organizer: 第51回化学関連支部合同九州大会
  • Place of Presentation: 北九州国際会議場
  • Year and Date: 2014-06-28
• [Presentation] 全国各地に散在する江戸の幕末から明治初期までの歴史鉄試料の分析化学的研究 (2014)
  • Author(s): 尾花 侑亮、栗崎 敏、沼子 千弥、長野暹、脇田久伸、山口敏男
  • Organizer: 第74回分析化学討論会
  • Place of Presentation: 日本大学工学部
  • Year and Date: 2014-05-24 – 2014-05-25
• [Presentation] DV-Xα分子軌道法による各種トリアザ環銅(II)錯体の溶存構造解析 (2013)
  • Author(s): 栗崎敏, 横山尚平, 脇田久伸
  • Organizer: 第26回DV-Xa研究会
  • Place of Presentation: 京都
• [Presentation] Electronic Structure Analysis of Ionic Liquids Using X-Ray Photoelectron Spectroscopy (2013)
  • Author(s): T. Kurisaki, D. Tanaka, Y. Inoue, H. Wakita, B. Minofar, S. Fukuda, S. Ishiguro, Y. Umebayashi
  • Organizer: ASIANALYSIS XII
  • Place of Presentation: Fukuoka
• [Presentation] Soft X-ray spectrometers developed for measuring XANES spectra of light element materials (2013)
  • Author(s): H. Wakita, T. Kurisaki
  • Organizer: TXRF2013
  • Place of Presentation: Osaka