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Rare metal extraction ability of hybrid polymers consist of cyclodextrin and diatomite

Research Project

Project/Area Number 25410188
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Green/Environmental chemistry
Research InstitutionAkita University

Principal Investigator

Kondo Yoshihiko  秋田大学, 工学(系)研究科(研究院), 講師 (00361238)

Co-Investigator(Kenkyū-buntansha) HAMADA Fumio  秋田大学, 工学(系)研究科(研究院), 名誉教授 (40156401)
YAMADA Manabu  秋田大学, 工学(系)研究科(研究院), 助教 (90588477)
Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2015: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2014: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2013: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywordsシクロデキストリン / レアメタル / ポリマー / 希少元素 / リサイクル / シクロデキストリンポリマー / 有機・無機ハイブリッドポリマー
Outline of Final Research Achievements

Cycrodextrins (CyDs) trous-shaped cyclic oligomer composing of 1,4-linked D-glucopyranose. A variety of organic compounds can be included in their center
cavities in aqueous media. A couple years ago, we have reported hybrid polymer consisted of be-ta-CyD and diatomite. In that report, it was shown that the hyblid polymer was high affinity for Cesium ion. In this study, we prepared hybrid polymers consisted of be-ta-CyD and diatomite, where ratio by weight of be-ta-CyD and diatomite in a reaction mixture was changed ranging from 1:0.5, 1:1, and 1:2. It was shown that the cecium extraction value of those hybrid polymers were over 90 % from 1 min of mixture time and mild acidity-nutral of pH condition.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (21 results)

All 2015 2014 2013

All Journal Article (7 results) (of which Peer Reviewed: 7 results) Presentation (13 results) (of which Int'l Joint Research: 2 results,  Invited: 3 results) Book (1 results)

  • [Journal Article] Selective extraction of Pd(II) ions from automotive catalyst residue in Cl− media by O-thiocarbamoyl-functionalized thiacalix[n]arenes2015

    • Author(s)
      Muniyappan Rajiv Gandhi, Manabu Yamada, Yoshihiko Kondo, Atsushi Shibayam, Fumio Hamada
    • Journal Title

      Hydrometallurgy

      Volume: 151 Pages: 133-140

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Synthesis and characterization of p-diethylaminomethylthiacalix[4]arene for selective recovery of platinum from automotive catalyst residue2014

    • Author(s)
      Manabu Yamada, Muniyappan Rajiv Gandhi, Yoshihiko Kondo and Fumio Hamada
    • Journal Title

      Supramol. Chem.

      Volume: 26(7-8) Issue: 7-8 Pages: 620-630

    • DOI

      10.1080/10610278.2014.887202

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] High selective extraction ability for platinum-group metals based on thiacalix[6]arene derivatives2014

    • Author(s)
      Yoshihiko Kondo, Munkhtuya Ulzii, Shinichi Itoh, Manabu Yamada and Fumio Hamada
    • Journal Title

      Int. J. Soc. Mater. Eng. Resour.

      Volume: 20(1) Pages: 103-108

    • NAID

      130005095371

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Characterization of Dimethylthocarbamoyl -Modified Thiacalix[n]arenes for Selective Pd(II)-Ion Extraction2014

    • Author(s)
      Muniyappan Rajiv Gandhi, Manabu Yamada, Yoshihiko Kondo, Ryo Sato and Fumio Hamada
    • Journal Title

      Ind. Eng. Chem. Res.

      Volume: 53 Issue: 7 Pages: 2559-2565

    • DOI

      10.1021/ie404161s

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] A 3D supramolecular network assembly based on thiacalix[4]arene by halogen-halogen, CH-Br, CH-π, and S-π interactions2013

    • Author(s)
      Manabu Yamada, Yuji Ootashiro, Yoshihiko Kondo, Fumio Hamada
    • Journal Title

      Tetrahedron Lett.

      Volume: 54 Pages: 1510-1514

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Metal Extraction capability for hybrid polymers consisted of β-cyclodextrin and diatomite2013

    • Author(s)
      Munkhtuya Ulzii, Yoshihiko Kondo, Manabu Yamada, and Fumio Hamada
    • Journal Title

      Int. J. Soc. Mater. Eng. Resour.

      Volume: 19(1) Pages: 32-36

    • NAID

      130004685654

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Supramolecular assemblies with water-soluble p-sulfonatothiacalix[6]arene lanthanide complexes: one-dimensional ‘ladder-type’ coordination polymers and one-dimensional hydrogenbonded polymers2013

    • Author(s)
      Manabu Yamada, Fumio Hamada
    • Journal Title

      CrystEngComm

      Volume: 15 Issue: 28 Pages: 5703-5712

    • DOI

      10.1039/c3ce40431e

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] Cesium extraction capability based on hybrid polymers consist of -cyclodextrin and diatomite2015

    • Author(s)
      99.Yoshihiko Kondo, Munkhtuya Ulzii, Manabu Yamada, Fumio Hamada
    • Organizer
      2015 International Chemical Congress of Pacific Basin Societies(PACIHICHEM2015)
    • Place of Presentation
      Honolulu Hawaii
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 修飾シクロデキストリンポリマーの合成およびガス吸着能の検討2015

    • Author(s)
      三戸千明・松田智紗・近藤良彦・濱田文男
    • Organizer
      第13回ホスト・ゲスト化学シンポジウム
    • Place of Presentation
      東北大学川内北キャンパス
    • Year and Date
      2015-06-06
    • Related Report
      2015 Annual Research Report
  • [Presentation] Synthesis and Gas Adsorption Properties of Hybrid Polymers Consisting of Modified Cyclodextrin and Amorphous Silica2015

    • Author(s)
      Chiaki Sannohe, Chisa Matsuda, Yoshihiko Kodno, Fumio Hamada
    • Organizer
      8th Asian Cyclodextrin Conference・第32回シクロデキストリンシンポジウム合同会議
    • Place of Presentation
      くまもと県民交流館パレア
    • Year and Date
      2015-05-14
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 3D-supramolecular network assemblies based on halogen-halogen, CH-Br, CH- interactions, halogen bonding, and hydrogen bonding in the thiacalixarenes systems2014

    • Author(s)
      Fumio Hamada and Manabu Yamada
    • Organizer
      BIT’s 4th annual World, Congress of Nanotechnology-2014
    • Place of Presentation
      Qingdao, China
    • Year and Date
      2014-10-29 – 2014-10-31
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] ガス吸蔵能を有するCDPの合成とその物理的性状2014

    • Author(s)
      髙木思野, 照井綾乃, 松田智紗, 近藤良彦, 濱田文男
    • Organizer
      第31回シクロデキストリンシンポジウム
    • Place of Presentation
      島根県民会館
    • Year and Date
      2014-09-11 – 2014-09-12
    • Related Report
      2014 Research-status Report
  • [Presentation] Cesium extraction for hybrid polymers consist of β-cyclodextrin and diatomite2014

    • Author(s)
      Yoshihiko Kondo, Munkhtuya Ulzii, Katsuya Tsurubuchi, Manabu Yamada and Fumio Hamada
    • Organizer
      17th International Cyclodextrin Symposium (ICS17)
    • Place of Presentation
      Saarland University, Saarbrücken, Germany
    • Year and Date
      2014-05-29 – 2014-05-31
    • Related Report
      2014 Research-status Report
  • [Presentation] Gas adsorption profile based on hybrid polymers consist of modified cyclodextrins and amorphous silica2014

    • Author(s)
      Fumio Hamada, Shino Takagi, Ayano Terui and Yoshihiko Kondo
    • Organizer
      17th International Cyclodextrin Symposium (ICS17)
    • Place of Presentation
      Saarland University, Saarbrücken, Germany
    • Year and Date
      2014-05-29 – 2014-05-31
    • Related Report
      2014 Research-status Report
  • [Presentation] Supramolecular Construction through the Halogen Bonding and Halogen-Halogen Interaction in the Thiacalixarene System2013

    • Author(s)
      Fumio Hamada, Manabu Yamada, Ryo Kanazawa
    • Organizer
      12th International Conference on Calixarene(Calix2013)
    • Place of Presentation
      St. John’s NL, Canada
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Highly Selective Extractability of Platinum Group Metals Based on New Thiacalix[4]arene Derivatives2013

    • Author(s)
      Yoshihiko Kondo, Manabu Yamada and Fumio Hamada
    • Organizer
      12th International Conference on Calixarene(Calix2013)
    • Place of Presentation
      St. John’s NL, Canada
    • Related Report
      2013 Research-status Report
  • [Presentation] Adsorption Functionality Based on Hybrid Polymers Consisted of Cyclodextrin and Diatomite2013

    • Author(s)
      Fumio Hamada, Munkhtuya Ulzii, Shino Takagi, Manabu Yamada and Yoshihiko Kondo
    • Organizer
      7th Asian Cyclodextrin Conference
    • Place of Presentation
      Bangkok, Thailand
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Selective Extraction Profile of Rare Metals Based on Thiacalix[4]arene Derivatives2013

    • Author(s)
      Yoshihiko Kondo, Manabu Yamada and Fumio Hamada
    • Organizer
      7th International Conference on Materials Engineering for Resources
    • Place of Presentation
      秋田 日本
    • Related Report
      2013 Research-status Report
  • [Presentation] Metal Extraction Profile for Hybrid Polymers Consisted of β-cyclodextrin and Diatomite2013

    • Author(s)
      Munkhtuya Ulzii, Yoshihiko Kondo, Manabu Yamada and Fumio Hamada
    • Organizer
      7th International Conference on Materials Engineering for Resources
    • Place of Presentation
      秋田
    • Related Report
      2013 Research-status Report
  • [Presentation] シクロデキストリン-珪藻土ハイブリットポリマーの金属抽出挙動2013

    • Author(s)
      近藤良彦・高木思野・山田 学・濱田文男
    • Organizer
      第30回シクロデキストリンシンポジウム
    • Place of Presentation
      熊本
    • Related Report
      2013 Research-status Report
  • [Book] シクロデキストリンの科学と技術 第11章修飾シクロデキストリンの工業的展開2013

    • Author(s)
      近藤良彦、濱田文男
    • Total Pages
      314
    • Publisher
      シーエムシー出版
    • Related Report
      2013 Research-status Report

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Published: 2014-07-25   Modified: 2019-07-29  

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